Synthetic methyl- and dimethylalkanes : Kovats Indices, [(13)C]NMR and mass spectra of some methylpentacosanes and 2,X-dimethylheptacosanes.

Abstract:

:All possible isomeric mono-methylpentacosanes as well as 2,6-, 2,8-, 2,10-, 2,12-, and 2,14-dimethylheptacosane were synthesized. The [(13)C]NMR shifts and the Kovats indices were determined, and the relationship to separation of isomeric mixtures of insect cuticular waxes are discussed. When several homologous series of hydrocarbon isomeric mixtures are to be separated, it is not practical to attempt complete gas-chromatographic separation of all possible isomers. The mass spectra of the 2,X-dimethylheptacosanes are presented and discussed.

journal_name

J Chem Ecol

authors

George Pomonis J,Hakk H,Fatland CL

doi

10.1007/BF01012084

subject

Has Abstract

pub_date

1989-09-01 00:00:00

pages

2319-33

issue

9

eissn

0098-0331

issn

1573-1561

journal_volume

15

pub_type

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