Toxicity removal assessments related to degradation pathways of azo dyes: Toward an optimization of Electro-Fenton treatment.

Abstract:

:The degradation pathway of Acid Orange 7 (AO7) by Electro-Fenton process using carbon felt cathode was investigated via HPLC-UV and LC-MS, IC, TOC analysis and bioassays (Vibrio Fischeri 81.9% Microtox(®) screening tests). The TOC removal of AO7 reached 96.2% after 8 h treatment with the optimal applied current density at -8.3 mA cm(-2) and 0.2 mM catalyst concentration. The toxicity of treated solution increased rapidly to its highest value at the early stage of electrolysis (several minutes), corresponding to the formation of intermediate poisonous aromatic compounds such as 1,2-naphthaquinone (NAPQ) and 1,4-benzoquinone (BZQ). Then, the subsequent formation of aliphatic short-chain carboxylic acids like acetic acid, formic acid, before the complete mineralization, leaded to a non-toxic solution after 270 min for 500 mL of AO7 (1 mM). Moreover, a quantitative analysis of inorganic ions (i.e. ammonium, nitrate, sulfate) produced during the course of degradation could help to verify molar balance with regard to original nitrogen and sulfur elements. To conclude, a clear degradation pathway of AO7 was proposed, and could further be applied to other persistent pharmaceuticals in aquatic environment.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Le TXH,Nguyen TV,Yacouba ZA,Zoungrana L,Avril F,Petit E,Mendret J,Bonniol V,Bechelany M,Lacour S,Lesage G,Cretin M

doi

10.1016/j.chemosphere.2016.06.108

subject

Has Abstract

pub_date

2016-10-01 00:00:00

pages

308-318

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(16)30879-7

journal_volume

161

pub_type

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