Iridoid glycosides from Gmelina philippensis.

Abstract:

:Six new iridoids, 6-O-alpha-L-(2"-O-, 3"-O-, 4"-O-tribenzoyl)rhamnopyranosylcatalpol, 6-O-alpha-L-(2"-O-, 3"-O-dibenzoyl, 4"-O-cis-p-coumaroyl)rhamnopyranosylcatalpol, 6-O-alpha-L-(2"-O-, 3"-O-dibenzoyl, 4"-O-trans-p-coumaroyl)rhamnopyranosylcatalpol, 6-O-alpha-L-(2"-O-benzoyl, 3"-O-trans-p-coumaroyl)rhamnopyranosylcatalpol, 6-O-alpha-L-(2"-O-, 3"-O-dibenzoyl)rhamnopyranosylcatalpol, and gmephiloside as well as five known monoacyl and diacyl rhamnopyranosylcatalpol derivatives were isolated from the aerial parts of Gmelina philippensis. Their structures were established by spectroscopic means. Additionally, the known iridoids catalpol, geniposidic acid, gardoside, and 8-epi-loganic acid were identified and quantified by GC and GC-MS. The taxonomic significance of rhamnopyranosylcatalpol derivatives and iridoid acids as chemical characters is discussed.

journal_name

Phytochemistry

journal_title

Phytochemistry

authors

Helfrich E,Rimpler H

doi

10.1016/s0031-9422(00)00060-1

subject

Has Abstract

pub_date

2000-05-01 00:00:00

pages

191-9

issue

2

eissn

0031-9422

issn

1873-3700

pii

S0031-9422(00)00060-1

journal_volume

54

pub_type

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