Photochemical degradation of selected nitropolycyclic aromatic hydrocarbons in solution and adsorbed to solid particles.

Abstract:

:To examine the relationship between the nitro group orientation and photochemical degradation, a series of NPAHs, including 6-nitrochrysene, 9-nitroanthracene and 6-nitrobenzo(a)pyrene were irradiated both dissolved in CH3CN and adsorbed onto a surface (alumina, silica, carbon and cellulose). In solution, not all NPAHs displayed a relationship between their relative and nitro group orientation. In the adsorbed state, the nature of the particle appeared to have more of an influence than did the structure of the NPAH. If the compound degraded, the main product was generally a quinone.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Warner SD,Farant JP,Butler IS

doi

10.1016/j.chemosphere.2003.09.020

subject

Has Abstract

pub_date

2004-02-01 00:00:00

pages

1207-15

issue

8

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(03)00934-2

journal_volume

54

pub_type

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