Decontamination of soil containing POPs by the combined action of solid Fenton-like reagents and microwaves.

Abstract:

:The effect on halogenated aromatics of solid, non-toxic oxidants such as sodium percarbonate and the urea/hydrogen peroxide complex (Fenton-like reagents) was investigated. A microwaves-assisted, solvent-free method for soil decontamination is presented. It marks a considerable advance in the search of more efficient, environment-friendly procedures for the degradative oxidation of persistent organic pollutants. Residual pollutants in treated soil samples were determined by GC/MS analysis after solvent extraction or direct thermal desorption. Results showed that 4-chloronaphthol, 2,4-dichlorophenoxyacetic acid and p-nonylphenol had been degraded completely, 2,4-dibromophenol to a large extent.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Cravotto G,Di Carlo S,Ondruschka B,Tumiatti V,Roggero CM

doi

10.1016/j.chemosphere.2007.05.078

subject

Has Abstract

pub_date

2007-10-01 00:00:00

pages

1326-9

issue

8

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(07)00737-0

journal_volume

69

pub_type

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