Fast atom bombardment: evidence of disproportionation and recombination of a synthetic porphyrin in the matrix.

Abstract:

:In addition to dimerization and polymerization of samples as previously suggested, it appears that during FAB-MS, reactions in the sample matrix can occur to yield new compounds that are recombinations of molecular fragments. This type of reaction may be especially critical to the integrity of peptide sequencing using FAB, since the reactions cited in this report involve the formation and rupture of amides or peptide bonds.

authors

Kurlansik L,Williams TJ,Campana JE,Green BN,Anderson LW,Strong JM

doi

10.1016/0006-291x(83)90331-5

subject

Has Abstract

pub_date

1983-03-16 00:00:00

pages

478-83

issue

2

eissn

0006-291X

issn

1090-2104

pii

0006-291X(83)90331-5

journal_volume

111

pub_type

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