Energy dissipation processes of singlet-excited 1-hydroxyfluorenone and its hydrogen-bonded complex with N-methylimidazole.

Abstract:

:Effects of solvent, pH and hydrogen bonding with N-methylimidazole (MIm) on the photophysical properties of 1-hydroxyfluorenone (1HOF) have been studied. Fluorescence lifetime, fluorescence quantum yield and triplet yield measurements demonstrated that intersystem crossing was the dominant process in apolar media and its rate constant significantly diminished with increasing solvent polarity. The acceleration of internal conversion in alcohols paralleled the strength of intermolecular hydrogen bonding. The faster energy dissipation from the singlet-excited state in cyclohexane was attributed to intramolecular hydrogen bonding. The pK(a) of 1HOF decreased from 10.06 to 5.0 on light absorption, and H(3)O(+) quenched the singlet-excited molecules in a practically diffusion-controlled reaction. On addition of MIm in toluene, dual fluorescence was observed, which was attributed to reversible formation of excited hydrogen-bonded ion pair. Rate constants for the various deactivation pathways were derived from the combined analysis of the steady-state and the time-resolved fluorescence results.

journal_name

Photochem Photobiol

authors

Sebok-Nagy K,Biczók L,Morimoto A,Shimada T,Inoue H

doi

10.1562/2004-01-27RA-067.1

subject

Has Abstract

pub_date

2004-07-01 00:00:00

pages

119-26

eissn

0031-8655

issn

1751-1097

pii

2004-01-27RA-067

journal_volume

80

pub_type

杂志文章
  • Slow solvent relaxation dynamics of nanometer sized reverse micellar systems through tryptophan metabolite, kynurenine.

    abstract::Exploration of environmental dynamics using intrinsic biological probe tryptophan is very important; however, it suffers from various difficulties. An alternative probe, kynurenine (KN), has been found to be an efficient probe for the ultrafast dynamics in the biological environment (Goswami et al., [2010] J. Phys. Ch...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.2011.01007.x

    authors: Rakshit S,Goswami N,Pal SK

    更新日期:2012-01-01 00:00:00

  • The use of wavelength-selective plastic cladding materials in horticulture: understanding of crop and fungal responses through the assessment of biological spectral weighting functions.

    abstract::Plant responses to light spectral quality can be exploited to deliver a range of agronomically desirable end points in protected crops. This can be achieved using plastics with specific spectral properties as crop covers. We have studied the responses of a range of crops to plastics that have either (a) increased tran...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1562/2004-12-06-RA-392

    authors: Paul ND,Jacobson RJ,Taylor A,Wargent JJ,Moore JP

    更新日期:2005-09-01 00:00:00

  • Effects of low-level laser therapy (LLLT) and diclofenac (topical and intramuscular) as single and combined therapy in experimental model of controlled muscle strain in rats.

    abstract::Muscle injuries represent ca 30% of sports injuries and excessive stretching of muscle causes more than 90% of injuries. Currently the most used treatments are nonsteroidal anti-inflammatory drugs (NSAIDs), however, in last years, low-level laser therapy (LLLT) is becoming an interesting therapeutic modality. The aim ...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.2012.01236.x

    authors: de Paiva Carvalho RL,Leal-Junior EC,Petrellis MC,Marcos RL,de Carvalho MH,De Nucci G,Lopes-Martins RA

    更新日期:2013-03-01 00:00:00

  • Applicability of the polysulphone horizontal calibration to differently inclined dosimeters.

    abstract::Polysulphone (PS) dosimetry has been a widely used technique for more than 30 years to quantify the erythemally effective UV dose received by anatomic sites (personal exposure). The calibration of PS dosimeters is an important issue as their spectral response is different from the erythemal action spectrum. It is perf...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.2011.01006.x

    authors: Casale GR,Siani AM,Diémoz H,Kimlin MG,Colosimo A

    更新日期:2012-01-01 00:00:00

  • Photophysical properties of the lowest excited singlet and triplet states of thio- and seleno-psoralens

    abstract::The decay processes of the lowest excited singlet and triplet states of five heteropsoralens (HPS) were investigated by steady-state and shift-phase fluorometry and by laser-flash photolysis in different solvents. The emission spectra of HPS are detectable only in trifluoroethanol (TFE), where fluorescence lifetimes (...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1562/0031-8655(2000)071<0506:ppotle>2.0.co;2

    authors: Aloisi GG,Elisei F,Moro S,Miolo G,Dall'Acqua F

    更新日期:2000-05-01 00:00:00

  • Membrane damage efficiency of phenothiazinium photosensitizers.

    abstract::Structure-activity relationships have been widely reported for porphyrin and phthalocyanine photosensitizers, but not for phenothiazinium derivatives. Here, four phenothiazinium salts (methylene blue, toluidine blue O, 1,9-dimethyl methylene blue and the pentacyclic derivative DO15) were used to investigate how the ab...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/php.12264

    authors: Bacellar IO,Pavani C,Sales EM,Itri R,Wainwright M,Baptista MS

    更新日期:2014-07-01 00:00:00

  • Heat and concentration effects on the small heat shock protein, alpha-crystallin.

    abstract::alpha-Crystallin, a major protein of the mammalian lens, plays a vital role in maintaining the structural stability and transparency of the lens. It performs this function through chaperone-like activity; it has recently been reported that heating alpha-crystallin enhances this ability. The present studies, using both...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1562/0031-8655(2000)071<0470:haceot>2.0.co;2

    authors: Mandal K,Dillon J,Gaillard ER

    更新日期:2000-04-01 00:00:00

  • Photosensitizers in dermatology.

    abstract::Systemic injection of hematoporphyrin derivative (HpD) in contribution with visible light (red or blue-green) delivered by laser was used to treat a patient with psoriasis. The psoriatic lesions responded vigorously to laser treatments, forming eschars by 1 week post irradiation. In contrast, only minimal erythema was...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.1987.tb04739.x

    authors: McCullough JL,Weinstein GD,Douglas JL,Berns MW

    更新日期:1987-07-01 00:00:00

  • Species-specific responses to combined thermal-irradiance stress in microalgae--"each is to its own".

    abstract::This article is a highlight of the study by Stamenkovic and Hanelt in this issue of Photochemistry and Photobiology describing the high-irradiance photophysiology of several strains of freshwater chlorophyte microalgal genus, Cosmarium. These strains exhibit distinct differences in how combined thermal- high irradianc...

    journal_title:Photochemistry and photobiology

    pub_type: 评论,杂志文章

    doi:10.1111/php.12081

    authors: Neale P

    更新日期:2013-07-01 00:00:00

  • Lethal Effect of Photodynamic Treatment on Persister Bacteria.

    abstract::Persister bacteria tolerate bactericidal antibiotics due to transient and reversible phenotypic changes. As these bacteria can limit the effectiveness of antibiotics to eradicate certain infections, their elimination is a relevant issue. Photodynamic therapy seems suitable for this purpose, but phenotypic tolerance to...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/php.12843

    authors: Oppezzo OJ,Forte Giacobone AF

    更新日期:2018-01-01 00:00:00

  • Intracellular target for alpha-terthienyl photosensitization: involvement of lysosomal membrane damage.

    abstract::Intracellular targets for the photosensitizer alpha-terthienyl (alpha T) were examined by fluorescence microscopy and microfluorospectrometry using human nonkeratinized buccal cells. Intracellular distribution of alpha T was observed as fluorescent patches widely dispersed in the cytoplasm. The distribution of the flu...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.1993.tb09213.x

    authors: Sasaki M,Koyama S,Tokiwa K,Fujita H

    更新日期:1993-05-01 00:00:00

  • Molecular changes during the photooxidation of alpha-crystallin in the presence of uroporphyrin.

    abstract::Singlet oxygen reacts preferentially with three amino acids in proteins, His, Trp and Met. In order to study the specific molecular events that result from such oxidations, calf alpha-crystallin was photooxidized in the presence of uroporphyrin and the reactions were investigated by high performance liquid chromatogra...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.1993.tb02330.x

    authors: Dillon J,Chiesa R,Wang RH,McDermott M

    更新日期:1993-03-01 00:00:00

  • Ultraviolet germicidal irradiation: future directions for air disinfection and building applications.

    abstract::Ultraviolet germicidal irradiation (UVGI) for air disinfection applications has relied on low-pressure mercury vapor lamps for decades. New design requirements have generated the need for alternatives in some uses. This study describes the current state of UVGI technology and describes future directions for technology...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章,评审

    doi:10.1111/php.12080

    authors: Miller SL,Linnes J,Luongo J

    更新日期:2013-07-01 00:00:00

  • Photointeraction of benzophenone triplet with lysozyme.

    abstract::The quenching of the benzophenone triplet by lysozyme and its constituent amino acids in aqueous solutions have been studied. Native lysozyme quenches the benzophenone triplet with a high rate constant, 4 x 10(9) M-1 s-1. The quenching process takes place with production of significant amounts of free ketyl radicals, ...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.1989.tb08424.x

    authors: Encinas MV,Lissi EA,Vasquez M,Olea AF,Silva E

    更新日期:1989-05-01 00:00:00

  • Molecular evolution of the Ca(2+)-binding photoproteins of the Hydrozoa.

    abstract::Alignment of the primary structures of the hydrozoan photoproteins, aequorin, mitrocomin, clytin and obelin showed very strong amino acid sequence identities. The Ca(2+)-binding sites of the proteins were found to be highly conserved. The Ca(2+)-binding sites were also homologous to the Ca(2+)-binding sites of other C...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.1995.tb08713.x

    authors: Tsuji FI,Ohmiya Y,Fagan TF,Toh H,Inouye S

    更新日期:1995-10-01 00:00:00

  • Fluorescence polarization studies of B-phycoerythrin oriented in polymer film.

    abstract::Polarized steady-state fluorescence and fluorescence excitation spectra as well as time-resolved fluorescence for B-phycoerythrin (B-PE) from red algae, Porphyridium cruentum, embedded in polyvinyl stretched films were measured. The lifetimes of polarized fluorescence were analyzed using exponential components and fra...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:

    authors: Frackowiak D,Ptak A,Gryczynski Z,Gryczynski I,Targowski P,Zelent B

    更新日期:2004-01-01 00:00:00

  • Targeted photochemical modification of HIV-derived oligoribonucleotides by antisense oligodeoxynucleotides linked to porphyrins.

    abstract::Antisense oligodeoxynucleotides directed against a 24-mer RNA derived from the long terminal repeat (LTR) region of HIV were linked to proto- and methylpyrroporphyrin and their zinc derivatives. The oligonucleotide-porphyrin conjugates were tested for their ability to induce photodamage on the target RNA. Upon hybridi...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.1994.tb05110.x

    authors: Mastruzzo L,Woisard A,Ma DD,Rizzarelli E,Favre A,Le Doan T

    更新日期:1994-10-01 00:00:00

  • Spectroscopic and microscopic characteristics of human skin autofluorescence emission.

    abstract::To improve the understanding of human skin autofluorescence emission, the spectroscopic and microscopic characteristics of skin autofluorescence were studied using a combined fluorescence and reflectance spectroanalyzer and a fiber optic microspectrophotometer. The autofluorescence spectra of in vivo human skin were m...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.1995.tb09881.x

    authors: Zeng H,MacAulay C,McLean DI,Palcic B

    更新日期:1995-06-01 00:00:00

  • Mutagenesis mediated by triple helix-forming oligonucleotides conjugated to psoralen: effects of linker arm length and sequence context.

    abstract::Targeted mutagenesis and gene knock-out can be mediated by triple helix-forming oligonucleotides (TFO) linked to mutagenic agents, such as psoralen. However, this strategy is limited by the availability of homopurine/homopyrimidine stretches at or near the target site because such sequences are required for high-affin...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:

    authors: Raha M,Lacroix L,Glazer PM

    更新日期:1998-03-01 00:00:00

  • Immobilized organic photosensitizers with versatile reactivity for various visible-light applications.

    abstract::Various photosensitizers were grafted by conventional peptide coupling methods to functionalized silica with several macroscopic shapes (powders, films) or embedded in highly transparent and microporous silica xerogel monoliths. Owing to the transparency and free-standing shape of the monoliths, the transient species ...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/php.12166

    authors: Ronzani F,Saint-Cricq P,Arzoumanian E,Pigot T,Blanc S,Oelgemöller M,Oliveros E,Richard C,Lacombe S

    更新日期:2014-03-01 00:00:00

  • Analysis of phosphorescence decay in heterogeneous systems: consequences of finite excitation flash duration.

    abstract::Analysis of phosphorescence lifetimes using the Stern-Volmer equation is a reliable means of determining quencher concentration for a uniform sample. Methods of analysis for heterogeneous systems are based on the assumption that the excitation is produced by a momentary flash. This condition is an idealization because...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:

    authors: Golub AS,Popel AS,Zheng L,Pittman RN

    更新日期:1999-06-01 00:00:00

  • Estimating the Diurnal Cycle and Daily Insolation of Ultraviolet and Photosynthetically Active Radiation at the Sea Surface.

    abstract::Accurate determination of the diurnal variability and daily insolation of surface (0(+) ) and subsurface (0(-) ) irradiance are essential to estimate several physical, chemical and biological processes occurring at the surface layer of marine environments. Natural downwelling PAR and spectral UVR were examined on eigh...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/php.12474

    authors: Kuwahara VS,Taguchi S

    更新日期:2015-09-01 00:00:00

  • Structure-activity and mechanism studies on silicon phthalocyanines with Plasmodium falciparum in the dark and under red light.

    abstract::Syntheses for the new photosensitizers HOSiPcOSi(CH3)2(CH2)3N(CH1)1 or 3(CH3)2, Pc 34 and Pc 25, have been developed and the order of activity of these photosensitizers and the previously reported photosensitizer Pc 4, HOSiPcOSi(CH3)2(CH2)3N(CH3)2, in the dark and with broad-band red light toward Plasmodium falciparum...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.1997.tb08656.x

    authors: Zhao XJ,Lustigman S,Li YS,Kenney ME,Ben-Hur E

    更新日期:1997-08-01 00:00:00

  • Deactivation of singlet molecular oxygen by organo-selenium compounds exhibiting glutathione peroxidase activity and by sulfur-containing homologs.

    abstract::The bimolecular rate constants (k) of quenching of molecular singlet oxygen 1O2 (1 delta g) by organo-selenium compounds exhibiting glutathione peroxidase activity and by sulfur analogs have been determined by time resolved phosphorescence detection of 1O2 in CD3OD and C6D6, with no solvent effect. The rate constants ...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.1991.tb02082.x

    authors: Scurlock R,Rougée M,Bensasson RV,Evers M,Dereu N

    更新日期:1991-11-01 00:00:00

  • Sub-lethal photodynamic damage to ARPE-19 cells transiently inhibits their phagocytic activity.

    abstract::Efficient phagocytosis of photoreceptor outer segments (POS) membranes by retinal pigment epithelium (RPE) plays a key role in biological renewal of these highly peroxidizable structures. Here, we tested whether photodynamic treatment, mediated by merocyanine 540 (MC 540), rose Bengal or a zinc-substituted chlorophyll...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.2010.00727.x

    authors: Olchawa M,Szewczyk G,Zareba M,Piłat A,Bzowska M,Mikołajczyk T,Sarna T

    更新日期:2010-07-01 00:00:00

  • The influence of water on the photophysical and photochemical properties of Piroxicam in AOT/iso-octane/water reversed micelles

    abstract::The photophysical properties of Piroxicam, a nonsteroidal anti-inflammatory drug (NSAID), were investigated at different pHext values in reversed micelles of Aerosol-OT (AOT) in iso-octane, using both steady-state and picosecond time-resolved fluorescence spectroscopy. In contrast with the very complex data obtained i...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:

    authors: Andrade SM,Costa SM,Pansu R

    更新日期:2000-04-01 00:00:00

  • Increasing Temperature Counteracts the Negative Effect of UV Radiation on Growth and Photosynthetic Efficiency of Microcystis aeruginosa and Raphidiopsis raciborskii.

    abstract::High temperature can promote cyanobacterial blooms, whereas ultraviolet radiation (UVR) can potentially depress cyanobacterial growth by damaging their photosynthetic apparatus. Although the damaging effect of UVR has been well documented, reports on the interactive effects of UV radiation exposure and warming on cyan...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/php.13377

    authors: Noyma NP,Mesquita MCB,Roland F,Marinho MM,Huszar VLM,Lürling M

    更新日期:2021-01-04 00:00:00

  • Investigation of photocatalytic effect of SnO2 nanoparticles synthesized by hydrothermal method on the decolorization of two organic dyes.

    abstract::Tin oxide nanoparticles about 4 nm in size were successfully synthesized using hydrothermal method. The photocatalytic activity of the particles was determined by the decolorization of malachite green (MG) and titanium yellow (TY) under UV light. 12 ppm of MG and TY were used for the solution with an initial volume of...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.2010.00863.x

    authors: Esen B,Yumak T,Sınağ A,Yıldız T

    更新日期:2011-03-01 00:00:00

  • In vitro photodynamic effects of lysyl chlorin p6: cell survival, localization and ultrastructural changes.

    abstract::The in vitro cell survival, localization and ultrastructural changes following irradiation were examined in 9L glioma cells sensitized with a new photosensitizer, lysyl chlorin p6 (LCP). In clonogenic assays, LCP was 10-100-fold more phototoxic than photofrin II on a microgram/mL basis. Lysyl chlorin p6 uptake was blo...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.1993.tb04948.x

    authors: Leach MW,Higgins RJ,Autry SA,Boggan JE,Lee SJ,Smith KM

    更新日期:1993-11-01 00:00:00

  • Wavelength dependence of DNA incision by a human ultraviolet endonuclease.

    abstract::The wavelength dependence of an ultraviolet irradiation of the DNA substrate for a human endonuclease was determined. Sites of DNA incision for all UVB and UVC wavelengths examined were at cytosines which were neither cyclobutane pyrimidine dimers nor 6-4'-(pyrimidin-2-one)pyrimidines. The optimal wavelengths for form...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.1989.tb04120.x

    authors: Gallagher PE,Weiss RB,Brent TP,Duker NJ

    更新日期:1989-03-01 00:00:00