Abstract:
:The structural spectroscopic, and thermal properties of a complex of sulfacetamide (Hsacm) with Cu(II) have been investigated. The complex [Cu(Hsacm)2(NO3)2] crystallizes in the monoclinic system, space group P2(1)/n. The cell dimensions are a = 7.696(7) A, b = 8.017(7) A, c = 19.230(10), beta = 110.80(1) degree, V = 1109(1) A3, Z = 2, and Dx = 1.84 g/cm3. The structure was refined to R = 0.0776. Cu(Hsacm)2(NO3)2 molecules form a long polymeric chain extended along the b-axis. The copper(II) coordinated geometry is tetragonally distorted octahedral with two amino nitrogens from Hsacm and two oxygens from nitrato anions in the basal plane and two acetamido oxygens from neighbor Hsacm molecules in the apical position. Each sulfacetamide, acting as a bidentate ligand, links two Cu(II) ions as a bridge through the Namino and the Oacetamido atoms. The complex proved to possess higher bacteriostatic activity than the corresponding ligand.
journal_name
J Inorg Biochemjournal_title
Journal of inorganic biochemistryauthors
Blasco F,Ortiz R,Perelló L,Borrás J,Amigó J,Debaerdemaeker Tdoi
10.1016/0162-0134(94)85026-7subject
Has Abstractpub_date
1994-02-01 00:00:00pages
117-26issue
2eissn
0162-0134issn
1873-3344pii
0162-0134(94)85026-7journal_volume
53pub_type
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journal_title:Journal of inorganic biochemistry
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journal_title:Journal of inorganic biochemistry
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journal_title:Journal of inorganic biochemistry
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journal_title:Journal of inorganic biochemistry
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journal_title:Journal of inorganic biochemistry
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journal_title:Journal of inorganic biochemistry
pub_type: 杂志文章
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pub_type: 杂志文章
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journal_title:Journal of inorganic biochemistry
pub_type: 杂志文章
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更新日期:2015-08-01 00:00:00
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journal_title:Journal of inorganic biochemistry
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journal_title:Journal of inorganic biochemistry
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journal_title:Journal of inorganic biochemistry
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journal_title:Journal of inorganic biochemistry
pub_type: 杂志文章
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journal_title:Journal of inorganic biochemistry
pub_type: 杂志文章
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journal_title:Journal of inorganic biochemistry
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doi:10.1016/j.jinorgbio.2004.02.021
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journal_title:Journal of inorganic biochemistry
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更新日期:2014-02-01 00:00:00
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journal_title:Journal of inorganic biochemistry
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doi:10.1016/s0162-0134(00)00125-2
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journal_title:Journal of inorganic biochemistry
pub_type: 杂志文章
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更新日期:2005-02-01 00:00:00
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journal_title:Journal of inorganic biochemistry
pub_type: 杂志文章
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journal_title:Journal of inorganic biochemistry
pub_type: 杂志文章
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更新日期:1980-07-01 00:00:00
abstract::The dinuclear complex [Zn(2)(DPCPMP)(pivalate)](ClO4), where DPCPMP is the new unsymmetrical ligand [2-(N-(3-((bis((pyridin-2-yl)methyl)amino)methyl)-2-hydroxy-5-methylbenzyl)-N-((pyridin-2-yl)methyl)amino)acetic acid], has been synthesized and characterized. The complex is a functional model for zinc phosphoesterases...
journal_title:Journal of inorganic biochemistry
pub_type: 杂志文章
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更新日期:2014-03-01 00:00:00
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journal_title:Journal of inorganic biochemistry
pub_type: 杂志文章
doi:10.1016/s0162-0134(03)00249-6
更新日期:2003-08-01 00:00:00
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journal_title:Journal of inorganic biochemistry
pub_type: 杂志文章
doi:10.1016/j.jinorgbio.2015.08.028
更新日期:2015-12-01 00:00:00
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journal_title:Journal of inorganic biochemistry
pub_type: 杂志文章
doi:10.1016/j.jinorgbio.2017.09.001
更新日期:2017-12-01 00:00:00