A spectroscopic study of the interaction of the VO2+ cation with the two components of chondroitin sulfate.

Abstract:

:The interaction of the vanadyl (IV) cation with N-acetyl-D-galactosamine, D-galactosamine, and D-glucuronic acid has been investigated by electron absorption spectroscopy at different metal to ligand ratios and pH values. In the case of D-glucuronic acid, a more detailed study was undertaken, using differential IR spectroscopy in solution. The results show that the cation interacts with the two nitrogenated molecules only at higher pH values, generating 2:1 ligand to metal complexes in which coordination occurs through two pairs of deprotonated OH groups of the rings. In the case of D-glucuronic acid, the IR-measurements allowed a wider insight into the structural characteristics of the complexes generated in acidic media. The involvement of the glycosidic oxygen atom in coordination, is suggested at pH = 3.

journal_name

Biol Trace Elem Res

authors

Etcheverry SB,Williams PA,Baran EJ

doi

10.1007/BF02785436

subject

Has Abstract

pub_date

1996-02-01 00:00:00

pages

169-76

issue

2

eissn

0163-4984

issn

1559-0720

journal_volume

51

pub_type

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