Investigations of polymer dynamics in nanoporous media by field cycling NMR relaxometry and the dipolar correlation effect.

Abstract:

:The chain dynamics of short-chain perfluoropolyether melts confined in Vycor nanoporous media has been characterized by field cycling nuclear magnetic resonance relaxometry and the dipolar correlation effect. The slowdown of motions under confinement, leading to larger residual dipolar couplings, has been probed by looking at the quotient of stimulated and primary echoes. Using field cycling relaxometry, it has been shown that there is strong evidence of reptation-like motion, even for such short-chain polymers as shown by the frequency and molecular weight dependences of the spin-lattice relaxation time.

journal_name

Magn Reson Imaging

authors

Kausik R,Fatkullin N,Hüsing N,Kimmich R

doi

10.1016/j.mri.2006.11.018

subject

Has Abstract

pub_date

2007-05-01 00:00:00

pages

489-92

issue

4

eissn

0730-725X

issn

1873-5894

pii

S0730-725X(06)00411-5

journal_volume

25

pub_type

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