Abstract:
:The Ca-exchanged clays were used to investigate the sorption of toluene under both high and low relative humidity conditions. According to the observed rates of sorption and desorption and the Fourier transform infrared (FTIR) spectra of sorbed toluene, the sorbate molecules on clays can be divided into three categories: labile (gaslike) phase, slow sorption (liquidlike) phase, and resistant-to-desorption phase with sorption/desorption time scales of less than 30 min, several hours, and several weeks, respectively. Aging changed the spectroscopic characteristics of the sorbed sorbates and contributed to the irreversibility of the sorption under both high and low relative humidity. Irreversibly sorbed portions of the sorbates and new characteristic peaks identified with FTIR spectrometry suggest the existence of chemical transformation of sorbed species under both high and low relative humidity conditions. It is suggested that the clay minerals, acting as catalysts, may contribute to abiotic natural attenuation of volatile organic aromatic hydrocarbons in soils.
journal_name
Environ Toxicol Chemjournal_title
Environmental toxicology and chemistryauthors
Chang ML,Wu SC,Chen PJ,Cheng SCdoi
10.1897/02-270subject
Has Abstractpub_date
2003-09-01 00:00:00pages
1956-62issue
9eissn
0730-7268issn
1552-8618journal_volume
22pub_type
杂志文章abstract::This study examined the bioaccumulation and dietary retention of 61 polychlorinated biphenyl (PCB) and four polybrominated diphenyl ether (PBDE) congeners in juvenile American kestrels (Falco sparverius). American kestrels were exposed to contaminants via egg injection and daily gavage dosing over the posthatch-to-fle...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1897/06-052r.1
更新日期:2007-02-01 00:00:00
abstract::Safety factors are used in ecological risk assessments to extrapolate from the toxic responses of laboratory test species to all species representing that group in the environment. More accurate extrapolation of species responses is important. Advances in understanding the mechanistic basis for toxicological responses...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1002/etc.382
更新日期:2011-01-01 00:00:00
abstract::Benzotriazole ultra violet stabilizers (BZT-UVs) are compounds used in many applications and products to prevent photochemical degradation. Despite their widespread presence in aquatic ecosystems and persistence in the environment, there are very limited data on their effects and toxicity, and their modes of action re...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1002/etc.3908
更新日期:2017-12-01 00:00:00
abstract::The estrogenic activity of the effluent from three municipal wastewater treatment plants (WWTPs) in Nanjing, China, was investigated. The water samples were enriched by solid-phase extraction and then eluted with different polar solvents, which gave 11 fractionated extracts. Chemical analysis and a vitellogenin (Vtg) ...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1002/etc.155
更新日期:2010-06-01 00:00:00
abstract::The aquatic ecological environment is being threatened from overuse of pesticides, and the aquatic toxicity toward rainbow trout (Oncorhynchus mykiss) plays a significant role in environmental risk assessment of agrochemicals. In the present study, 2 norm index formulas were developed, from which several norm descript...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1002/etc.4621
更新日期:2020-02-01 00:00:00
abstract::Silver nanoparticles (AgNPs) from industrial use, discharged via the land application of sewage sludge, are interacting with soil biota, including earthworms. In affected organisms, excessive production of reactive oxygen species can result in lipid peroxidation, shifting the balance between oxidants and antioxidants ...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1002/etc.4713
更新日期:2020-05-01 00:00:00
abstract::The polymer adsorbent Tenax has been widely employed for studying desorption of organic contaminants in soils and sediments and for correlating physical availability with bioavailability. Although Tenax has been invoked to act as an infinite sink that completely and instantaneously removes solutes from the aqueous pha...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1897/03-161
更新日期:2004-07-01 00:00:00
abstract::Metal cation toxicity to basidiomycete fungi is poorly understood, despite its well-known importance in terrestrial ecosystems. Moreover, there is no reported methodology for the routine evaluation of metal toxicity to basidiomycetes. In the present study, we describe the development of a procedure to assess the acute...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1002/etc.42
更新日期:2010-02-01 00:00:00
abstract::Variable sizes of nanoparticles, ranging from nano to micro scale, are of toxicological interest. In the present study, the authors hypothesized that, in addition to the size, the shape of iron oxide (Fe2O3) nanoparticles is a major factor that contributes to particle cytotoxicity. Cytotoxicity to mouse macrophage cel...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1002/etc.2735
更新日期:2014-12-01 00:00:00
abstract::Radiotracer experiments were conducted to examine the influence of the concentration of Cd, Se, and Zn in ingested phytoplankton (dinoflagellate Prorocentrum minimum and diatom Thalassiosira weissflogii) and in ambient seawater on metal assimilation and elimination efficiencies of three marine copepods, Acartia spinic...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:
更新日期:2001-05-01 00:00:00
abstract::A series of atomistic simulations was performed to assess the ability of the Schulten dissolved organic matter (DOM) molecule, a well-established model humic molecule, to reproduce the physical and chemical behavior of natural humic substances. The unhydrated DOM molecule had a bulk density value appropriate to humic ...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1897/04-567r.1
更新日期:2005-08-01 00:00:00
abstract::This study investigates both the methods and the multispecies and functional level effects of a release of a complex hydrocarbon mixture from sediments using a 60-d modified mixed flask culture (MFC) microcosm. Neat Jet-A was injected and mixed into the sediment with one nondosed and three dosed concentrations. Univar...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:
更新日期:2001-09-01 00:00:00
abstract::Environmental factors, in particular temperature, have been shown to affect the toxicity of chemicals. In the present study the authors exposed the nematode Caenorhabditis elegans to five concentrations of Cd (2, 4, 6, 8, and 10 mg Cd/L agar) at four constant temperatures (11, 15, 18, and 21°C) and monitored survival ...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1002/etc.1746
更新日期:2012-04-01 00:00:00
abstract::The avian embryo is an excellent model for testing adverse developmental effects of environmental chemicals as well as uptake and movement of xenobiotics within the egg compartments. Before incubation at embryonic day 0, 14 C 3,3',4,4'-tetrachlorobiphenyl (14 C PCB 77) was injected into Japanese quail eggs either onto...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1002/etc.3977
更新日期:2018-01-01 00:00:00
abstract::Pharmaceuticals and personal care products (PPCPs) such as caffeine and sulfamethoxazole have been detected in the estuarine environment. The present study characterized effects of a maternal exposure of these compounds on the development of the daggerblade grass shrimp Palaemonetes pugio from embryo to juvenile life ...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1002/etc.2669
更新日期:2014-09-01 00:00:00
abstract::Native freshwater mussels (family Unionidae) are among the most imperiled faunal groups in the world. Factors contributing to the decline of mussel populations likely include pesticides and other aquatic contaminants; however, there is a paucity of data regarding the toxicity of even the most globally distributed pest...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1897/06-519R1.1
更新日期:2007-10-01 00:00:00
abstract::Pesticides are frequently detected in urban streams, with concentrations often exceeding those reported in surface waters within agricultural areas. The authors studied growth, survival, and return rates of coho salmon (Oncorhynchus kisutch) smolts exposed to a pesticide mixture ("cocktail") representative of the pest...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1002/etc.2593
更新日期:2014-07-01 00:00:00
abstract::Soil samples spiked with five concentrations of pyrene and phenanthrene were aged for 0, 10, 40, and 120 d before toxicity was investigated using a standardized bioassay with the soil-dwelling collembolan Folsomia fimetaria L. Toxic effects were measured as reductions in survival and reproductive output after 3 weeks ...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1897/1551-5028(2002)021<0489:soteos>2.0.co;2
更新日期:2002-03-01 00:00:00
abstract::The degradation of plasticizers by the yeast Rhodotorula rubra J-96-1 (American Type Culture Collection 9449) in the presence of glucose was studied. The plasticizers included the commonly used bis-2-ethylhexyl adipate (B(EH)A), dioctyl phthalate (DOP), and dioctyl terephthalate (DOTP), and the less commonly used dipr...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:
更新日期:2003-06-01 00:00:00
abstract::In plant tissues, xenobiotics often are conjugated with natural constituents such as sugars, amino acids, glutathione, and malonic acid. Usually, conjugation processes result in a decrease in the reactivity and toxicity of xenobiotics by increasing the water solubility and polarity of conjugates, and reducing their mo...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1897/07-036R.1
更新日期:2007-11-01 00:00:00
abstract::The increased application of nanoparticles (NPs) is increasing the risk of their release into the environment. Although many toxicity studies have been conducted, the environmental risk is difficult to estimate, because uptake mechanisms are often not determined in toxicity studies. In the present study, the authors r...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章,评审
doi:10.1002/etc.2470
更新日期:2014-03-01 00:00:00
abstract::Although the estrogenic hormones 17 beta-estradiol and 17 alpha-ethinyl estradiol can be quantified in polluted waters by gas chromatography/mass spectrometry (GC/MS) and gas chromatography/tandem mass spectrometry (GC/MS/MS), the compounds often are present at concentrations below detection limits. Enzyme-linked immu...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:
更新日期:2001-01-01 00:00:00
abstract::Monte Carlo simulations were used to evaluate statistical methods for estimating 95% upper confidence limits of mean constituent concentrations for left-censored data with nonuniform detection limits. Two primary scenarios were evaluated: data sets with 15 to 50% nondetected samples and data sets with 51 to 80% nondet...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1897/05-548r.1
更新日期:2006-09-01 00:00:00
abstract::The risk to adjacent aquatic systems posed by leachates from scrap tires used in engineering applications has not been characterized adequately. Toxicity testing, toxicity identification evaluation (TIE), and groundwater modeling were used to determine the circumstances under which tire shreds could be used as roadbed...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1897/04-532r2.1
更新日期:2006-02-01 00:00:00
abstract::The Alberta Oil Sands Region in Canada is home to one of the largest oil bitumen deposits in the world. The North American river otter (Lontra canadensis) is a top predator with a small home range and is sensitive to disturbances; it has been designated as a sentinel species for the potential impacts of the natural re...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1002/etc.4876
更新日期:2020-12-01 00:00:00
abstract::The occurrence of intersex fish in a number of European rivers has been attributed to exposure to estrogenic chemicals present in sewage treatment work (STW) effluents. To further understand the environmental fate of these contaminants, the estrogenic activity of effluents, water, and sediments were investigated both ...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1897/03-41
更新日期:2004-04-01 00:00:00
abstract::Hexanitrohexaazaisowurtzitane (CL-20), a new polycyclic polynitramine, has the same functional nitramine groups (N-NO2) as the widely used energetic chemicals hexahydro-1,3,5-trinitro-1,3,5-triazacyclohexane (royal demolition explosive [RDX]) and octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (high-melting explosive...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1897/054-188r.1
更新日期:2005-10-01 00:00:00
abstract::The trophic transfer of monoaromatic hydrocarbons to predatory organisms feeding upon contaminated marine animals is not well reported within the scientific literature. Branched alkylbenzenes (BABs) unresolved by gas chromatography have been reported to be principal toxic components of bioaccumulated hydrocarbons in t...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1897/08-298.1
更新日期:2009-02-01 00:00:00
abstract::A key success factor for the performance of passive samplers is the proper calibration of sampling rates. Sampling rates for a wide range of polar organic compounds are available for Chemcatchers and polar organic chemical integrative samplers (POCIS), but the mechanistic models that are needed to understand the effec...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章,评审
doi:10.1002/etc.4160
更新日期:2018-07-01 00:00:00
abstract::Equilibrium passive sampling methods (EPSMs) allow quantification of freely dissolved contaminant concentrations (Cfree ) in sediment porewater. Polydimethylsiloxane (PDMS) is a convenient sampling polymer that can be equilibrated in field (in situ) or laboratory (ex situ) sediments to determine Cfree , providing reli...
journal_title:Environmental toxicology and chemistry
pub_type: 杂志文章
doi:10.1002/etc.4849
更新日期:2020-11-01 00:00:00