Enhanced degradation of chlorinated ethylenes in groundwater from a paint contaminated site by two-stage fluidized-bed reactor.

Abstract:

:Groundwater, used in this study, contaminated predominantly with aromatic compounds, was biologically treated in a fluidized-bed reactor (FBR) with immobilized cells. The aromatics were completely decomposed, while cis-1,2-dichloroethylene (cis-DCE) and trichloroethylene (TCE) were decomposed only approximately 20% and 5%, respectively. In these studies a significant improvement of the decomposition efficiency for chlorinated ethylenes was achieved by utilizing cometabolism. Methanol (MeOH) and toluene were used as the substrate in the case of one-stage reactor (Single Reactor). MeOH (187 mg l(-1)) increased the decomposition efficiency up to 40% and 60% for cis-DCE and TCE, respectively, while toluene (20 mg l(-1)) increased the decomposition efficiency of cis-DCE to 92% and the decomposition efficiency of TCE to 76%. In the case of two-stage reactor system (Reactor 1 and Reactor 2), MeOH and methane (CH4) were used as the substrate. In this system, cells grown on MeOH or CH4 in the Reactor 1 were continuously fed into Reactor 2 and groundwater was fed into Reactor 2 only. When MeOH (384 mg l(-1) d(-1)) was used as substrate the decomposition efficiency of cis-DCE and TCE were 60% and 70%, respectively. Similar decomposition efficiency was observed for a small amount of CH4 (19.3 mg l(-1) d(-1)).

journal_name

Chemosphere

journal_title

Chemosphere

authors

Ohlen K,Chang YK,Hegemann W,Yin CR,Lee ST

doi

10.1016/j.chemosphere.2004.08.060

subject

Has Abstract

pub_date

2005-01-01 00:00:00

pages

373-7

issue

3

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(04)00729-5

journal_volume

58

pub_type

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