Abstract:
:Helical organic micro- and nanostructures are formed by a charge-transfer complex, cinchonidine-TCNQ. These unusual forms result from the chirality, the steric structure and specific interactions of cinchonidine molecules. These materials are semiconductors (10-4 S cm-1), with the typical absorption spectra in IR and UV-vis, but also have a characteristic of CD spectrum. Surprisingly, conductive micro and nano helices are not formed in pseudo-enantiomeric cinchonine, i.e. the complex of cinchonine and TCNQ.
journal_name
R Soc Open Scijournal_title
Royal Society open scienceauthors
Langer JJ,Hreczycho Gdoi
10.1098/rsos.171499subject
Has Abstractpub_date
2018-03-14 00:00:00pages
171499issue
3issn
2054-5703pii
rsos171499journal_volume
5pub_type
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