Abstract:
:Metal fractionation provides information on mobility and stability of various metal species which can be used to evaluate the movement of such metals in soils. The effect of wastewater irrigation on the fractions, spatial distribution, and mobility of cadmium (Cd) and zinc (Zn) was investigated in five urban gardens in Kano, Nigeria. Concentration of total Zn in the surface soils (0-20 cm) ranged from 121 to 207 mg kg(- 1) while Cd concentration was 0.3-2.0 mg kg(- 1). Speciation of both heavy metals into seven operationally defined fractions indicated that the most reactive forms extracted with ammonium nitrate and ammonium acetate, also considered as the bioavailable fractions, accounted for 29-42% of total Cd and 22-54% of total Zn, respectively. The weakly bound fractions of Cd and Zn reached up to 50% of the total Cd and Zn concentrations in the soils. Such high proportions of labile Cd and Zn fractions are indicative of anthropogenic origins, arising from the application of wastewater for irrigation and municipal biosolids for soil fertility improvement. Thus, given the predominance of sandy soil textures, high concentrations of labile Cd and Zn in these garden soils represent a potential hazard for the redistribution and translocation of these metals into the food chain and aquifer.
journal_name
Environ Monit Assessjournal_title
Environmental monitoring and assessmentauthors
Abdu N,Agbenin JO,Buerkert Adoi
10.1007/s10661-011-2099-2subject
Has Abstractpub_date
2012-04-01 00:00:00pages
2057-66issue
4eissn
0167-6369issn
1573-2959journal_volume
184pub_type
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