Effect of thermal treatments on chiral nematic cellulose nanocrystal films.

Abstract:

:The ability to manipulate the optical appearance of materials is essential in virtually all products and areas of technology. Structurally coloured chiral nematic cellulose nanocrystal (CNC) films proved to be an excellent platform to design optical appearance, as their response can be moulded by organising them in hierarchical architectures. Here, we study how thermal treatments influence the optical appearance of structurally coloured CNC films. We demonstrate that the CNCs helicoidal architecture and the chiral optical response can be maintained up to 250 °C after base treatment and cross-linking with glutaraldehyde, while, alternatively, an exposure to vacuum allows for the helicoidal arrangement to be further preserved up to 900 °C, thus producing aromatic chiral carbon. The ability to retain the helicoidal arrangement, and thus the visual appearance, in CNC films up to 250 °C is highly desirable for high temperature colour-based industrial applications and for passive colorimetric heat sensors. Similarly, the production of chiral carbon provides a new type of conductive carbon for electrochemical applications.

journal_name

Carbohydr Polym

journal_title

Carbohydrate polymers

authors

Guidetti G,Frka-Petesic B,Dumanli AG,Hamad WY,Vignolini S

doi

10.1016/j.carbpol.2021.118404

keywords:

["Carbonisation","Cellulose nanocrystals","Chiral carbon","Cross-linking","Photonic pigments","Thermal stability"]

subject

Has Abstract

pub_date

2021-11-15 00:00:00

pages

118404

eissn

0144-8617

issn

1879-1344

pii

S0144-8617(21)00791-8

journal_volume

272

pub_type

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