Abstract:
:This research study highlights the catalytic usage of hetero atoms doped and undoped biogenic carbon nano dots (BCNDs) in the reduction of Alizarine yellow R (AYR) dye. Hydrothermal route was followed to synthesize the eco-friendly and fluorescent undoped as well as, N, B & S doped BCNDs from Syzygium cumini (S. cumini) fruit extract. Synthesized BCNDs exhibited good fluorescent and optical properties. From the HR-TEM results, the sizes of the spherically shaped undoped, N, B & S doped BCNDs were found to be 4.75 nm, 4.31 nm, 4.07 nm & 3.96 nm respectively. XRD results highlighted their amorphous nature. Functional groups and elemental percentages were elucidated from the results of FT-IR, EDS and XPS. Graphitic texture of the BCNDs were explained from Raman spectroscopy results and SAED. Thermal stability of BCNDs was evident from the results of TGA analysis. Further, BCNDs were used as green catalyst in the reduction of Alizarine Yellow R (AYR) dye. Langmuir- Hinshelwood mechanism was applied to evaluate the catalytic influence of BCNDs on AYR dye.
journal_name
Spectrochim Acta A Mol Biomol Spectroscauthors
Dhanush C,Sethuraman MGdoi
10.1016/j.saa.2021.119920keywords:
["Alizarine yellow R (AYR) dye","Biogenic carbon nano dots (BCNDs)","Catalytic potency","Hydrothermal carbonization","Syzygium cumini fruit extract"]subject
Has Abstractpub_date
2021-11-05 00:00:00pages
119920eissn
1386-1425issn
1873-3557pii
S1386-1425(21)00496-0journal_volume
260pub_type
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