A rapid extractive spectrophotometric determination of copper(II) in environmental samples, alloys, complexes and pharmaceutical samples using 4-[N,N(dimethyl)amino]benzaldehyde thiosemicarbazone.

Abstract:

:4-[N,N-(Dimethyl)amino]benzaldehyde thiosemicarbazone (DMABT) is proposed as an analytical reagent for the extractive spectrophotometric determination of copper(II). DMABT forms yellow colored complex with copper(II) in the pH range 4.4-5.4. Beer's law is obeyed in the concentration range up to 4.7 μg mL(-1). The optimum concentration range for minimum photometric error as determined by Ringbom plot method is 1.2-3.8 μg mL(-1). The yellowish Cu(II)-DMABT complex shows a maximum absorbance at 420 nm, with molar absorptivity of 1.72 × 10(4)dm(3) mol(-1) cm(-1) and Sandell's sensitivity of the complex obtained from Beer's data is 0.0036 μg cm(-2). The composition of the Cu(II)-DMABT complex is found to be 1:2 (M/L). The interference of various cations and anions in the method were studied. Thus the method can be employed for the determination of trace amount of copper(II) in water, alloys and other natural samples of significant importance.

journal_name

Environ Monit Assess

authors

Karthikeyan J,Naik PP,Shetty AN

doi

10.1007/s10661-010-1593-2

subject

Has Abstract

pub_date

2011-05-01 00:00:00

pages

419-26

issue

1-4

eissn

0167-6369

issn

1573-2959

journal_volume

176

pub_type

杂志文章
  • Temporal changes of soil respiration under different tree species.

    abstract::Soil respiration rates were measured monthly (from April 2007 to March 2008) under four adjacent coniferous plantation sites [Oriental spruce (Picea orientalis L.), Austrian pine (Pinus nigra Arnold), Turkish fir (Abies bornmulleriana L.), and Scots pine (Pinus sylvestris L.)] and adjacent natural Sessile oak forest (...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-012-2795-6

    authors: Akburak S,Makineci E

    更新日期:2013-04-01 00:00:00

  • Strategies for the use of mixed-effects models in continuous forest inventories.

    abstract::Forest inventory data often consists of measurements taken on field plots as well as values predicted from statistical models, e.g., tree biomass. Many of these models only include fixed-effects parameters either because at the time the models were established, mixed-effects model theory had not yet been thoroughly de...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-016-5252-0

    authors: Westfall JA

    更新日期:2016-04-01 00:00:00

  • Effect of long-term application of treated sewage water on heavy metal accumulation in vegetables grown in northern India.

    abstract::Use of industrial and wastewater for irrigation is on the rise in India and other developing countries because of scarcity of good-quality irrigation water. Wastewaters contain plant nutrients that favour crop growth but leave a burden of heavy metals which can enter the food chain and is a cause of great concern. The...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-011-2018-6

    authors: Ghosh AK,Bhatt MA,Agrawal HP

    更新日期:2012-01-01 00:00:00

  • Use of fuzzy logic models for prediction of taste and odor compounds in algal bloom-affected inland water bodies.

    abstract::Mechanistic modeling of how algal species produce metabolites (e.g., taste and odor compounds geosmin and 2-methyl isoborneol (2-MIB)) as a biological response is currently not well understood. However, water managers and water utilities using these reservoirs often need methods for predicting metabolite production, s...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-013-3471-1

    authors: Bruder S,Babbar-Sebens M,Tedesco L,Soyeux E

    更新日期:2014-03-01 00:00:00

  • On the estimation of phosphorus from the Niagara River to Lake Ontario.

    abstract::A predictive or model based approach to making inferences about the loading of a contaminant from a point source is presented and illustrated by estimating the total phosphorus, TP, loading from the Niagara River to Lake Ontario for the years 1967 to 1982. Information about explanatory variables and/or autodependence ...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/BF00394237

    authors: Thompson ME,El-Shaarawi AH

    更新日期:1989-11-01 00:00:00

  • Black carbon in urban topsoils of Xuzhou (China): environmental implication and magnetic proxy.

    abstract::Combustion-derived black carbon has received attention as a form of refractory organic carbon that may be preferentially preserved in soils and sediments. However, little is understood about the environmental roles of black carbon in urban soils. This investigation represented the preliminary study to characterize bla...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-009-0814-z

    authors: Wang XS

    更新日期:2010-04-01 00:00:00

  • Evaluation of groundwater quality in a rural community in North Central of Nigeria.

    abstract::Evaluation of water quality of nine boreholes and three open hand-dug wells in a rural community in North Central Nigeria revealed relative abundance of cations Na > k > Ca > Mg > Zn > Pb and anions Cl(-) > PO4(2-) > SO4(2-) > NO3(-) in the boreholes and cations Ca > Na > K > Mg > Pb and anions NO3(-)  > PO4(2-)  > SO...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-016-5149-y

    authors: Sojobi AO

    更新日期:2016-03-01 00:00:00

  • Heavy metals in the SPM of air in the environment surrounding a ferro-alloy industrial plant in India.

    abstract::Prices for ferro-alloys have hardened due to the closure of plants in developed countries on account of increasingly stringent pollution control legislation, resulting in a higher cost of production. A ferro-alloy industry with a capacity of 80000 MT per annum was selected to study the nature of pollution. Because of ...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/BF00549132

    authors: Reddy MK,Venkat Rao D,Rama Rao KG,Rama Mohan Rao I,Vittal Rao M

    更新日期:1993-04-01 00:00:00

  • Sediment contamination, by habitat, in the Tampa Bay estuarine system (1993-1999): PAHs, pesticides and PCBs.

    abstract::More than 760 Tampa Bay (Florida, U.S.A.) sediment samples have been analyzed for organic contaminants (PAHs, organochlorine pesticides, and PCBs) since 1993. Data were analyzed to assess status by habitat (defined by overlapping salinity zones and sediment type). The habitats most degraded by PAHs and pesticides were...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1023/b:emas.0000009232.18889.37

    authors: Grabe SA,Barron J

    更新日期:2004-02-01 00:00:00

  • Dust events and their influence on aerosol optical properties over Jaipur in Northwestern India.

    abstract::In this study, we systematically document the link between dust episodes and local scale regional aerosol optical properties over Jaipur located in the vicinity of Thar Desert in the northwestern state of Rajasthan. The seasonal variation of AOT(500 nm) (aerosol optical thickness) shows high values (0.51 ± 0.18) durin...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-013-3103-9

    authors: Verma S,Payra S,Gautam R,Prakash D,Soni M,Holben B,Bell S

    更新日期:2013-09-01 00:00:00

  • Ecological-health risk assessment and bioavailability of potentially toxic elements (PTEs) in soil and plant around a copper smelter.

    abstract::Soil and the dominant plant species in the vicinity of Khatoon Abad copper smelter in Kerman province of Iran are examined to determine contamination, bioavailability, and ecological-health risk of potentially toxic elements (PTEs) based on 23 collected soil samples and 13 Artemisia siebri plant species. Cu, Mo, As, a...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-020-08589-4

    authors: Nematollahi MJ,Keshavarzi B,Zaremoaiedi F,Rajabzadeh MA,Moore F

    更新日期:2020-09-14 00:00:00

  • Performance of different composting techniques in reducing oestrogens content in manure from livestock in a Vietnamese setting.

    abstract::Steroid oestrogens (SE) are released by humans and animals into the environment. In the Mekong Delta animal excrement is directly discharged into surface water and can pollute the water. Only a few animal production sites are currently treating the excrement in either biogas plants or vermicomposting systems. The conc...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-012-2563-7

    authors: Le TA,Clemens J,Nguyen TH

    更新日期:2013-01-01 00:00:00

  • Integrating geospatial and ground geophysical information as guidelines for groundwater potential zones in hard rock terrains of south India.

    abstract::The increasing demand of water has brought tremendous pressure on groundwater resources in the regions were groundwater is prime source of water. The objective of this study was to explore groundwater potential zones in Maheshwaram watershed of Andhra Pradesh, India with semi-arid climatic condition and hard rock gran...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-011-2305-2

    authors: Rashid M,Lone MA,Ahmed S

    更新日期:2012-08-01 00:00:00

  • Assessment of spatial distribution of soil loss over the upper basin of Miyun reservoir in China based on RS and GIS techniques.

    abstract::Soil conservation planning often requires estimates of the spatial distribution of soil erosion at a catchment or regional scale. This paper applied the Revised Universal Soil Loss Equation (RUSLE) to investigate the spatial distribution of annual soil loss over the upper basin of Miyun reservoir in China. Among the s...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-010-1766-z

    authors: Chen T,Niu RQ,Wang Y,Li PX,Zhang LP,Du B

    更新日期:2011-08-01 00:00:00

  • Problems of correlation of global and local monitoring of air pollution.

    abstract::(1) The Air Polluttion Monitoring System has got a significant development of late, which is in direct relation with a considerable extention and improvement of the observation network in cities and industrial areas, with creation of a new network for assessing regional and global background of the atmosphere pollutio...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/BF00416697

    authors: Berlyand ME,Volberg NS,Lavrinenko RF,Rusina EN

    更新日期:1982-12-01 00:00:00

  • Sampling for landscape elements--a case study from Lower Saxony, Germany.

    abstract::The estimation of coverage, i.e., the proportion of the total area in a study region covered by a given target class, is essential to many aspects of environmental monitoring. We analyze and compare the efficiency of different sample-based approaches for the estimation of coverage of different land cover classes from ...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-013-3464-0

    authors: Fehrmann L,Seidel D,Krause B,Kleinn C

    更新日期:2014-03-01 00:00:00

  • Microbiological water quality of the Mfoundi River watershed at Yaoundé, Cameroon, as inferred from indicator bacteria of fecal contamination.

    abstract::Using the membrane filtration technique to count total coliform (TC), fecal coliform (FC) and fecal streptococci (FS), the microbiological water quality of the Mfoundi River and four of its representative tributaries at Yaoundé, Cameroon, was assessed for human use and contact. Sampling was conducted so as to examine ...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-005-9172-7

    authors: Djuikom E,Njine T,Nola M,Sikati V,Jugnia LB

    更新日期:2006-11-01 00:00:00

  • Meiofauna ratios as environmental indicators in the profundal depths of large lakes.

    abstract::Two sets of samples from Lake Päijänne and one from Lake Ladoga were used to examine the relations between the meiofauna and environmental variables. The most obvious indicators of an unpolluted environment were, in order of importance, the true meiofauna/total meiofauna ratio, the proportion of Aeolosomatidae, the pr...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/BF00414370

    authors: Särkkä J

    更新日期:1996-09-01 00:00:00

  • Evaluation of sampling strategies to characterize dissolved oxygen conditions in northern Gulf of Mexico estuaries.

    abstract::Dissolved oxygen was continuously monitored in eight sites of northern Gulf of Mexico estuaries in August, 1990. Monte Carlo analyses on subsamples of the data were used to evaluate several commonly used monitoring strategies. Monitoring strategies which involve single point sampling of dissolved oxygen may often misc...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/BF00545979

    authors: Summers JK,Engle VD

    更新日期:1993-02-01 00:00:00

  • Trace elements as tracers of environmental pollution in the canal sediments (alluvial formation of the Danube River, Serbia).

    abstract::The purpose of this study was to examine the levels of trace elements and to discuss the origin and mobility of these contaminants in the canal sediments (alluvial formation of the Danube River). The most significant fractions binding all of the studied elements were oxides and silicates. The high proportion of elemen...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-009-1044-0

    authors: Sakan SM,Dordević DS,Manojlović DD

    更新日期:2010-08-01 00:00:00

  • Soil characteristics and heavy metal accumulation by native plants in a Mn mining area of Guangxi, South China.

    abstract::Revegetation and ecological restoration of a Mn mineland are important concerns in southern China. To determine the major constraints for revegetation and select suitable plants for phytorestoration, pedological and botanical characteristics of a Mn mine in Guangxi, southern China were investigated. All the soils were...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-013-3535-2

    authors: Liu J,Zhang XH,Li TY,Wu QX,Jin ZJ

    更新日期:2014-04-01 00:00:00

  • Biogeochemical responses to nutrient inputs in a Cuban coastal lagoon: runoff, anthropogenic, and groundwater sources.

    abstract::Laguna Larga, a coastal lagoon in central Cuba, has been heavily altered by tourism infrastructure construction and sewage disposal. We hypothesize that this has decreased the circulation and caused eutrophication of the lagoon. To assess this, 12 bimonthly samplings were carried out in 2007-2008. Temperature, salinit...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-013-3316-y

    authors: González-De Zayas R,Merino-Ibarra M,Soto-Jiménez MF,Castillo-Sandoval FS

    更新日期:2013-12-01 00:00:00

  • Status and future of the forest health indicators program of the USA.

    abstract::For two decades, the US Department of Agriculture, Forest Service, has been charged with implementing a nationwide field-based forest health monitoring effort. Given its extensive nature, the monitoring program has been gradually implemented across forest health indicators and inventoried states. Currently, the Forest...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-010-1644-8

    authors: Woodall CW,Amacher MC,Bechtold WA,Coulston JW,Jovan S,Perry CH,Randolph KC,Schulz BK,Smith GC,Tkacz B,Will-Wolf S

    更新日期:2011-06-01 00:00:00

  • Applying parcel-specific land-use data for improved monitoring of semi-natural grassland in Denmark.

    abstract::A major obstacle to the conservation and management of semi-natural grassland (SNG) is the general lack of consistent and precise maps showing the extent and quality of this habitat type. SNG is related to, and influenced by, agricultural land use. Both intensive land use as well as a lack of extensive land use can re...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-012-2735-5

    authors: Levin G

    更新日期:2013-03-01 00:00:00

  • Behavior of pathogenic microbes in a treated wastewater reuse system and examination of new standards for the reuse of treated wastewater.

    abstract::We researched the behavior of pathogenic microbes in a treated wastewater reuse system to acquire knowledge for establishing new standards for the reuse of treated wastewater. Based on the results that showed occasional growth of total coliforms but barely any growth of Escherichia coli in the supply tank, we found th...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-006-9424-1

    authors: Tajima A,Sakurai K,Minamiyama M

    更新日期:2007-06-01 00:00:00

  • Temporal and spatial variability of instream indicator bacteria (Escherichia coli) and implications for water quality monitoring.

    abstract::Many water quality monitoring programs quantify Escherichia coli, an indicator of fecal contamination and potential sewage pollution. However, interpretation of E. coli data can be complex due to abiotic factors that influence its growth and mortality. The goal of this study was to quantify the variability of E. coli ...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-019-7930-1

    authors: Crosby SC,Spiller NC,Tietz KE,Cooper JR,Fraboni PJ

    更新日期:2019-11-13 00:00:00

  • Response of lake water quality to wastewater inputs from land-based fish farm located on Yuvarlakçay Creek in Köyceğiz-Dalyan Specially Protected Area, Turkey.

    abstract::Köyceğiz Lake is located in the south-western part of Turkey. The area between the Köyceğiz Lake and the Mediterranean Sea is covered with four small lakes and several canals. The surroundings of the lake, canals and forests have a great potential as a reproduction areas for Mediterranean Sea turtles (Caretta caretta)...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-008-0555-4

    authors: Taşeli BK

    更新日期:2009-10-01 00:00:00

  • Preparation and validation of gridded emission inventory of criteria air pollutants and identification of emission hotspots for megacity Delhi.

    abstract::Delhi is one of the many megacities struggling with punishing levels of pollution from industrial, residential, and transportation sources. Over the years, pollution abatement in Delhi has become an important constituent of state policies. In the past one decade a lot of policies and regulations have been implemented ...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-006-9400-9

    authors: Mohan M,Dagar L,Gurjar BR

    更新日期:2007-07-01 00:00:00

  • Assessing different sources of uncertainty in hydrological projections of high and low flows: case study for Omerli Basin, Istanbul, Turkey.

    abstract::This study investigates the assessment of uncertainty contribution in projected changes of high and low flows from parameterization of a hydrological model and inputs of ensemble regional climate models (RCM). An ensemble of climate projections including 15 global circulation model (GCM)/RCM combinations and two bias ...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/s10661-017-6059-3

    authors: Engin BE,Yücel I,Yilmaz A

    更新日期:2017-07-01 00:00:00

  • Reporting emissions of greenhouse gases in Canada.

    abstract::Non-carbon dioxide greenhouse gases are considered in "Canada's National Report on Climate Change: Actions to Meet Commitments Under the United Nations Framework Convention on Climate Change". By including all major greenhouse gases and their anthropogenic sources and sinks using best available science, the Report pro...

    journal_title:Environmental monitoring and assessment

    pub_type: 杂志文章

    doi:10.1007/BF00547181

    authors: Finlay P,Stobbs R

    更新日期:1994-05-01 00:00:00