Determination of nitrobenzene in wastewater using a hanging mercury drop electrode.

Abstract:

:The determination of trace amount nitrobenzene in wastewater on a hanging mercury drop electrode was studied. The determination conditions of pH, supporting electrolyte, accumulation potential, accumulation time, and voltammetric response were optimized. The sharp peak of the nitrobenzene was appeared at 0.05 V. The peak electric current was proportional to the concentration of nitrobenzene in the range of 1.47 x 10(-5) approximately 1.0 x 10(-3) mol/l with relative standard deviations of 3.99 approximately 8.94%. The detection limit of the nitrobenzene in water was 5 x 10(-6) mol/l. The proposed method offered low limit of determination, easy operation, the use of simple instrumentation, high sensitivity and good reproducibility. It was applied to the determination of nitrobenzene in wastewater with an average recovery of 94.0% approximately 105%. The proposed method provided fast, sensitive and sometimes real time detection of nitrobenzene.

journal_name

Environ Monit Assess

authors

Liang SX,Zhang HK,Lu D

doi

10.1007/s10661-006-9366-7

subject

Has Abstract

pub_date

2007-06-01 00:00:00

pages

331-7

issue

1-3

eissn

0167-6369

issn

1573-2959

journal_volume

129

pub_type

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