Pseudo-enantiomeric chiral components and formation of the helical micro- and nanostructures in charge-transfer complexes.

Abstract:

:Helical organic micro- and nanostructures are formed by a charge-transfer complex, cinchonidine-TCNQ. These unusual forms result from the chirality, the steric structure and specific interactions of cinchonidine molecules. These materials are semiconductors (10-4 S cm-1), with the typical absorption spectra in IR and UV-vis, but also have a characteristic of CD spectrum. Surprisingly, conductive micro and nano helices are not formed in pseudo-enantiomeric cinchonine, i.e. the complex of cinchonine and TCNQ.

journal_name

R Soc Open Sci

authors

Langer JJ,Hreczycho G

doi

10.1098/rsos.171499

subject

Has Abstract

pub_date

2018-03-14 00:00:00

pages

171499

issue

3

issn

2054-5703

pii

rsos171499

journal_volume

5

pub_type

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