Characterization and identification of gamma-irradiated sauces by electron spin resonance spectroscopy using different sample pretreatments.

Abstract:

:Tomato ketchup, barbeque sauce, sweet chili sauce, and spaghetti sauce were gamma irradiated at 0, 1, 5, and 10 kGy. Electron spin resonance (ESR) technique was used to characterize the irradiated sauces, targeting radiation-induced cellulose radicals and using a modified sample pretreatment method. The samples were first washed with water, and then the residues were extracted with alcohol. The non-irradiated sauces exhibited the single central signal, whose intensity showed a significant increase on irradiation. The ESR spectra from the radiation-induced cellulose radicals, with two side peaks (g=2.02012 and g=1.98516) equally spaced (± 3 mT) from the central signal, were also observed in the irradiated sauces. The improvements in the central (natural) and radiation-induced (two side peaks corresponding to the cellulose radicals) signal intensities were obvious, when compared with routine freeze-drying and alcoholic-extraction techniques.

journal_name

Food Chem

journal_title

Food chemistry

authors

Akram K,Ahn JJ,Kwon JH

doi

10.1016/j.foodchem.2012.11.044

subject

Has Abstract

pub_date

2013-06-01 00:00:00

pages

1878-83

issue

2-3

eissn

0308-8146

issn

1873-7072

pii

S0308-8146(12)01775-X

journal_volume

138

pub_type

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