Abstract:
:The interaction of the vanadyl (IV) cation with N-acetyl-D-galactosamine, D-galactosamine, and D-glucuronic acid has been investigated by electron absorption spectroscopy at different metal to ligand ratios and pH values. In the case of D-glucuronic acid, a more detailed study was undertaken, using differential IR spectroscopy in solution. The results show that the cation interacts with the two nitrogenated molecules only at higher pH values, generating 2:1 ligand to metal complexes in which coordination occurs through two pairs of deprotonated OH groups of the rings. In the case of D-glucuronic acid, the IR-measurements allowed a wider insight into the structural characteristics of the complexes generated in acidic media. The involvement of the glycosidic oxygen atom in coordination, is suggested at pH = 3.
journal_name
Biol Trace Elem Resjournal_title
Biological trace element researchauthors
Etcheverry SB,Williams PA,Baran EJdoi
10.1007/BF02785436subject
Has Abstractpub_date
1996-02-01 00:00:00pages
169-76issue
2eissn
0163-4984issn
1559-0720journal_volume
51pub_type
杂志文章abstract::Copper (Cu) and zinc (Zn) are involved in inflammatory process. This study was to investigate the clinical significance of Cu and Zn homeostasis alterations in acute appendicitis (AA). One hundred twenty-two AA patients and 102 healthy controls were enrolled in this study. Of which, 85 patients' appendixes were collec...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/s12011-019-01661-2
更新日期:2019-12-01 00:00:00
abstract::The effects of dietary sodium selenite and vitamin E on the microvascular permeability of rat organs such as heart, brain, kidney, liver and eye were investigated by using the Evans blue leakage method. Combined deficiency of selenium and vitamin E caused an increase in the permeability of the heart and eye with respe...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/BF02783332
更新日期:1998-07-01 00:00:00
abstract::The present study investigated the role of kisspeptin-10 on reproductively significant trace elements in relation to testosterone release in male rabbits, Oryctolagus cuniculus. Groups of rabbits were exposed to single 1 μg kisspeptin dose (i.v., saphenous vein), while simultaneous groups were pretreated with a kisspe...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/s12011-013-9720-x
更新日期:2013-08-01 00:00:00
abstract::Fluoride compounds are abundant and widely distributed in the environment at a variety of concentrations. Further, fluoride induces toxic effects in target organs such as the liver. In this study, we investigated liver histopathology, DNA damage, apoptosis, and the mRNA and protein expressions of caspase-3 and -9 in t...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/s12011-015-0265-z
更新日期:2015-08-01 00:00:00
abstract::Plasma zinc (Zn), copper (Cu), and magnesium (Mg) concentrations, copper/zinc ratio, and selenium (Se) status were studied in 44 vegetarians (22 males and 22 females) and their age- and sex-matched nonvegetarians in the Bratislava region (Slovakia). Vegetarians had statistically significant lower levels of plasma Zn a...
journal_title:Biological trace element research
pub_type: 临床试验,杂志文章
doi:10.1007/BF02789145
更新日期:1995-10-01 00:00:00
abstract::Cadmium (Cd) is a kind of toxic heavy metal and it can cause damage to organs and tissues. Selenium (Se) can antagonize some metal element toxicity including Cd. The present study was designed to investigate Cd-induced damage to chicken ovary by autophagy and the protective mechanism of Se on Cd-induced damage. Admini...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/s12011-018-1341-y
更新日期:2018-12-01 00:00:00
abstract::Guizhou black goats are essential to the production system in the Wumeng prairie in the Western China. This study aimed to determine the influence of nano-copper on antioxidant system in copper-deprived Guizhou black goats. We analyzed mineral contents in soil, forage, and goats' tissues. Blood parameters were also de...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/s12011-020-02342-1
更新日期:2020-08-18 00:00:00
abstract::This study assessed the effect of dietary selenium (Se) deficiency on male reproductive function in chicken. A total of 180 Hy-line laying cocks (1 day old; Weiwei) were randomly divided into 2 groups (n = 90) of Se-deficient chickens and control chickens. The control group was fed a basic diet (containing 0.15 mg of ...
journal_title:Biological trace element research
pub_type: 杂志文章,随机对照试验
doi:10.1007/s12011-015-0534-x
更新日期:2016-06-01 00:00:00
abstract::Cadmium (Cd) is an environmental toxicant and an inflammation-related xenobiotic. Selenium (Se) is a well-known nutritional trace element and a potent chemopreventive agent. The present study aimed to investigate the effect of Se on the cytotoxicity of Cd in bird immunocytes in vitro. Chicken splenic lymphocytes expos...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/s12011-015-0354-z
更新日期:2015-11-01 00:00:00
abstract::This in vitro study was designed to assess the impact of divalent (Fe(2+)) or trivalent (Fe(3+)) iron on the activity and oxidative balance of bovine spermatozoa at specific time intervals (0, 2, 8, 16, and 24 h) during an in vitro culture. Forty-five semen samples were collected from adult breeding bulls and diluted ...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/s12011-015-0288-5
更新日期:2015-09-01 00:00:00
abstract::Since 1992, the International Atomic Energy Agency (IAEA) has been promoting studies of air pollution using a standard design of air sampler that provides separation on filters into two size fractions with cutoffs of 2.5 and 10 microns (approximately). These are the size ranges presently considered to have the most im...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/BF02784202
更新日期:1999-01-01 00:00:00
abstract::Modifications in the enzyme activity of lysozyme, a protein implied in the defence barrier of the organism, can be a good biomarker of alterations in the immune system as a result of exposure to toxic metal, such as lead. The aim of this work was to evaluate the effect of a 200 ppm dose of lead on lysozyme activity in...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/s12011-012-9446-1
更新日期:2012-12-01 00:00:00
abstract::Bioenvironmental trace elements play a vital role in plant, animal, and man metabolism. This study aims to determine trace element concentration in different parts (pods, pericarp, seeds, cotyledon, and taste) of the warm climate plant pigeon pea (Cajanus cajan L. Millsp.). The pigeon pea pods were collected from the ...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/s12011-020-02256-y
更新日期:2020-06-20 00:00:00
abstract::The degree of accumulation and distribution of Cd and Pb in the organs of young animals compared to the amount taken in with water or feed have not been thoroughly investigated yet. The experiment aimed to verify whether the source of toxic metals (feed, drinking water) administered to growing rats orally has an influ...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/s12011-015-0414-4
更新日期:2016-02-01 00:00:00
abstract::Sugar-borates (SBs) are mono- or di-sugar-borate esters (SBEs) comprised of one or two monosaccharide molecules linked to a boron (B) atom. SBEs occur naturally in commonly consumed herbs, vegetables, fruits, seeds, and nuts and, other than greatly varying levels of B found in local drinking water, are the primary nat...
journal_title:Biological trace element research
pub_type: 杂志文章,评审
doi:10.1007/s12011-018-1550-4
更新日期:2019-03-01 00:00:00
abstract::Recently, several studies on the effects of a compound named "chromium malate," with the proposed formula "Cr2malate3·xH2O" where x = 3.5 or 5, on the health of healthy and diabetic rats have appeared. However, the compound is poorly characterized, and knowing the identity of this material could be important in the in...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/s12011-017-1046-7
更新日期:2018-02-01 00:00:00
abstract::Zinc is an essential micronutrient for the organism and is critical for the functional and structural integrity of cells. Determination of the amount of trace element concentrations in tissues such as hair samples have been used for the evaluation of the metabolic status especially in children. Unlike serum zinc, conc...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/s12011-020-02115-w
更新日期:2020-08-01 00:00:00
abstract::Zinc uptake regulator (Zur) is a negative transcriptional regulator of bacteria that belongs to the FUR superfamily of proteins and regulates zinc (Zn) homeostasis under extreme Zn conditions. The Zur protein of Bacillus anthracis (BaZur) was though characterized previously, but the residues of this transcriptional re...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/s12011-020-02427-x
更新日期:2020-10-14 00:00:00
abstract::Quantitative analysis of follicular fluid and granulosa cells from small, medium and large antral atretic follicles of goat (Capra hircus) ovaries was conducted to study the alterations in trace elements viz zinc (Zn), copper (Cu), manganese (Mn), and iron (Fe). The zinc content was lower in the follicular fluid (0.99...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/s12011-010-8700-7
更新日期:2011-06-01 00:00:00
abstract::It is well known that rare earth elements (REEs) have come into extensive use in a number of fields. As a result, REEs are becoming closely related to human's daily life. However, until now, the distributions of REEs in the brain are not yet very clear. In this study, Sprague-Dawley male rats were intraperitoneally in...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1385/BTER:104:1:033
更新日期:2005-04-01 00:00:00
abstract::The objective of this paper is to investigate the correlation between serum macro-element and trace element contents and bone mineral density (BMD) as well as the occurrence of osteoporosis. After the epidemiological investigation of 290 postmenopausal women from ages 45 to 65 in the Xi'an urban area, their blood was ...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/s12011-009-8363-4
更新日期:2009-12-01 00:00:00
abstract::Rare earth elements can promote photosynthesis, but their mechanisms are still poorly understood under magnesium deficiency. The present study was designed to determine the role of cerium in magnesium-deficient maize plants. Maize was cultivated in Hoagland's solution added with cerium with and without adequate quanti...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/s12011-010-8769-z
更新日期:2011-09-01 00:00:00
abstract::In the present study, adult Wistar albino male rats were exposed to formaldehyde at different periods (subacute and subchronic) and concentrations (5.0 and 10.0 ppm) in order to figure out the changes in the concentration of Zn, Cu and Fe. It was observed that the formaldehyde inhalation caused gradual decline of body...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/s12011-010-8686-1
更新日期:2011-05-01 00:00:00
abstract::Calcium, phytic acid, polyphenols and fiber are major inhibitors of iron absorption and they could be found in excess in some diets, thereby altering or modifying the iron nutrition status. The purpose of this study is to evaluate the effect of calcium, tannic acid, phytic acid, and pectin over iron uptake, using an i...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/s12011-014-9911-0
更新日期:2014-04-01 00:00:00
abstract::In present study, the levels of some toxic elements in 19 different home-made cosmetic products (spray hair dye, henna, tattoo, eyeliner, eye mascara, smear, lip moisturizer, and lipstick) were analyzed by inductively coupled plasma mass spectrometric (ICP-MS) after microwave digestion. The ICP-MS results were verifie...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/s12011-020-02357-8
更新日期:2020-09-05 00:00:00
abstract::The accumulation of cadmium, its affinity for metallothioneins (MTs), and its relation to copper, zinc, and selenium were investigated in the experimental mudpuppy Necturus maculosus and the common toad Bufo bufo captured in nature. Specimens of N. maculosus were exposed to waterborne Cd (85 μg/L) for up to 40 days. E...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/s12011-012-9461-2
更新日期:2012-12-01 00:00:00
abstract::After considering the need for quality control in NAA, the concept of quality in NAA procedures themselves is discussed, and some important factors identified. Two approaches to improve quality are then described in more detail. The first concerns the unique ability of NAA using different isotopic reactions and differ...
journal_title:Biological trace element research
pub_type: 杂志文章,评审
doi:10.1007/BF02917356
更新日期:1994-10-01 00:00:00
abstract::Manganese (Mn) is an essential element for normal development and bodily functions in humans. In the present study, we examined whether Mn supplementation can alter the serum lipid parameters and liver function in Ca-deficient ovariectomized (OVX) rats. Sixty female Sprague-Dawley rats (6 weeks) were divided into five...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/s12011-010-8714-1
更新日期:2011-06-01 00:00:00
abstract::Methylmercury (MeHg) is highly toxic, and its principal target tissue in human is the nervous system, which has made MeHg intoxication a public health concern for many decades. Portulaca oleraceae (purslane), a member of the Portulacaceae family, is widespread as a weed and has been ranked the eighth most common plant...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1007/s12011-015-0546-6
更新日期:2016-07-01 00:00:00
abstract::Zinc and fluorides are capable of modifying the process of bone formation and mineralization. Statistically significant differences have been revealed in the content of zinc and fluorides between structures of the femur in chicken. The content of zinc in compact bone remained constant during the first 50 d of life. Lo...
journal_title:Biological trace element research
pub_type: 杂志文章
doi:10.1385/BTER:91:1:67
更新日期:2003-01-01 00:00:00