Metabolism of uniconazole-P in water-sediment systems under illumination.

Abstract:

:Aerobic soil metabolism of uniconazole-P ([S]-E-1-[4-chlorophenyl]-4,4-dimethyl-2-[1,2,4-triazole-1-yl]-penten-3-ol) and the effect of illumination on metabolic profiles were studied in the water-sediment system when spiked to water. Uniconazole-P was gradually partitioned to the sediment with an aquatic half-life of 6.9 d in darkness with formation of bound residues. Illumination of the system from a xenon lamp (>290 nm) greatly accelerated the degradation of uniconazole-P via photoinduced isomerization between E- and Z-isomers with a subsequent intramolecular cyclization, and its aquatic half-life was greatly reduced to 0.6 d. Kinetic analysis based on compartment models suggested the possible contribution of photodegradation at the water-sediment interface, leading to more formation of the cyclized derivative in the sediment.

journal_name

Environ Toxicol Chem

authors

Kodaka R,Sugano T,Katagi T

doi

10.1897/05-116ra.1

subject

Has Abstract

pub_date

2006-02-01 00:00:00

pages

310-6

issue

2

eissn

0730-7268

issn

1552-8618

journal_volume

25

pub_type

杂志文章
  • Effects of carbaryl on green frog (Rana clamitans) tadpoles: timing of exposure versus multiple exposures.

    abstract::The majority of studies on pesticide impacts have evaluated the effects of single exposures. However, multiple exposures to a pesticide may be more prevalent. The objective of our study was to determine how multiple exposures versus single exposure at different times during development affected survival to metamorphos...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1897/02-401

    authors: Boone MD,Bridges CM

    更新日期:2003-11-01 00:00:00

  • Alternative methods for toxicity assessments in fish: comparison of the fish embryo toxicity and the larval growth and survival tests in zebrafish and fathead minnows.

    abstract::An increased demand for chemical toxicity evaluations has resulted in the need for alternative testing strategies that address animal welfare concerns. The fish embryo toxicity (FET) test developed for zebrafish (Danio rerio) is one such alternative, and the application of the FET test to other species such as the fat...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.2718

    authors: Jeffries MK,Stultz AE,Smith AW,Rawlings JM,Belanger SE,Oris JT

    更新日期:2014-11-01 00:00:00

  • Organochlorine compounds (polychlorinated biphenyls and pesticides) and polycyclic aromatic hydrocarbons in populations of Hexaplex trunculus affected by imposex in the lagoon of Venice, Italy.

    abstract::Concentrations of polychlorinated biphenyls (PCBs), organochlorine pesticides, and polycyclic aromatic hydrocarbons (PAHs) were measured in gastropods from the Lagoon of Venice, Italy. The visceral coil and the rest of the soft body of organisms (Hexaplex trunculus) sampled at two stations inside the lagoon and three ...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1897/05-202r.1

    authors: Maran C,Centanni E,Pellizzato F,Pavoni B

    更新日期:2006-02-01 00:00:00

  • Cytochrome P4501A biomarker indication of oil exposure in harlequin ducks up to 20 years after the Exxon Valdez oil spill.

    abstract::Hydrocarbon-inducible cytochrome P4501A (CYP1A) expression was measured, as ethoxyresorufin-O-deethylase (EROD) activity, in livers of wintering harlequin ducks (Histrionicus histrionicus) captured in areas of Prince William Sound, Alaska, USA, oiled by the 1989 Exxon Valdez spill and in birds from nearby unoiled area...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.129

    authors: Esler D,Trust KA,Ballachey BE,Iverson SA,Lewis TL,Rizzolo DJ,Mulcahy DM,Miles AK,Woodin BR,Stegeman JJ,Henderson JD,Wilson BW

    更新日期:2010-05-01 00:00:00

  • Relating the sediment phase speciation of arsenic, cadmium, and chromium with their bioavailability for the deposit-feeding polychaete Nereis succinea.

    abstract::We studied the influence of sediment geochemistry on bioavailability of As, Cd, and Cr in deposit-feeding polychaetes. Metal phase speciation in sediments was determined with a sequential extraction scheme, and assimilation efficiencies (AEs) of ingested metals were determined by pulse-chase feeding experiments using ...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.436

    authors: Baumann Z,Fisher NS

    更新日期:2011-03-01 00:00:00

  • Toxicity of two insecticides to California, USA, anurans and its relevance to declining amphibian populations.

    abstract::Contaminants have been associated with population declines of several amphibian species in California (USA). Pesticides from the Central Valley of California are transported by winds into the Sierra Nevada Mountains and precipitate into wet meadows where amphibians breed. The present study examined the chronic toxicit...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1897/08-336.1

    authors: Sparling DW,Fellers GM

    更新日期:2009-08-01 00:00:00

  • Bioconcentration and elimination of avermectin B1 in sturgeon.

    abstract::The bioconcentration and elimination of avermectin B1 in sturgeon muscle were investigated with high-performance liquid chromatography. Mean concentrations of 0.2 and 1 ng x ml(-1) in water were maintained for a 22-d exposure period. The concentrations of avermectin B1alpha in muscle tissues reached steady state withi...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1897/03-480.1

    authors: Shen J,Zhang Q,Ding S,Zhang S,Coats JR

    更新日期:2005-02-01 00:00:00

  • Lethal and behavioral impacts of diesel and fuel oil on the Antarctic amphipod Paramoera walkeri.

    abstract::Toxicity testing with Antarctic species is required for risk assessment of fuel spills in Antarctic coastal waters. The lethal and sublethal (movement behavior) sensitivities of adults and juveniles of the Antarctic amphipod Paramoera walkeri to the water accommodated fractions (WAFs) of 3 fuels were estimated in exte...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.3778

    authors: Brown KE,King CK,Harrison PL

    更新日期:2017-09-01 00:00:00

  • Uptake and depuration of cadmium, nickel, and lead in laboratory-exposed Tubifex tubifex and corresponding changes in the concentration of a metallothionein-like protein.

    abstract::Based on weight loss in water, 24 h is recommended for Tubifex tubifex gut clearance. Biota-to-sediment accumulation factors (BSAFs) in gut-cleared T. tubifex following six weeks of exposure to Cd-, Ni-, and Pb-spiked sediment were 12.4, 3.0, and 19.0, respectively. Tissue Ni concentrations peaked after 12 h, whereas ...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1897/02-415

    authors: Gillis PL,Dixon DG,Borgmann U,Reynoldson TB

    更新日期:2004-01-01 00:00:00

  • Estimation of polychlorinated biphenyl fugacity ratios.

    abstract::On the quantitative comparison of solubilities or vapor pressures of homologous series, the variation in the effect of crystal structure on solid properties may substantially influence the outcome of the comparison. Usually, the effect of this variation is eliminated by comparing values of the liquid state. The ratio ...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1897/06-083r.1

    authors: Van Noort PC

    更新日期:2006-11-01 00:00:00

  • Occurrence and distribution pattern of acidic pharmaceuticals in surface water, wastewater, and sediment of the Msunduzi River, Kwazulu-Natal, South Africa.

    abstract::The paucity of information on the occurrence of pharmaceuticals in the environment in African countries led the authors to investigate 8 acidic pharmaceuticals (4 antipyretics, 3 antibiotics, and 1 lipid regulator) in wastewater, surface water, and sediments from the Msunduzi River in the province of KwaZulu-Natal, So...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.3144

    authors: Agunbiade FO,Moodley B

    更新日期:2016-01-01 00:00:00

  • Effect of extraction conditions on deposit feeder in trace element solubilization in only a digestive fluid.

    abstract::In vitro extraction of sediments using digestive fluid of deposit-feeding invertebrates has been advocated as a measure of in vivo bioavailability, but the standard procedure used for the extractions alters fluid properties relative to in vivo conditions. In vivo fluid properties (redox potential [Eh], pH, dissolved o...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1897/03-483

    authors: Weston DP,Judd JR,Mayer LM

    更新日期:2004-08-01 00:00:00

  • Gene expression in caged fish as a first-tier indicator of contaminant exposure in streams.

    abstract::The development of sensitive, biologically based indicators of contaminant exposure (i.e., biomarkers) is an ongoing topic of research. These indicators have been proposed as a first-tier method of identifying contaminant exposure. The primary objective of this research was to implement a biomarker-based method of exp...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1897/05-137r.1

    authors: Roberts AP,Oris JT,Burton GA Jr,Clements WH

    更新日期:2005-12-01 00:00:00

  • Comparison of Alternative Methods for Bioaccumulation Assessment: Scope and Limitations of In Vitro Depletion Assays with Rainbow Trout and Bioconcentration Tests in the Freshwater Amphipod Hyalella azteca.

    abstract::Bioaccumulation assessment predominantly relies on the bioconcentration factor (BCF) as the sole decisive metric. The test guideline 305 by the Organisation for Economic Co-operation and Development (OECD) provides the standard procedure for deriving this in vivo fish BCF, which is not only expensive and labor-intensi...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.4791

    authors: Kosfeld V,Fu Q,Ebersbach I,Esser D,Schauerte A,Bischof I,Hollender J,Schlechtriem C

    更新日期:2020-09-01 00:00:00

  • The Gut Microbial Community Structure of the North American River Otter (Lontra canadensis) in the Alberta Oil Sands Region in Canada: Relationship with Local Environmental Variables and Metal Body Burden.

    abstract::The Alberta Oil Sands Region in Canada is home to one of the largest oil bitumen deposits in the world. The North American river otter (Lontra canadensis) is a top predator with a small home range and is sensitive to disturbances; it has been designated as a sentinel species for the potential impacts of the natural re...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.4876

    authors: Guo G,Eccles KM,McMillan M,Thomas PJ,Chan HM,Poulain AJ

    更新日期:2020-12-01 00:00:00

  • Glyphosate Accelerates the Proliferation of Microcystis aeruginosa, a Dominant Species in Cyanobacterial Blooms.

    abstract::Glyphosate is a commonly used herbicide known for its high performance in killing certain plants and grasses; however, its use is regulated due to its harmful effects on the aquatic environment. The present study investigated and compared the toxic mechanisms of glyphosate on Microcystis aeruginosa (a toxin-producing ...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.4942

    authors: Wang W,Jiang M,Sheng Y

    更新日期:2021-02-01 00:00:00

  • Valve closure response to uranium exposure for a freshwater bivalve (Corbicula fluminea): quantification of the influence of pH.

    abstract::Laboratory experiments were carried out to analyze the first valve closure response of a freshwater bivalve (Corbicula fluminea) exposed to uranium during a 5-h period. Experiments were performed in a well-defined artificial water at two pH values, 5.5 and 6.5, with a noninvasive method of valve recording. Sensitivity...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1897/02-604

    authors: Fournier E,Tran D,Denison F,Massabuau JC,Garnier-Laplace J

    更新日期:2004-05-01 00:00:00

  • Passive air sampling of polycyclic aromatic hydrocarbons and polychlorinated naphthalenes across Europe.

    abstract::This study presents concurrently sampled ambient air data for a range of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated naphthalenes (PCNs) at the continental scale. This was achieved with a passive air sampling system, by deploying polyurethane foam disks, which were prepared in one laboratory, sealed to...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1897/03-420

    authors: Jaward FM,Farrar NJ,Harner T,Sweetman AJ,Jones KC

    更新日期:2004-06-01 00:00:00

  • Analysis of estrogens in sediment from a sewage-impacted urban estuary using high-performance liquid chromatography/time-of-flight mass spectrometry.

    abstract::We describe a highly selective and sensitive method for determination of estrone (E1) and beta-estradiol (E2) in sediments, using high-performance liquid chromatography/time-of-flight (HPLC-ToF) mass spectrometry. The method involved sequential cleanup of sediment extracts over solid phase extraction cartridges, norma...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1897/04-167r.1

    authors: Reddy S,Brownawell BJ

    更新日期:2005-05-01 00:00:00

  • Relationships between polychlorinated biphenyls and health status in harbor porpoises (Phocoena phocoena) stranded in the United Kingdom.

    abstract::To investigate possible relationships between polychlorinated biphenyl (PCB) exposure and infectious disease mortality in harbor porpoises (Phocoena phocoena) in United Kingdom waters, summed blubber concentrations of 25 chlorobiphenyl congeners (sigma25CB) in healthy harbor porpoises that died of acute physical traum...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1897/03-663.1

    authors: Jepson PD,Bennett PM,Deaville R,Allchin CR,Baker JR,Law RJ

    更新日期:2005-01-01 00:00:00

  • Subcellular distribution of zinc in Daphnia magna and implication for toxicity.

    abstract::We examined the subcellular partitioning of zinc (Zn) in Daphnia magna both under acute and chronic exposures. In the acute Zn toxicity tests, the daphnids were exposed to different Zn concentrations for 48 h or to one lethal concentration (1,000 microg/L) for different durations (time to death for up to 47 h). Signif...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.229

    authors: Wang WX,Guan R

    更新日期:2010-08-01 00:00:00

  • Comparative toxicity of 20 herbicides to 5 periphytic algae and the relationship with mode of action.

    abstract::The authors used 5 species of periphytic algae to conduct toxicity assays of 20 herbicides. The 5 tested species represent riverine primary producers most likely to be affected by herbicides. A fluorescence microplate toxicity assay was used as an efficient and economical high-throughput assay. Toxicity characteristic...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.3150

    authors: Nagai T,Taya K,Yoda I

    更新日期:2016-02-01 00:00:00

  • Can we reduce the number of fish in the OECD acute toxicity test?

    abstract::OECD (Organisation for Economic Co-operation and Development) Guideline 203, Fish Acute Toxicity Test, states that the test should be performed using at least five concentrations in a geometric series with a separation factor not exceeding 2.2, with at least seven fish per concentration. However, the efficiency of thi...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.465

    authors: Rufli H,Springer TA

    更新日期:2011-04-01 00:00:00

  • Growth and survival of pacific coho salmon smolts exposed as juveniles to pesticides within urban streams in western Washington, USA.

    abstract::Pesticides are frequently detected in urban streams, with concentrations often exceeding those reported in surface waters within agricultural areas. The authors studied growth, survival, and return rates of coho salmon (Oncorhynchus kisutch) smolts exposed to a pesticide mixture ("cocktail") representative of the pest...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.2593

    authors: King KA,Grue CE,Grassley JM,Fisk RJ,Conquest LL

    更新日期:2014-07-01 00:00:00

  • Risk assessment of imidacloprid use in forest settings on the aquatic macroinvertebrate community.

    abstract::The isolated effects of a single insecticide can be difficult to assess in natural settings because of the presence of numerous pollutants in many watersheds. Imidacloprid use for suppressing hemlock woolly adelgid, Adelges tsugae (Annand) (Hemiptera: Adelgidae), in forests offers a rare opportunity to assess potentia...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.3887

    authors: Benton EP,Grant JF,Nichols RJ,Webster RJ,Schwartz JS,Bailey JK

    更新日期:2017-11-01 00:00:00

  • Cytotoxicity and aryl hydrocarbon receptor-mediated activity of n-heterocyclic polycyclic aromatic hydrocarbons: structure-activity relationships.

    abstract::Toxic effects of many persistent organic pollutants (e.g., polychlorinated biphenyls or polychlorinated dibenzo-p-dioxins and furans) are mediated via the aryl hydrocarbon receptor (AhR). Although polycyclic aromatic hydrocarbons (PAHs) and their derivatives also activate AhR, their toxic effects remain to be fully el...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1897/05-388r.1

    authors: Sovadinová I,Bláha L,Janosek J,Hilscherová K,Giesy JP,Jones PD,Holoubek I

    更新日期:2006-05-01 00:00:00

  • Plasma concentrations of organohalogenated pollutants in predatory bird nestlings: associations to growth rate and dietary tracers.

    abstract::The extent to which persistent organic pollutants (POPs) with different physicochemical properties originated from the food (dietary input) was assessed in raptor nestlings. Lipophilic polychlorinated biphenyl (PCB) 153, 1-dichloro-2,2-bis(p-chlorophenyl)ethylene (p,p'-DDE), and hexachlorobenzene (HCB), and protein-bo...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.2329

    authors: Bustnes JO,Bårdsen BJ,Herzke D,Johnsen TV,Eulaers I,Ballesteros M,Hanssen SA,Covaci A,Jaspers VL,Eens M,Sonne C,Halley D,Moum T,Nøst TH,Erikstad KE,Ims RA

    更新日期:2013-11-01 00:00:00

  • Effects of ethynylestradiol on the reproductive physiology in zebrafish (Danio rerio): time dependency and reversibility.

    abstract::Environmental pollution with natural or synthetic estrogens may pose a serious threat to reproduction of wildlife species. This study describes the effects of 17-alpha-ethynylestradiol (EE2) on fish reproductive organs in a laboratory model. Adult zebrafish were semistatically exposed to nominal concentrations of 0, 1...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:

    authors: Van den Belt K,Wester PW,van der Ven LT,Verheyen R,Witters H

    更新日期:2002-04-01 00:00:00

  • Comparing the effects of nanosilver size and coating variations on bioavailability, internalization, and elimination, using Lumbriculus variegatus.

    abstract::As the production and applications of silver nanoparticles (AgNPs) increase, it is essential to characterize fate and effects in environmental systems. Nanosilver materials may settle from suspension; therefore, the authors' objective was to utilize environmentally relevant bioassays and study the impact, bioaccumulat...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.2278

    authors: Coleman JG,Kennedy AJ,Bednar AJ,Ranville JF,Laird JG,Harmon AR,Hayes CA,Gray EP,Higgins CP,Lotufo G,Steevens JA

    更新日期:2013-09-01 00:00:00

  • The effects of salinity exposure on multiple life stages of a common freshwater mussel, Elliptio complanata.

    abstract::There is growing concern over the effects of increased salinization on freshwater organisms, which are largely unknown for unionid mussels. Adult and larval Elliptio complanata were exposed to low-level salt concentrations to determine the effects on mussel survival, physiology, and reproduction. Adults were exposed t...

    journal_title:Environmental toxicology and chemistry

    pub_type: 杂志文章

    doi:10.1002/etc.2381

    authors: Blakeslee CJ,Galbraith HS,Robertson LS,St John White B

    更新日期:2013-12-01 00:00:00