Mercury speciation and dispersion from an active gold mine at the West Wits area, South Africa.

Abstract:

:Total mercury (HgTOT), inorganic mercury (IHg), and methylmercury (MHg) were determined in dry season waters, sediments, and tailings from an active mine which has long history of gold exploitation. Although HgTOT in waters was generally low (0.03 to 19.60 ng L(-1)), the majority of the samples had proportions of MHg of at least 90 % of HgTOT which denotes a substantial methylation potential of the mine watersheds. Mercury was relatively high in tailing materials (up to 867 μg kg(-1)) and also in the mine sediments (up to 837 μg kg(-1)) especially in samples collected near tailing storage facilities and within a receiving water dam. Sediment profiles revealed mercury enrichment and enhanced methylation rate at deeper layers. The presence of IHg and decaying plants (organic matter) in the watersheds as well as the anoxic conditions of bulk sediments are believed to be some of the key factors favoring the mercury methylation at the site.

journal_name

Environ Monit Assess

authors

Lusilao-Makiese JG,Tessier E,Amouroux D,Tutu H,Chimuka L,Weiersbye I,Cukrowska EM

doi

10.1007/s10661-015-5059-4

subject

Has Abstract

pub_date

2016-01-01 00:00:00

pages

47

issue

1

eissn

0167-6369

issn

1573-2959

pii

10.1007/s10661-015-5059-4

journal_volume

188

pub_type

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