Abstract：
:Environmental catalysis also can refer to catalytic technologies for reducing emission of environmentally unacceptable compounds. Catalytic decomposition also is one of the cost-effective technologies to solve the troublesome volatile organic compounds. This study treated methyl isobutyl ketone (MIBK) by a commercial catalyst, Pt/gamma-Al(2)O(3), in an isothermal fixed bed differential reactor. The effects of O(2) and MIBK content in carrier gas on the catalysis's reaction rate are also observed. Three kinetic models, i.e. the Mars and van Krevelen model, Langmuir-Hinshelwood model and power-rate law were applied to best fit the experimental results. The results indicate that the kinetic behavior of MIBK oxidation with catalysis can be accounted for by using the rate expression of the Mars and van Krevelen model and Langmuir-Hinshelwood model. Kinetic parameters are also determined on the basis of the differential reactor data. The experimental results are compared with those of the model predicted.
journal_name
Chemospherejournal_title
Chemosphereauthors
Tseng TK,Chu H,Ko TH,Chaung LKdoi
10.1016/j.chemosphere.2005.03.009subject
Has Abstractpub_date
2005-10-01 00:00:00pages
469-77issue
4eissn
0045-6535issn
1879-1298pii
S0045-6535(05)00411-Xjournal_volume
61pub_type
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