Characterization of the products formed by the reaction of trichlorocyanuric acid with 2-propanol.

Abstract:

:We report a recent investigation into the death of a cat that was initially thought to involve intentionally burning the animal via the use of an ignitable liquid. The exposure of the animal to flame was ruled out. Instead, forensic investigation revealed the intentional mixing together of a common outdoor swimming pool chlorinator, trichlorocyanuric acid (TCCA), and 2-propanol (aka, isopropyl alcohol or rubbing alcohol). The reaction of these two chemicals resulted in the formation of cyanuric acid residue, hydrochloric acid, and the evolution of a significant volume of chlorine gas. Further alpha-chlorination side reactions also occurred between 2-propanol and TCCA to produce a variety of chlorinated 2-propanone species that were detected on the submitted evidence. The identification of the products of both the main reaction and the side reactions allowed the authors to determine what chemicals were originally mixed together by the culprit.

journal_name

J Forensic Sci

authors

Sandercock PM,Barnett JS

doi

10.1111/j.1556-4029.2009.01181.x

subject

Has Abstract

pub_date

2009-11-01 00:00:00

pages

1336-40

issue

6

eissn

0022-1198

issn

1556-4029

pii

JFO1181

journal_volume

54

pub_type

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