Characterization of hydrocarbon contaminated areas by multivariate statistical analysis: Case studies.

Abstract:

:Analysis of soil gases is a relatively rapid and inexpensive method to delineate and measure hydrocarbon contamination in the subsurface caused by diesel or gasoline. Techniques originally developed for petroleum exploration have been adapted to tracking hydrocarbons which have leaked or spilled at or below the earth's surface.Discriminant analysis (a multivariate statistical technique) is used to classify soil gas samples of C1 to C7 hydrocarbons as biogenic (natural soil gases) or thermogenic (contaminant hydrocarbons). Map plots of C1 to C7 total interstitial hydrocarbons, C2 to C7 interstitial hydrocarbons, and C1/ΣC n rations are used to further delineate and document the extent and migration of contamination.Three case studies of the technique are presented: each involves leakage of hydrocarbons from underground storage tanks. Soil gas analysis clearly defines the spread of contamination and can serve as the basis for the correct placement of monitoring wells. The method proved to be accurate, rapid, and cost-effective; it therefore has potential for widespread application to the identification of soil and groundwater contaminated by hydrocarbons.

journal_name

Environ Monit Assess

authors

Saenz G,Pingitore NE

doi

10.1007/BF00399309

subject

Has Abstract

pub_date

1991-01-01 00:00:00

pages

281-302

issue

2-3

eissn

0167-6369

issn

1573-2959

journal_volume

17

pub_type

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