Abstract:
:Ionic liquid-containing semipermeable membrane devices (IL-SPMDs) were developed to monitor the polycyclic aromatic hydrocarbons in water. Uptake kinetics of naphthalene, 1-methylnaphthalene, phenanthrene, pyrene, chrysene by layflat low-density polyethylene tubing (15 cm x 2 cm) filled with 0.5 ml 1-butyl-3-methylimidazolium hexafluorophosphate ionic liquid were studied in a laboratory continuous-flow system for the duration of 16 days. The device concentration factors were in the range of 830-7800 for the studied PAHs. The kinetic parameters of IL/water partition coefficients, analytes uptake rate constants and sampling rates were estimated using mathematical models. These parameters were used in the field experiment to estimate the concentrations of the PAHs in Lanzhou section of Yellow River in China, with the result in comparison with that obtained by triolein-SPMD.
journal_name
Chemospherejournal_title
Chemosphereauthors
Zhao W,Han M,Dai S,Xu J,Wang Pdoi
10.1016/j.chemosphere.2005.06.041subject
Has Abstractpub_date
2006-03-01 00:00:00pages
1623-9issue
10eissn
0045-6535issn
1879-1298pii
S0045-6535(05)00866-0journal_volume
62pub_type
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