Phase distribution of synthetic pyrethroids in runoff and stream water.

Abstract:

:Synthetic pyrethroids (SPs) are a group of hydrophobic compounds with significant aquatic toxicity. Their strong affinity to suspended solids and humic materials suggests that SPs in natural surface water are distributed in solid-adsorbed, dissolved organic matter (DOM)-adsorbed, and freely dissolved phases. The freely dissolved phase is of particular importance because of its mobility and bioavailability. In the present study, we used solid-phase microextraction to detect the freely dissolved phase, and we evaluated the phase distribution of bifenthrin and permethrin in stream and runoff waters. In stream water, most SPs were associated with the suspended solids and, to a lesser extent, with DOM. The freely dissolved phase contributed only 0.4% to 1.0%. In runoff effluents, the freely dissolved concentration was 10% to 27% of the overall concentration. The predominant partitioning into the adsorbed phases implies that the toxicity of SPs in surface water is reduced because of decreased bioavailability. This also suggests that monitoring protocols that do not selectively define the freely dissolved phase can lead to significant overestimation of toxicity or water-quality impacts by SPs.

journal_name

Environ Toxicol Chem

authors

Liu W,Gan JJ,Lee S,Kabashima JN

doi

10.1897/03-183

subject

Has Abstract

pub_date

2004-01-01 00:00:00

pages

7-11

issue

1

eissn

0730-7268

issn

1552-8618

journal_volume

23

pub_type

杂志文章
  • Understanding solution-state noncovalent interactions between xenobiotics and natural organic matter using 19F/1H heteronuclear saturation transfer difference nuclear magnetic resonance spectroscopy.

    abstract::A combination of forward and reverse heteronuclear ((19)F/(1)H) saturation transfer difference (STD) nuclear magnetic resonance (NMR) spectroscopic techniques were applied to characterize the noncovalent interactions between perfluorinated aromatic xenobiotics and dissolved humic acid. These NMR techniques produce det...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.560

    authors: Longstaffe JG,Simpson AJ

    更新日期:2011-08-01 00:00:00

  • Characterization of salinity-enhanced toxicity of aldicarb to Japanese medaka: sexual and developmental differences.

    abstract::The effects of salinity, gender, and development on the acute toxicity of aldicarb were examined in the euryhaline fish, Japanese medaka (Oryzias latipes). The 96-h median lethal concentrations (LC50s) at 1.5 parts per thousand (per thousand) salinity were not significantly different between adults and juveniles but l...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:

    authors: El-Alfy AT,Grisle S,Schlenk D

    更新日期:2001-09-01 00:00:00

  • Toxicological Evaluation and Quantification of Ingested Metal-Core Nanoplastic by Daphnia magna Through Fluorescence and Inductively Coupled Plasma-Mass Spectrometric Methods.

    abstract::There are few studies on nanoplastic that propose quantification of the amount ingested combined with evaluation of the toxic effects on aquatic organisms. We propose 2 methods to quantify the amount of polystyrene nanoplastic (PSNP) ingested by Daphnia magna: fluorescence intensity, where a fluorescent monomer (F) is...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.4528

    authors: Vicentini DS,Nogueira DJ,Melegari SP,Arl M,Köerich JS,Cruz L,Justino NM,Oscar BV,Puerari RC,da Silva MLN,Simioni C,Ouriques LC,Matias MS,de Castilhos Junior AB,Matias WG

    更新日期:2019-10-01 00:00:00

  • Enhancement of aerobic microbial degradation of polychlorinated biphenyl in soil microcosms.

    abstract::This article reports the results of various biodegradation experiments on polychlorinated biphenyl (PCB)-contaminated sandy soil employing a mixed culture of acclimatized bacteria. Following the optimization of different variables without chemical pretreatment, the elimination rate achieved of Aroclor 1242 in slurry-p...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:

    authors: Manzano MA,Perales JA,Sales D,Quiroga JM

    更新日期:2003-04-01 00:00:00

  • Acute and chronic toxicity of nickel to rainbow trout (Oncorhynchus mykiss).

    abstract::Of the fish species tested in chronic Ni exposures, rainbow trout (Oncorhynchus mykiss) is the most sensitive. To develop additional Ni toxicity data and to investigate the toxic mode of action for Ni, we conducted acute (96-h) and chronic (85-d early life-stage) flow-through studies using rainbow trout. In addition t...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1897/03-38

    authors: Brix KV,Keithly J,DeForest DK,Laughlin J

    更新日期:2004-09-01 00:00:00

  • Nonlethal laparoscopic detection of intersex (testicular oocytes) in largemouth bass (Micropterus salmoides) and smallmouth bass (Micropterus dolomieu).

    abstract::Intersex in wild fish populations has received considerable attention in the scientific literature and public media. Conventional detection of testicular oocytes, the presence of immature oocytes within testis of male fish, commonly employs transverse sectioning of excised testis and is lethal. The present study used ...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.3716

    authors: MacLeod AH,Blazer VS,Matsche MA,Yonkos LT

    更新日期:2017-07-01 00:00:00

  • Improving substance information in USEtox® , part 2: Data for estimating fate and ecosystem exposure factors.

    abstract::The scientific consensus model USEtox® has been developed since 2003 under the auspices of the United Nations Environment Programme-Society of Environmental Toxicology and Chemistry Life Cycle Initiative as a harmonized approach for characterizing human and freshwater toxicity in life cycle assessment and other compar...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.3903

    authors: Saouter E,Aschberger K,Fantke P,Hauschild MZ,Kienzler A,Paini A,Pant R,Radovnikovic A,Secchi M,Sala S

    更新日期:2017-12-01 00:00:00

  • Inhibition of microbial metabolism in anaerobic lagoons by selected sulfonamides, tetracyclines, lincomycin, and tylosin tartrate.

    abstract::Antibiotics are used to maintain healthy livestock and to promote weight gain in concentrated animal feed operations. Antibiotics rarely are metabolized completely by livestock and, thus, are often present in livestock waste and in waste-treatment lagoons. The introduction of antibiotics into anaerobic lagoons commonl...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1897/04-093r.1

    authors: Loftin KA,Henny C,Adams CD,Surampali R,Mormile MR

    更新日期:2005-04-01 00:00:00

  • Species-specific metabolism of naphthalene and phenanthrene in 3 species of marine teleosts exposed to Deepwater Horizon crude oil.

    abstract::The 2 most abundant polycyclic aromatic hydrocarbons (PAHs) measured in Deepwater Horizon crude oil, naphthalene and phenanthrene, and their associated homologs have both been shown to be acutely toxic in fish. Although fish have a relatively high metabolic capacity for PAHs, hydroxylated PAH (OH-PAH) derivatives form...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.3898

    authors: Pulster EL,Main K,Wetzel D,Murawski S

    更新日期:2017-11-01 00:00:00

  • Simultaneous analysis of multiclass contaminants of emerging concern in sediments by liquid chromatography with tandem quadrupole mass spectrometry.

    abstract::A quick, easy, cheap, effective, rugged, and safe (QuEChERS)-based extraction and simultaneous dispersive solid-phase extraction (dSPE) clean-up method was developed for contaminants of emerging concern (CECs) in sediment samples. Hydration with a phosphate buffer (pH 2.0) and salting out with NaCl and MgSO4 facilitat...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.4450

    authors: Rashid A,Wang Y,Li Y,Yu CP,Sun Q

    更新日期:2019-07-01 00:00:00

  • Spatial variation of metals and acid volatile sulfide in floodplain lake sediment.

    abstract::In risk assessment of aquatic sediments, much attention is paid to the immobilizing effect of acid volatile sulfide (AVS) on trace metals. The difference of AVS and simultaneously extracted metals (SEM) gives an indication of metal availability. In floodplain sediments, where changing redox conditions occur, AVS may p...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:

    authors: van Griethuysen C,Meijboom EW,Koelmans AA

    更新日期:2003-03-01 00:00:00

  • Perfluorooctanesulfonic Acid-Induced Toxicity on Zebrafish Embryos in the Presence or Absence of the Chorion.

    abstract::Perfluorooctanesulfonic acid (PFOS) is a perfluorinated compound used in many industrial and consumer products. It has been linked to a broad range of adverse effects in several species, including zebrafish (Danio rerio). The zebrafish embryo is a widely used vertebrate model to elucidate potential adverse effects of ...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.4899

    authors: Mylroie JE,Wilbanks MS,Kimble AN,To KT,Cox CS,McLeod SJ,Gust KA,Moore DW,Perkins EJ,Garcia-Reyero N

    更新日期:2020-10-12 00:00:00

  • Concentrations of Metals in Fishes from the Athabasca and Slave Rivers of Northern Canada.

    abstract::There is growing concern about possible effects of exploitation of the Alberta Oil Sands on the ambient environment, including possible effects on populations of fishes in the Athabasca River and farther downstream in Lake Athabasca and the Slave River. In the present study, concentrations of metals in dorsal muscle t...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.4852

    authors: Tendler B,Ohiozebau E,Codling G,Giesy JP,Jones PD

    更新日期:2020-11-01 00:00:00

  • Intersex and liver alterations induced by long-term sublethal exposure to 17α-ethinylestradiol in adult male Cnesterodon decemmaculatus (Pisces: Poeciliidae).

    abstract::The aim of the present study was to assess the responses of the gonopodium morphology and the gonadal and liver histology of adult male Cnesterodon decemmaculatus to sublethal long-term exposure concentrations of 17α-ethinylestradiol (EE2). Two experiments were conducted exposing the fish to waterborne concentrations ...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.3547

    authors: Young BJ,López GC,Cristos DS,Crespo DC,Somoza GM,Carriquiriborde P

    更新日期:2017-07-01 00:00:00

  • Toxicity of fluoride to aquatic species and evaluation of toxicity modifying factors.

    abstract::The present study was performed to investigate the toxicity of fluoride to a variety of freshwater aquatic organisms and to establish whether water quality variables contribute substantively to modifying its toxicity. Water hardness, chloride, and alkalinity were tested as possible toxicity modifying factors for fluor...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.2963

    authors: Pearcy K,Elphick J,Burnett-Seidel C

    更新日期:2015-07-01 00:00:00

  • Sublethal toxicity of trace metals to larvae of the blacklip abalone, Haliotis rubra.

    abstract::The availability of literature regarding sublethal and chronic toxicity of heavy metals to early life stages of marine species is restricted to a few species of invertebrate mollusks. The early life stage of abalone, an important gastropod both environmentally and commercially, has been involved in limited research in...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1897/05-060r.1

    authors: Gorski J,Nugegoda D

    更新日期:2006-05-01 00:00:00

  • The effect of nitrobenzene on antioxidative enzyme activity and DNA damage in tobacco seedling leaf cells.

    abstract::Nitrobenzene, although widely used in industry, is a highly toxic environmental pollutant. To evaluate the toxicity of nitrobenzene to tobacco seedlings, seedlings were exposed to varying concentrations of nitrobenzene (0-100 mg/L) for 24 h. The contents of reactive oxygen species (hydrogen peroxide [H(2)O(2)] and sup...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.1920

    authors: Si L,Guo C,Cao Y,Cong W,Yuan Z

    更新日期:2012-09-01 00:00:00

  • Simultaneous exposure to chronic hypoxia and dissolved polycyclic aromatic hydrocarbons results in reduced egg production and larval survival in the sheepshead minnow (Cyprinodon variegatus).

    abstract::Estuarine fish in the northern Gulf of Mexico are exposed annually to hypoxic conditions. In addition to hypoxia, fish located throughout the northern Gulf of Mexico were potentially exposed to oil released during the Deepwater Horizon incident. Therefore, the interaction between oil exposure and hypoxia is worth inve...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.3207

    authors: Hedgpeth BM,Griffitt RJ

    更新日期:2016-03-01 00:00:00

  • Comparison of Alternative Methods for Bioaccumulation Assessment: Scope and Limitations of In Vitro Depletion Assays with Rainbow Trout and Bioconcentration Tests in the Freshwater Amphipod Hyalella azteca.

    abstract::Bioaccumulation assessment predominantly relies on the bioconcentration factor (BCF) as the sole decisive metric. The test guideline 305 by the Organisation for Economic Co-operation and Development (OECD) provides the standard procedure for deriving this in vivo fish BCF, which is not only expensive and labor-intensi...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.4791

    authors: Kosfeld V,Fu Q,Ebersbach I,Esser D,Schauerte A,Bischof I,Hollender J,Schlechtriem C

    更新日期:2020-09-01 00:00:00

  • Estrogenic potential of halogenated derivatives of nonylphenol ethoxylates and carboxylates.

    abstract::Halogenated derivatives of nonylphenol and of its alkylates are generated during drinking water disinfection and treatment procedures. In this paper we analyze the potential of these compounds to interact with the estrogen receptor and to activate hormone-regulated gene promoters. We used the recombinant yeast assay (...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1897/03-141

    authors: García-Reyero N,Requena V,Petrovic M,Fischer B,Hansen PD,Díaz A,Ventura F,Barceló D,Piña B

    更新日期:2004-03-01 00:00:00

  • A Petri Net Approach to Physiologically Based Toxicokinetic Modeling.

    abstract::Physiologically based toxicokinetic (PBTK) modeling enables researchers to predict internal tissue concentrations for various species exposed to exogenous compounds through different routes at varying concentrations without having to run in vivo experiments for each scenario. Parameters for the models may be gathered ...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.4390

    authors: Edhlund I,Lee C

    更新日期:2019-05-01 00:00:00

  • Endocrine-disrupting effect of the ultraviolet filter benzophenone-3 in zebrafish, Danio rerio.

    abstract::The chemical ultraviolet (UV) filter benzophenone-3 (BP-3) is suspected to be an endocrine disruptor based on results from in vitro and in vivo testing. However, studies including endpoints of endocrine adversity are lacking. The present study investigated the potential endocrine-disrupting effects of BP-3 in zebrafis...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.3129

    authors: Kinnberg KL,Petersen GI,Albrektsen M,Minghlani M,Awad SM,Holbech BF,Green JW,Bjerregaard P,Holbech H

    更新日期:2015-12-01 00:00:00

  • Fate of tributyltin in a created tidal wetland.

    abstract::The ability of Spartina alterniflora to degrade tributyltin (TBT) in contaminated dredge spoils was investigated in a created wetland at Little Creek Naval Amphibious Base in Norfolk, Virginia, USA. Concentrations of TBT up to 250 ng/g did not inhibit S. alterniflora growth over a 16-month period. Disappearance rates ...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:

    authors: Anderson BA,Unger MA,Moore KA

    更新日期:2002-06-01 00:00:00

  • Different behavior of tetracyclines and sulfonamides in sandy soils after repeated fertilization with liquid manure.

    abstract::Recently we showed that tetracyclines tend to persist and may accumulate in sandy soils after repeated fertilizations with liquid manure. We continued these field investigations from 2001 to 2003 and observed no further accumulation of tetracyclines in soil, but found that the average tetracycline concentration remain...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1897/04-182r.1

    authors: Hamscher G,Pawelzick HT,Höper H,Nau H

    更新日期:2005-04-01 00:00:00

  • Multigenerational acclimation of Daphnia magna to mercury: relationships between biokinetics and toxicity.

    abstract::We examined the effects of multigenerational exposure of mercury (Hg) on Hg toxicity and biokinetics in a population of Daphnia magna. After chronic Hg exposure at 3.8 microg Hg/L, the first generation (F0) adults had an elevated 24-h median lethal concentration (LC50) of Hg (76 microg/L) when compared to the control ...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1897/05-085r.1

    authors: Tsui MT,Wang WX

    更新日期:2005-11-01 00:00:00

  • Degradation rate of sodium fluoroacetate in three New Zealand soils.

    abstract::The degradation rate of sodium fluoroacetate (SFA) was assessed in a laboratory microcosm study incorporating 3 New Zealand soil types under different temperature (5 °C, 10 °C, or 20 °C) and soil moisture (35% or 60% water holding capacity) conditions using guideline 307 from the Organisation for Economic Co-operation...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.2536

    authors: Northcott G,Jensen D,Ying L,Fisher P

    更新日期:2014-05-01 00:00:00

  • Cumulative toxicity of neonicotinoid insecticide mixtures to Chironomus dilutus under acute exposure scenarios.

    abstract::Extensive agricultural use of neonicotinoid insecticide products has resulted in the presence of neonicotinoid mixtures in surface waters worldwide. Although many aquatic insect species are known to be sensitive to neonicotinoids, the impact of neonicotinoid mixtures is poorly understood. In the present study, the cum...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.3878

    authors: Maloney EM,Morrissey CA,Headley JV,Peru KM,Liber K

    更新日期:2017-11-01 00:00:00

  • Variation, replication, and power analysis of Myriophyllum spp. microcosm toxicity data.

    abstract::Myriophyllum spp. have been proposed as a new standard laboratory aquatic macrophyte test species for the registration of pesticides. The main objectives of this investigation were to determine the power of Myriophyllum sibiricum and Myriophyllum spicatum toxicity data derived from an outdoor microcosm bioassay, to ev...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:

    authors: Hanson ML,Sanderson H,Solomon KR

    更新日期:2003-06-01 00:00:00

  • Effects of a natural toxin on life history and gene expression of Eisenia andrei.

    abstract::Earthworms perform key functions for a healthy soil ecosystem, such as bioturbation. The soil ecosystem can be challenged by natural toxins such as isothiocyanates (ITCs), produced by many commercial crops. Therefore, the effects of 2-phenylethyl ITC were investigated on the earthworm Eisenia andrei using an ecotoxico...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.2446

    authors: van Ommen Kloeke AE,Gong P,Ellers J,Roelofs D

    更新日期:2014-02-01 00:00:00

  • Impact of herbicides on the abundance and structure of indigenous beta-subgroup ammonia-oxidizer communities in soil microcosms.

    abstract::In this study, mixtures of five herbicide-formulated products (atrazine, dicamba, fluometuron, metolachlor, and sulfentrazone) were applied to soil microcosm columns in increasing concentrations. The toxic impact of herbicides on the indigenous beta-subclass Proteobacteria autotrophic ammonia-oxidizer (beta-AAO) commu...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1897/1551-5028(2001)020<2462:iohota>2.0.co;2

    authors: Chang YJ,Hussain AK,Stephen JR,Mullen MD,White DC,Peacock A

    更新日期:2001-11-01 00:00:00