Abstract:
:The pathway and ab initio direct kinetics of the decomposition 5-aminotetrazole (5-ATZ) to HN(3) and NH(2)CN was investigated. Reactant, products and transition state were optimized with MP2 and B3LYP methods using 6-311G** and aug-cc-pVDZ basis sets. The intrinsic reaction coordinate curve of the reaction was calculated using the MP2 method with 6-311G** basis set. The energies were refined using CCSD(T)/6-311G**. Rate constants were evaluated by conventional transition-state theory (CVT) and canonical variational transition-state theory (TST), with tunneling effect over 300 to 2,500 K. The results indicated that the tunneling effect and the variational effect are small for the calculated rate constants. The fitted three-parameter expression calculated using the CVT and TST methods are k(T) = 4.07 x 10(11) x T(0.84) x e((-2.42 x 10(4))/T)s(-1) and k(T) = 2.09 x 10(11) x T(0.89) x e((-2.36 x 10(4))/T)s(-1), respectively.
journal_name
J Mol Modeljournal_title
Journal of molecular modelingauthors
Zhang JG,Feng LN,Zhang SW,Zhang TL,Zheng HHdoi
10.1007/s00894-008-0290-3subject
Has Abstractpub_date
2008-05-01 00:00:00pages
403-8issue
5eissn
1610-2940issn
0948-5023journal_volume
14pub_type
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