Microwave absorption enhancement of 2-dimensional CoZn/C@MoS2@PPy composites derived from metal-organic framework.

Abstract:

:Metal-organic framework (MOF) materials have caused widespread concerns in the field of microwave absorption, due to the unique microstructure and electronic state. Herein, the CoZn/C@MoS2@polypyrrole (PPy) composites were prepared through MOF self-template method. The MoS2 sheets and PPy shell incorporated for optimizing impedance matching of two-dimensional (2D) CoZn/C composites. The introduction of MoS2 sheets and PPy shell endowed the composites with enhanced microwave absorption. The as-prepared CoZn/C@MoS2@PPy composites showed a minimum reflection loss (RL) of -49.18 dB with the thickness of 1.5 mm. In addition, the effective absorption bandwidth (EAB, RL values exceeding -10 dB) covered 4.56 GHz, which showed greater performances than CoZn/C composites under a lower thickness (<2 mm). This work not only provides a facile route for fabricating MOF-derived carbon-based composites as microwave absorbers, but also broadens the application of MOF materials.

authors

Bi Y,Ma M,Liu Y,Tong Z,Wang R,Chung KL,Ma A,Wu G,Ma Y,He C,Liu P,Hu L

doi

10.1016/j.jcis.2021.04.137

keywords:

["Impedance matching","Metal organic frameworks","Microwave absorption","Polypyrrole"]

subject

Has Abstract

pub_date

2021-10-15 00:00:00

pages

209-218

eissn

0021-9797

issn

1095-7103

pii

S0021-9797(21)00656-1

journal_volume

600

pub_type

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