An equilibrium and stability study of Δ(1)-pyrroline.

Abstract:

:Several properties of the compound 3,4-dihydro-2H-pyrrole(A1-pyrroline), which has been reported as a component of the male-produced Mediterranean fruit fly pheromone, have been determined by [(1)H]- and [(13)C]nuclear magnetic resonance spectroscopy. The stability of Δ(1)-pyrroline in several solvents and at moderately elevated temperatures has been investigated, and it has been established that it exists as both a monomer and trimer in solution. Although equilibrium studies indicate that the trimer is thermodynamically more stable than the monomer in solution, only the monomer was found in the vapor phase based on infrared analysis.

journal_name

J Chem Ecol

authors

Baker JD,Heath RR,Millar JG

doi

10.1007/BF00993232

subject

Has Abstract

pub_date

1992-09-01 00:00:00

pages

1595-602

issue

9

eissn

0098-0331

issn

1573-1561

journal_volume

18

pub_type

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