Event monitoring of herbicides with naked and membrane-covered Empore disk integrative passive sampling devices.

Abstract:

:Subsequent to an initial wet season flood event in the Brisbane River, Australia, both fast (naked disk) and slow (membrane-covered) variants of SDB-RPS Empore disk passive sampling devices were deployed with an automated grab sampling program. A trend increase in the aquatic dissolved concentrations of diuron and simazine was observed over a 10-day period. Kinetic and equilibrium parameters for each sampler were calculated based on the dynamic concentration. Absolute percent difference for duplicate passive samples was <10% in the fast and <25% in the slow samplers. For kinetic sampling, significantly shortened integrative periods are available with the fast compared with the slow variant, with higher sampling rates offering improved detection limits. The study demonstrates a method for determining kinetic parameters of passive samplers in a variable concentration field deployment, and illustrates the differences in quality between active and passive data, in terms of capturing changes in concentration associated with rainfall events.

journal_name

Mar Pollut Bull

authors

Stephens BS,Kapernick AP,Eaglesham G,Mueller JF

doi

10.1016/j.marpolbul.2009.04.012

subject

Has Abstract

pub_date

2009-08-01 00:00:00

pages

1116-1122

issue

8

eissn

0025-326X

issn

1879-3363

pii

S0025-326X(09)00150-7

journal_volume

58

pub_type

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