Synthesis of coal fly ash supported MnO2 for the enhanced degradation of Acid Red 73 in the presence of peroxymonosulfate.

Abstract:

:In this study, coal fly ash supported MnO2 (CFA@MnO2) was synthesized as heterocatalyst for the activation of peroxymonosulfate to degrade Acid Red 73 (AR73). The synthesized catalyst was characterized by X-Ray Fluorescence Spectrometer (XRF), X-ray powder diffraction (XRD), Scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS) and Brunauer-Emmett-Teller (BET). The composite of CFA@MnO2 possesses a large surface area of 74.59 m2/g. In the catalytic experiment, CFA@MnO2 exhibits excellent catalytic performance with 99.13% AR73 removed within 40 min with a high kinetic rate constant of 0.124 min-1, 5.49 times higher than that of pure MnO2. The operating parameters of CFA@MnO2-based fenton catalytic system were discussed, including MnO2 loading, solution pH, PMS dosage and temperature. The catalyst maintained a relatively high removal rate (>85%) over 5 cycles and degradation intermediates are detected on the catalyst surface after cycled via XPS analysis. The degradation mechanism was investigated by quenching experiments and Electron Paramagnetic Resonance technology. The surface-bound ·OH and SO4·- are considered as the main active radicals in the degradation process. The composite of CFA@MnO2 provides a low-cost and efficient alternative for the catalytic oxidation of organic pollutants.

journal_name

Environ Technol

journal_title

Environmental technology

authors

Li X,Yi L,Zhu Q,Zhao L,Xu Y,Liu M,Liu T,Wu Q

doi

10.1080/09593330.2019.1620868

subject

Has Abstract

pub_date

2021-01-01 00:00:00

pages

81-92

issue

1

eissn

0959-3330

issn

1479-487X

journal_volume

42

pub_type

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