Abstract:
:Concentrations of dissolved metals (Cd, Cu, Ni, Mn and Zn) were determined for summer and winter, under low-flow conditions in Port Jackson, a microtidal, well-mixed estuary in south-east Australia. Mean concentrations of Cd (0.04+/-0.02 microg/l), Ni (0.86+/-0.40 microg/l), Mn (20.0+/-25 microg/l) and Zn (6.47+/-2.0 microg/l) were below water quality guidelines. Concentrations of Cu (1.68+/-0.37 microg/l), however, slightly exceeded recommended values. Dissolved Ni and Mn behaved mostly conservatively, whereas Cd, Cu and Zn showed mid-estuarine maxima. Peaks in Cd, Cu and Zn concentrations were located in the upper estuary, independent of the salinity and suspended particulate matter loading, and were consistent with anthropogenic inputs of metals in the estuary. Concentrations of dissolved Cu were highest in summer, whereas concentrations of Cd, Ni and Mn were significantly lower in summer than winter (P< or =0.05). The increase in temperature and biological activity during summer explained the seasonal variation. The sequence of log K(d) values (20-30 salinity) was Mn>Zn>Cu>Ni. These results give unique information concerning the contemporaneous distribution of dissolved trace metals in the Port Jackson estuary and they provide a data set against which the long-term contamination may be assessed.
journal_name
Mar Pollut Bulljournal_title
Marine pollution bulletinauthors
Hatje V,Apte SC,Hales LT,Birch GFdoi
10.1016/S0025-326X(03)00061-4subject
Has Abstractpub_date
2003-06-01 00:00:00pages
719-30issue
6eissn
0025-326Xissn
1879-3363pii
S0025-326X(03)00061-4journal_volume
46pub_type
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journal_title:Marine pollution bulletin
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journal_title:Marine pollution bulletin
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journal_title:Marine pollution bulletin
pub_type: 杂志文章
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更新日期:2011-04-01 00:00:00
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