Evaluation of lead recovery efficiency from waste CRT funnel glass by chlorinating volatilization process.

Abstract:

:The current study was carried out to develop a novel process, namely chloride volatilization procedure for lead recovery from waste cathode ray tube (CRT) funnel glass. In the recovery system, the glass powder was first compressed into cylindrical pellet homogeneously with chlorinating agents, and then subjected to thermal treatment for solid-phase reaction. In this case, lead could be easily released from the silicon oxide network of the glass and it was recovered in the form of PbCl₂. It was found that CaCl2 was the most effective chlorinating agent, and the optimum operation temperature, holding time and system pressure were 1000 °C, 2 h, 600 ± 50 Pa, respectively. The evaporated PbCl₂could be easily recovered by a cooling device. The evaporation ratio of lead from waste CRT was 99.1% and the purity of the recovered PbCl₂product was 97.0%. The reaction routes and lead recovery mechanisms of the process were identified. This study provides an efficient and practical process for waste CRT funnel glass detoxification and recycling.

journal_name

Environ Technol

journal_title

Environmental technology

authors

Erzat A,Zhang FS

doi

10.1080/09593330.2014.921731

subject

Has Abstract

pub_date

2014-11-01 00:00:00

pages

2774-80

issue

21-24

eissn

0959-3330

issn

1479-487X

journal_volume

35

pub_type

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