Synthesis, spectra and photophysics of some free base tetrafluoroalkyl and tetrafluoroaryl porphyrins with potential applications in imaging.

abstract：:The photodegradation of the herbicide clomazone in the presence of S(2)O(8) (2-) or of humic substances of different origin was investigated. A value of (9.4 +/- 0.4) x 10(8) m(-1) s(-1) was measured for the bimolecular rate constant for the reaction of sulfate radicals with clomazone in flash-photolysis experiments. ...

journal_title：Photochemistry and photobiology

authors： David Gara PM,Bosio GN,Arce VB,Poulsen L,Ogilby PR,Giudici R,Gonzalez MC,Mártire DO

更新日期：2009-05-01 00:00:00

abstract：:Iranian firefly larvae, Lampyris turkestanicus collected from north of Iran and their luciferin were analyzed by HPLC, TLC, MS and spectroscopic Fourier transform ([FT]-IR, FT-NMR, UV and fluorescence) methods. The results showed that luciferin in L turkestanicus lanterns was the same as in the American firefly, Photi...

journal_title：Photochemistry and photobiology

authors： Hadj-Mohammadi MR,Chaichi MJ

更新日期：1996-11-01 00:00:00

abstract：:To improve the understanding of human skin autofluorescence emission, the spectroscopic and microscopic characteristics of skin autofluorescence were studied using a combined fluorescence and reflectance spectroanalyzer and a fiber optic microspectrophotometer. The autofluorescence spectra of in vivo human skin were m...

journal_title：Photochemistry and photobiology

authors： Zeng H,MacAulay C,McLean DI,Palcic B

更新日期：1995-06-01 00:00:00

abstract：:The inefficient endosomal escape of drugs or macromolecules is a major obstacle to achieving successful delivery to therapeutic targets. An efficient approach to circumvent this barrier is photochemical internalization (PCI), which uses light and photosensitizers for endosomal escape of the delivered macromolecules. T...

journal_title：Photochemistry and photobiology

authors： Soe TH,Nanjo T,Watanabe K,Ohtsuki T

更新日期：2019-11-01 00:00:00

abstract：:The multifunctional polypeptide cyclosporin synthetase (CySyn) remains one of the most complex nonribosomal peptide synthetase described. In this study we used a highly specific photoaffinity labeling procedure with the natural cofactor S-adenosyl-L-methionine (AdoMet), 14C-isotopically labeled at the Sdelta methyl gr...

journal_title：Photochemistry and photobiology

authors： Velkov T,Lawen A

更新日期：2003-02-01 00:00:00

abstract：:Continuous wave and pulsed laser ablation of tissue is described as an explosive event. A subsurface temperature maximum and superheated tissue produce high pressures that eject fragments from the tissue. Decreased water content due to dehydration and vaporization decreases thermal conductivity which reduces heat cond...

journal_title：Photochemistry and photobiology

authors： Welch AJ,Motamedi M,Rastegar S,LeCarpentier GL,Jansen D

更新日期：1991-06-01 00:00:00

abstract：:The photodegradation of the S(+)- and R(-)-ketoprofen (KP) enantiomers in the bovine serum albumin matrix was studied by steady-state photolysis with the use of lambda(irr) > 320 nm and transient absorption spectroscopy with lambda(exc) = 355 nm, at 1/1 and 2/1 KP/BSA molar ratios. R(-)-KP was found to be more labile ...

journal_title：Photochemistry and photobiology

authors： Monti S,Manet I,Manoli F,Morrone R,Nicolosi G,Sortino S

更新日期：2006-01-01 00:00:00

abstract：:Tin oxide nanoparticles about 4 nm in size were successfully synthesized using hydrothermal method. The photocatalytic activity of the particles was determined by the decolorization of malachite green (MG) and titanium yellow (TY) under UV light. 12 ppm of MG and TY were used for the solution with an initial volume of...

journal_title：Photochemistry and photobiology

authors： Esen B,Yumak T,Sınağ A,Yıldız T

更新日期：2011-03-01 00:00:00

abstract：:More scheduled outdoor stay is increasingly advocated for school children. This study measured 2(nd) , 5(th) and 8(th) graders' erythemal UV-exposure in September, March and May at four Swedish schools. We related those exposures, as fractions of total available ambient radiation, to the schools outdoor environments d...

journal_title：Photochemistry and photobiology

authors： Pagels P,Wester U,Söderström M,Lindelöf B,Boldemann C

更新日期：2016-01-01 00:00:00

abstract：:The present work is aimed to synthesize CdTe/ZnSe core/shell quantum dots (QDs) in an easy way and to explore the possibilities of its application in in vitro imaging of chicken tissue and embryo. The QDs were prepared using microwave irradiation with different temperatures, which is a very easy and less time-consumin...

journal_title：Photochemistry and photobiology

authors： Moulick A,Blazkova I,Milosavljevic V,Fohlerova Z,Hubalek J,Kopel P,Vaculovicova M,Adam V,Kizek R

更新日期：2015-03-01 00:00:00

abstract：:Detergent solubilized bacteriorhodopsin (BR) proteins which contain alterations made by site-directed mutagenesis (Asp-96----Asn, D96N; Asp-85----Asn, D85N; and Arg-82----Gln, R82Q) have been studied with resonance Raman spectroscopy. Raman spectra of the light-adapted (BRLA) and M species in D96N are identical to tho...

journal_title：Photochemistry and photobiology

authors： Lin SW,Fodor SP,Miercke LJ,Shand RF,Betlach MC,Stroud RM,Mathies RA

更新日期：1991-03-01 00:00:00

abstract：:Adaptability to a broad range of environments together with relatively high resistance to antibiotics and to disinfectants makes Pseudomonas aeruginosa a concern in hospitals and in public health. We investigated whether UVA-mediated photochemical inactivation of P. aeruginosa could be accomplished with high efficienc...

journal_title：Photochemistry and photobiology

authors： Sagripanti JL,Grote G,Niederwöhrmeier B,Hülseweh B,Marschall HJ

更新日期：2012-01-01 00:00:00

abstract：:Pyocyanin (PyO-) (1-hydroxy-5-methylphenazine) is a cytotoxic compound secreted by Pseudomonas aeruginosa, an omnipresent bacterium and a human pathogen. We report that visible light illumination in the presence of rose bengal, or riboflavin, in aerated solutions (pH 7.0-7.2) induces irreversible loss of the pigment's...

journal_title：Photochemistry and photobiology

authors： Reszka KJ,Denning GM,Britigan BE

更新日期：2006-03-01 00:00:00

abstract：:Synthesis of extracellular matrix (ECM) proteins and their degradation by matrix metalloproteinases (MMP) are part of the dermal remodeling resulting from chronic exposure of skin to ultraviolet radiation (UVR). We have compared two alternative mechanisms for these responses, namely, a direct mechanism in which UV-B o...

journal_title：Photochemistry and photobiology

authors： Kossodo S,Wong WR,Simon G,Kochevar IE

更新日期：2004-01-01 00:00:00

abstract：:Urinary cytology is a noninvasive and unconstraining technique for urothelial cancer diagnosis but lacks sensitivity for detecting low-grade lesions. In this study, the fluorescence properties of classical Papanicolaou-stained urothelial cytological slides from patients or from cell lines were monitored to investigate...

journal_title：Photochemistry and photobiology

authors： Steenkeste K,Lécart S,Deniset A,Pernot P,Eschwège P,Ferlicot S,Lévêque-Fort S,Briandet R,Fontaine-Aupart MP

更新日期：2007-09-01 00:00:00

abstract：:Within this study, the erythemal ultraviolet (UV) exposure received by different parts of the body during four different activities is determined. Optoelectronic devices were used to measure the erythemal UV exposure at 10 different positions of the body. The measuring devices were fixed on the forehead, on the should...

journal_title：Photochemistry and photobiology

authors： Weihs P,Schmalwieser A,Reinisch C,Meraner E,Walisch S,Harald M

更新日期：2013-07-01 00:00:00

abstract：:The XPA gene-deficient mouse, an animal model of xeroderma pigmentosum (XP), develops enhanced photobiologic reactions including acute inflammation, immunosuppression and skin carcinogenesis, because of the defect in the excision repair of ultraviolet-induced DNA lesions. The results strongly suggest that nuclear DNA ...

journal_title：Photochemistry and photobiology

authors： Horio T,Miyauchi-Hashimoto H,Kuwamoto K,Yamazaki F,Okamoto H

更新日期：2007-01-01 00:00:00

abstract：:Copper(II), in the presence of UV-B radiation (280-315 nm), can generate single-strand breaks in the sugar-phosphate backbone of pBR322 plasmid DNA. A low level of single-strand backbone breaks occurs in the presence of Cu(II) alone, but UV-B irradiation increases the rate by the more than 100-fold. Concomitant with t...

journal_title：Photochemistry and photobiology

authors： Lloyd RE,Larson RA,Adair TL,Tuveson RW

更新日期：1993-06-01 00:00:00

abstract：:The activity of the bimodal fluorescent protein (bmFP) (lambda max, 488 and 517 nm) in the in vitro luciferase reaction has been studied. The bmFP that is produced by Photobacterium phosphoreum strain bmFP is a dimer of two homologous subunits binding four riboflavin 5'-phosphate (FMN)-myristate chromophores. The addi...

journal_title：Photochemistry and photobiology

authors： Karatani H,Konaka T

更新日期：2000-02-01 00:00:00

abstract：:Abstract- Time-resolved transmittance was used to extract in vivo optical properties of leaves of green plants experimentally. In time-resolved transmittance measurements an ultrashort light pulse is directed onto the surface of the object and the transmitted light is measured with a time resolution in the range of pi...

journal_title：Photochemistry and photobiology

authors： Johansson J,Berg R,Pifferi A,Svanberg S,Björn LO

更新日期：1999-02-01 00:00:00

abstract：:In this paper, we propose a new physical method in combination with mixed solution of thiazone and polyethylene glycol 400 (thiazone PEG 400 solution) penetration into tissue to assess the skin optical clearing. Four treatments were performed: (1) control group (C); (2) polyethylene glycol 400 (PEG400); (3) 0.25% thia...

journal_title：Photochemistry and photobiology

authors： Zhong H,Guo Z,Wei H,Guo L,Wang C,He Y,Xiong H,Liu S

更新日期：2010-05-01 00:00:00

abstract：:The pharmacokinetics of Zn phthalocyanine (ZnPc) encapsulated in dipalmitoyl-phosphatidylcholine (DPPC) liposomes, injected intravenously in Skh:HR-1 nude mice, was monitored by two in vitro techniques and one in vivo technique, all based on fluorescence spectroscopy. The in vitro methods involve either fluorescence m...

journal_title：Photochemistry and photobiology

authors： Biolo R,Jori G,Kennedy JC,Nadeau P,Pottier R,Reddi E,Weagle G

更新日期：1991-01-01 00:00:00

abstract：:DNA UVB dosimeters, consisting of minidots of dried bacteriophage DNA placed on a UV-transparent polymer film, were analyzed by polymerase chain reactions (PCR). Ultraviolet-B dosimetry obtained with amplification of phage lambda DNA of segments of 1.08 kilobase pairs (kbp) and 2.24 kbp was compared with that obtained...

journal_title：Photochemistry and photobiology

authors： Yoshida H,Regan JD

更新日期：1997-11-01 00:00:00

abstract：:We investigated the effect of the cation-π interaction on the susceptibility of a tryptophan model system toward interaction with singlet oxygen, that is, type II photooxidation. The model system consists of two indole units linked to a lariat crown ether to measure the total rate of removal of singlet oxygen by the i...

journal_title：Photochemistry and photobiology

authors： Arevalo GE,Cagan DA,Monsour CG,Garcia AC,McCurdy A,Selke M

更新日期：2020-11-01 00:00:00

abstract：:Several studies in the literature indicate that histones (lysine rich proteins found associated with DNA in eukaryotic chromatin), as well as poly-L-lysine, can be photocross-linked by ultraviolet (UV) light to DNA in which 5-bromo-2'-deoxyuridine has been substituted for thymidine. To gain some insight into the possi...

journal_title：Photochemistry and photobiology

authors： Shetlar MD,Rose RB,Hom K,Shaw AA

更新日期：1991-05-01 00:00:00

abstract：:Photodynamic treatment of promyelocytic K562 cells in the presence of a monoglucosylporphyrin or hematoporphyrin leads to a sequence of events recognized as hallmarks of apoptosis: a drop in mitochondrial potential, concurrent with a drop in ATP level and a decrease in cell respiration, translocation of phosphatidylse...

journal_title：Photochemistry and photobiology

authors： Carré V,Jayat C,Granet R,Krausz P,Guilloton M

更新日期：1999-01-01 00:00:00

abstract：:Pharmacological therapy is widely used in the treatment of muscle injuries. On the other hand, low-level laser therapy (LLLT) arises as a promising nonpharmacological treatment. The aim of this study was to analyze the effects of sodium diclofenac (topical application) and LLLT on morphological aspects and gene expres...

journal_title：Photochemistry and photobiology

authors： de Almeida P,Lopes-Martins RÁ,Tomazoni SS,Albuquerque-Pontes GM,Santos LA,Vanin AA,Frigo L,Vieira RP,Albertini R,de Carvalho Pde T,Leal-Junior EC

更新日期：2013-03-01 00:00:00

abstract：:The marine annelid Chaetopterus variopedatus produces bioluminescence by an unknown and potentially novel mechanism. We have advanced the study of this fascinating phenomenon, which has not been investigated for nearly 60 years after initial studies were first reported for this species. Here, we show that the luminous...

journal_title：Photochemistry and photobiology

authors： Branchini BR,Behney CE,Southworth TL,Rawat R,Deheyn DD

更新日期：2014-01-01 00:00:00

abstract：:Light-dark cycles are considered important cues to entrain biological clocks. A feedback loop of clock gene transcription and translation is the molecular basis underlying the mechanism of both central and peripheral clocks. Xenopus laevis embryonic melanophores respond to light with melanin granule dispersion, respon...

journal_title：Photochemistry and photobiology

authors： Magalhães Moraes MN,de Oliveira Poletini M,Ribeiro Ramos BC,de Lima LH,de Lauro Castrucci AM

更新日期：2014-05-01 00:00:00

abstract：:A novel antibody-fluorescence method has been developed to elucidate the chromophore topography in phytochrome as it undergoes a photochromic transformation. Förster energy transfer from N-terminal bound, fluorescently labeled Oat-25 Fab antibody fragments to the phytochrome chromophore was measured. The results sugge...

journal_title：Photochemistry and photobiology

authors： Farrens DL,Cordonnier MM,Pratt LH,Song PS

更新日期：1992-11-01 00:00:00