Abstract:
:New ionic liquids (ILs) involving increasing numbers of organic and inorganic ions are continuously being reported. We recently developed a new force field; in the present work, we applied that force field to investigate the structural properties of a few novel imidazolium-based ILs in aqueous mixtures via molecular dynamics (MD) simulations. Using cluster analysis, radial distribution functions, and spatial distribution functions, we argue that organic ions (imidazolium, deprotonated alanine, deprotonated methionine, deprotonated tryptophan) are well dispersed in aqueous media, irrespective of the IL content. Aqueous dispersions exhibit desirable properties for chemical engineering. The ILs exist as ion pairs in relatively dilute aqueous mixtures (10 mol%), while more concentrated mixtures feature a certain amount of larger ionic aggregates.
journal_name
J Mol Modeljournal_title
Journal of molecular modelingauthors
Chaban VV,Fileti EEdoi
10.1007/s00894-015-2783-1subject
Has Abstractpub_date
2015-09-01 00:00:00pages
236issue
9eissn
1610-2940issn
0948-5023journal_volume
21pub_type
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