Differential Individual Particle Analysis (DIPA): applications in particulate matter characterization.

Abstract:

:Operator-controlled and computer-controlled scanning electron microscopy (CCSEM) are used extensively to characterize particulate matter in environmental media. Analysis in a scanning electron microscope (SEM) coupled with chemical extraction is a potentially powerful tool that is capable of determining how various sample components are associated at the individual particle level. This involves initial characterization in a SEM, after which the material is exposed to a liquid or gas phase reaction for a specified time, and once exposure is concluded, the particles are reanalyzed in the SEM. This particle analysis by difference, or differential individual particle analysis (DIPA), possesses considerable potential for describing the behavior of environmental particles under changing chemical conditions. Here we describe DIPA applications with illustrative examples drawn from the analysis of particulate matter modified by reactions in a fluid environment. In situ DIPA permits the same particles to be analyzed in the SEM before and after modification. Repeated exposure to the same, or different modifying conditions, provides information on the time dependence of specific reactions. Significant numbers of particles can be analyzed using CCSEM, and the same particles can be analyzed after the reaction by accurate sample relocation in the SEM. Ex situ DIPA, which involves a bulk sample modification, uses CCSEM to characterize significant numbers of particles pre- and postreaction. The CCSEM approach is extremely efficient; recent developments in silicon drift detectors have increased the speed of characteristic X-rays detection, and very large numbers of particles can be analyzed in a short period of time.

journal_name

J Environ Qual

authors

Hunt A,Johnson DL

doi

10.2134/jeq2010.0315

subject

Has Abstract

pub_date

2011-05-01 00:00:00

pages

742-50

issue

3

eissn

0047-2425

issn

1537-2537

journal_volume

40

pub_type

杂志文章
  • Modeling phosphorus transport in an agricultural watershed using the WEPP model.

    abstract::The Water Erosion Prediction Project (WEPP) model has been tested for its ability to predict soil erosion, runoff, and sediment delivery over a wide range of conditions and scales for both hillslopes and watersheds. Since its release in 1995, there has been considerable interest in adding a chemical transport element ...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:

    authors: Perez-Bidegain M,Helmers MJ,Cruse R

    更新日期:2010-11-01 00:00:00

  • Spatial extrapolation of soil characteristics using whole-soil particle size distributions.

    abstract::Soils support ecosystem functions such as plant growth and water quality because of certain physical, chemical, and biological properties. These properties have been studied at different spatial scales, including point scales to satisfy basic research needs, and regional scales to satisfy monitoring needs. Recently, s...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2001.301101x

    authors: Shirazi MA,Boersma L,Haggerty PK,Johnson CB

    更新日期:2001-01-01 00:00:00

  • Measurement and Modeling of Denitrification in Sand-Bed Streams under Various Land Uses.

    abstract::Although many studies have measured denitrification in stream sediments, few have utilized these data with local water column and sediment measurements to develop a predictive model for NO uptake. In this study, sediment denitrification was measured from cores in five streams under various land uses in south-central M...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2013.06.0249

    authors: Guentzel KS,Hondzo M,Badgley BD,Finlay JC,Sadowsky MJ,Kozarek JL

    更新日期:2014-05-01 00:00:00

  • SOIL-SOILN simulations of water drainage and nitrate nitrogen transport from soil core lysimeters.

    abstract::Water resources protection from nitrate nitrogen (NO3-N) contamination is an important public concern and a major national environmental issue. The abilities of the SOIL-SOILN model to simulate water drainage and nitrate N fluxes from orchardgrass (Dactylis glomerata L.) were evaluated using data from a 3-yr field exp...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2001.302584x

    authors: Jabro JD,Stout WL,Fales SL,Fox RH

    更新日期:2001-03-01 00:00:00

  • Using the soil and water assessment tool to estimate dissolved inorganic nitrogen water pollution abatement cost functions in central portugal.

    abstract::Coastal aquatic ecosystems are increasingly affected by diffuse source nutrient water pollution from agricultural activities in coastal catchments, even though these ecosystems are important from a social, environmental and economic perspective. To warrant sustainable economic development of coastal regions, we need t...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2011.0400

    authors: Roebeling PC,Rocha J,Nunes JP,Fidélis T,Alves H,Fonseca S

    更新日期:2014-01-01 00:00:00

  • Managing Beef Backgrounding Residual Soil Contaminants by Alum and Biochar Amendments.

    abstract::Heavy manure-derived contamination of soils can make animal congregating areas nonpoint sources for environmental pollution. In situ soil stabilization is a cost-effective management strategy with a focus on lowering contaminant availability and limiting release to the environment. Soil stabilizing amendments can help...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2018.02.0088

    authors: Netthisinghe AMP,Cook KL,Gilfillen RA,Woosley PB,Kingery T,Sistani KR

    更新日期:2018-09-01 00:00:00

  • Reduction of odorants in swine manure by carbohydrate and bacterial amendments.

    abstract::Malodors from pig manure storage pits are a problem lacking a cost-efficient solution particularly for small pig (Sus domestica) farms. The objective of this study was to reduce emissions of noxious odorants by changing the conditions in the pig manure to favor an altered microbial community. Sugars (maltose, lactose,...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2008.0530

    authors: Nykänen AM,Hämäläinen N,Kostia S,Mikola J,Romantschuk M

    更新日期:2010-02-19 00:00:00

  • Assessment of the sulfur hexafluoride (SF6) tracer technique for measuring enteric methane emissions from cattle.

    abstract::A commonly used method of measuring enteric methane (CH4) emissions from ruminants is the SF6 tracer technique that measures respired and eructated CH4. However, within the animal, a small proportion of CH4 is produced post-ruminally and some of this may escape through the rectum. The comparison of emissions using a c...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2006.0054

    authors: McGinn SM,Beauchemin KA,Iwaasa AD,McAllister TA

    更新日期:2006-08-09 00:00:00

  • Nitrate and sediment fluxes from a California rangeland watershed.

    abstract::Long-term water quality records for assessing natural variability, impact of management, and that guide regulatory processes to safeguard water resources are rare for California oak woodland rangelands. This study presents a 20-yr record (1981-2000) of nitrate-nitrogen (NO(3)-N) and suspended sediment export from a ty...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2006.0042

    authors: Lewis DJ,Singer MJ,Dahlgren RA,Tate KW

    更新日期:2006-10-27 00:00:00

  • Moisture Effects on Nitrogen Availability in Municipal Biosolids from End-of-Life Municipal Lagoons.

    abstract::Nitrogen (N) availability affects plant biomass yield and, hence, phytoextraction of contaminants during phytoremediation of end-of-life municipal lagoons. End-of-life lagoons are characterized by fluctuating moisture conditions, but the effects on biosolid N dynamics have not been adequately characterized. This 130-d...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2015.02.0084

    authors: Jeke NN,Zvomuya F,Ross L

    更新日期:2015-11-01 00:00:00

  • Cadmium concentrations in new zealand pastures: relationships to soil and climate variables.

    abstract::Cadmium (Cd) is a nonessential element that occurs at above-background concentrations in many New Zealand (NZ) soils. Most of this Cd is due to the historical application of single superphosphate that was made from Nauru phosphate rock containing between 400 and 600 mg Cd kg P. Pasture Cd uptake exacerbates the entry ...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2013.09.0367

    authors: Reiser R,Simmler M,Portmann D,Clucas L,Schulin R,Robinson B

    更新日期:2014-05-01 00:00:00

  • Water quality changes in a polluted stream over a twenty-five-year period.

    abstract::The Deckers Creek watershed in northern West Virginia (USA), containing a land area of 166 km2 (63 mi2), has a long history of industrial development and attendant environmental abuses from both land and water pollution practices. The water in Deckers Creek was sampled in 1974 at 29 locations along the main stem and r...

    journal_title:Journal of environmental quality

    pub_type: 历史文章,杂志文章

    doi:10.2134/jeq2003.6540

    authors: Stewart J,Skousen J

    更新日期:2003-03-01 00:00:00

  • Temperature and freezing effects on phosphorus release from soils to overlying floodwater under flooded-anaerobic conditions.

    abstract::Increased phosphorus (P) availability under flooded, anaerobic conditions may accelerate P loss from soils to water bodies. Existing knowledge on P release to floodwater from flooded soils is limited to summer conditions and/or room temperatures. Spring snowmelt runoff, which occurs under cold temperatures with freque...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.1002/jeq2.20062

    authors: Kumaragamage D,Concepcion A,Gregory C,Goltz D,Indraratne S,Amarawansha G

    更新日期:2020-05-01 00:00:00

  • Modeling of phosphorus loads in sugarcane in a low-relief landscape using ontology-based simulation.

    abstract::Water flow and P dynamics in a low-relief landscape manipulated by extensive canal and ditch drainage systems were modeled utilizing an ontology-based simulation model. In the model, soil water flux and processes between three soil inorganic P pools (labile, active, and stable) and organic P are represented as databas...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2009.0509

    authors: Kwon HY,Grunwald S,Beck HW,Jung Y,Daroub SH,Lang TA,Morgan KT

    更新日期:2010-09-01 00:00:00

  • Rye cover crop and gamagrass strip effects on NO3 concentration and load in tile drainage.

    abstract::A significant portion of the NO3 from agricultural fields that contaminates surface waters in the Midwest Corn Belt is transported to streams or rivers by subsurface drainage systems or "tiles." Previous research has shown that N fertilizer management alone is not sufficient for reducing NO3 concentrations in subsurfa...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2006.0468

    authors: Kaspar TC,Jaynes DB,Parkin TB,Moorman TB

    更新日期:2007-08-31 00:00:00

  • Seasonal Differences in Relationships between Nitrate Concentration and Denitrification Rates in Ditch Sediments Vegetated with Rice Cutgrass.

    abstract::Increased application of nitrogen (N) fertilizers in agricultural systems contributes to significant environmental impacts, including eutrophication of fresh and coastal waters. Rice cutgrass [ (L.) Sw.] can significantly enhance denitrification potential in agricultural ditch sediments and potentially reduce N export...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2016.11.0450

    authors: Speir SL,Taylor JM,Scott JT

    更新日期:2017-11-01 00:00:00

  • Imidacloprid movement in soils and impacts on soil microarthropods in southern Appalachian eastern hemlock stands.

    abstract::Imidacloprid is a systemic insecticide effective in controlling the exotic pest (hemlock woolly adelgid) in eastern hemlock () trees. Concerns over imidacloprid impacts on nontarget species have limited its application in southern Appalachian ecosystems. We quantified the movement and adsorption of imidacloprid in fo...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2011.0306

    authors: Knoepp JD,Vose JM,Michael JL,Reynolds BC

    更新日期:2012-03-01 00:00:00

  • Validation of Sensor-Directed Spatial Simulated Annealing Soil Sampling Strategy.

    abstract::Soil spatial variability has a profound influence on most agronomic and environmental processes at field and landscape scales, including site-specific management, vadose zone hydrology and transport, and soil quality. Mobile sensors are a practical means of mapping spatial variability because their measurements serve ...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2015.09.0458

    authors: Scudiero E,Lesch SM,Corwin DL

    更新日期:2016-07-01 00:00:00

  • Assessing selenium contamination in the irrigated stream-aquifer system of the Arkansas River, Colorado.

    abstract::Prudent interventions for reducing selenium (Se) in groundwater and streams within an irrigated river valley must be guided by a sound understanding of current field conditions. An emerging picture of the nature of Se contamination within the Lower Arkansas River Valley in Colorado is provided by data from a large num...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2008.0499

    authors: Gates TK,Cody BM,Donnelly JP,Herting AW,Bailey RT,Mueller Price J

    更新日期:2009-10-29 00:00:00

  • Nitrate Leaching in a Loamy Sand Soil Receiving Two Rates of Liquid Hog Manure and Fertilizer.

    abstract::The effect of liquid hog manure (LHM) and commercial fertilizer on NO-N leaching was measured for 2 yr in a long-term manure experiment on a loamy sand soil at Carberry, MB. The field experiment, sown to barley ( L.) and wheat ( L.), comprised six treatments including two rates of LHM (28, 084 and 56,168 L ha [2500 an...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2017.08.0333

    authors: Karimi R,Akinremi W

    更新日期:2018-05-01 00:00:00

  • Potential mineralization of four herbicides in a ground water--fed wetland area.

    abstract::Herbicides may leach from agricultural fields into ground water feeding adjacent wetlands. However, only little is known of the fate of herbicides in wetland areas. The purpose of the study was to examine the potential of a riparian fen to mineralize herbides that could leach from an adjacent catchment area. Slurries ...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2001.30124x

    authors: Larsen L,Jørgensen C,Aamand J

    更新日期:2001-01-01 00:00:00

  • Spring to summer nitrogen level in a brackish lake is higher in abundant snowmelt years: Correlation and causation.

    abstract::Eutrophication is an issue of concern in many brackish lakes with an agricultural watershed. The amount of snowfall in snowy areas is anticipated to decline because of global climate change. The aim of this study was to assess the impact of changes in the inflow of snowmelt on the nutrient concentrations of a downstre...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.1002/jeq2.20033

    authors: Shizuka K,Maie N,Nagasaki M,Kakino W,Tanji H

    更新日期:2020-01-01 00:00:00

  • Controls of Chloride Loading and Impairment at the River Network Scale in New England.

    abstract::Chloride contamination of rivers due to nonpoint sources is increasing throughout developed temperate regions due to road salt application in winter. We developed a river-network model of chloride loading to watersheds to estimate road salt application rates and investigated the meteorological factors that control riv...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2017.11.0418

    authors: Zuidema S,Wollheim WM,Mineau MM,Green MB,Stewart RJ

    更新日期:2018-07-01 00:00:00

  • Photodegradation of the endocrine-disrupting chemical 4-nonylphenol in biosolids applied to soil.

    abstract::There is increasing concern about the environmental fate and impact of biosolids-associated anthropogenic organic chemicals, among which 4-nonylphenol (4-NP) is one of the most studied chemicals. This is primarily because 4-NP is an endocrine disruptor and has been frequently detected in environmental samples. Due to ...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2004.1568

    authors: Xia K,Jeong CY

    更新日期:2004-07-01 00:00:00

  • Studies on mobility and degradation pathways of terbuthylazine using lysimeters on a field scale.

    abstract::Terbuthylazine [N2-tert-butyl-6-chloro-N4-ethyl-1,3,5-triazine-2,4-diamine] degradation pathways in agricultural soils were evaluated by following the appearance and mobility of its main transformation products: dealkylated and hydroxylated derivatives. Three experimental degradation studies in open field were perform...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2003.1089

    authors: Guzzella L,Rullo S,Pozzoni F,Giuliano G

    更新日期:2003-05-01 00:00:00

  • System dynamics modeling of nitrogen removal in a stormwater infiltration basin with biosorption-activated media.

    abstract::Stormwater infiltration basins, one of the typical stormwater best management practices, are commonly constructed for surface water pollution control, flood mitigation, and groundwater restoration in rural or residential areas. These basins have soils with better infiltration capacity than the native soil; however, th...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2012.0504

    authors: Xuan Z,Chang NB,Wanielista MP,Williams ES

    更新日期:2013-07-01 00:00:00

  • Manure composition and incorporation effects on phosphorus in runoff following corn biomass removal.

    abstract::Greater demand for corn ( L.) stover for bioenergy use may lead to increased corn production acreage with minimal surface residue cover, resulting in greater risk for soil erosion and phosphorus (P) losses in runoff. A rainfall simulation study was conducted to determine the effects of spring-applied dairy cow () manu...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2010.0505

    authors: Yagüe MR,Andraski TW,Laboski CA

    更新日期:2011-11-01 00:00:00

  • Approaches for quantifying and managing diffuse phosphorus exports at the farm/small catchment scale.

    abstract::Quantifying and managing diffuse P losses from small catchments or at the farm scale requires detailed knowledge of farming practices and their interaction with catchment processes. However, detailed knowledge may not be available and hence modeling is required. This paper demonstrates two approaches to developing too...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2007.0651

    authors: McDowell RW,Nash D,George A,Wang QJ,Duncan R

    更新日期:2009-08-24 00:00:00

  • X-Ray Fluorescence to Estimate the Maximum Temperature Reached at Soil Surface during Experimental Slash-and-Burn Fires.

    abstract::An important aspect for the evaluation of fire effects in slash-and-burn agricultural system, as well as in wildfire, is the soil burn severity. The objective of this study is to estimate the maximum temperature reached in real soil burn events using energy dispersive X-ray fluorescence (EDXRF) as an analytical tool, ...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2015.06.0305

    authors: Melquiades FL,Thomaz EL

    更新日期:2016-05-01 00:00:00

  • Near-field dust exposure from cotton field tilling and harvesting.

    abstract::The frequency and intensities of dust exposures in and near farm fields, which potentially contribute to high intensity human exposure events, are undocumented due to the transient nature of local dust plumes and the difficulties of making accurate concentration measurements. The objective of this study is to measure ...

    journal_title:Journal of environmental quality

    pub_type: 杂志文章

    doi:10.2134/jeq2006.0408

    authors: Hiscox AL,Miller DR,Holmén BA,Yang W,Wang J

    更新日期:2008-03-01 00:00:00