Sensitive Determination of Acetochlor, Alachlor, Metolachlor and Fenthion Utilizing Mechanical Shaking Assisted Dispersive Liquid-Liquid Microextraction Prior to Gas Chromatography-Mass Spectrometry.

Abstract:

:A green, sensitive and accurate dispersive liquid-liquid microextraction (DLLME) method was used to preconcentrate four selected pesticides in dam lake water samples for determination by gas chromatography-mass spectrometry (GC-MS). Conditions of the DLLME method were comprehensively investigated and optimized according to type/volume of extraction solvent, type/volume of dispersive solvent, and type/period of mixing. The developed method was validated according to the limits of detection and quantitation, accuracy, precision and linearity. Under the optimum conditions, limit of detection values calculated for alachlor, acetochlor, metolachlor and fenthion were 1.7, 1.7, 0.2 and 7.8 µg/kg (mass based), respectively. The method recorded 202, 104, 275 and 165 folds improvement in detection power values for acetochlor, alachlor, metolachlor and fenthion, respectively, when compared with direct GC-MS measurements. In order to evaluate the accuracy of the developed method, real sample application with spiking experiments was performed on dam lake water samples, and satisfactory percent recovery results in the range of 81%-120% were obtained.

authors

Bodur S,Borahan T,Ates N,Bakırdere S

doi

10.1007/s00128-020-02965-z

subject

Has Abstract

pub_date

2020-09-01 00:00:00

pages

460-467

issue

3

eissn

0007-4861

issn

1432-0800

pii

10.1007/s00128-020-02965-z

journal_volume

105

pub_type

杂志文章
  • Spatial Variability and Source Apportionment of Aliphatic Hydrocarbons in Sediments from the Typical Coal Mining Area.

    abstract::Fifty-four surface sediments from the typical coal mining area were analyzed for pristane, phytane and C8-C40 n-alkanes using gas chromatography-mass spectrometry (GC-MS). The spatial distribution, homolog profiles and source apportionment of aliphatic hydrocarbons were investigated. Bimodal distribution pattern, cent...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-020-02938-2

    authors: Wang S,Liu G,Yuan Z,Liu Y,Lam PKS

    更新日期:2020-08-01 00:00:00

  • Batch Adsorption and Column Leaching Studies of Aniline in Chinese Loess Under Different Hydrochemical Conditions.

    abstract::Through batch adsorption and column leaching experiments, this study aimed to investigate the adsorption and transport behavior of aniline in loess and related mechanism under different hydrochemical conditions. Batch experiments results indicated that aniline adsorption reached equilibrium after about 120 min, and th...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-020-02830-z

    authors: Zhou B,Zhang Z,Wang S,Wu Y,Hu S,Sun R

    更新日期:2020-04-01 00:00:00

  • The Protective Role of Thiourea on Leuciscus cephalus Exposed to Sublethal Doses of Pendigan 330EC (Pendimethalin) Herbicide.

    abstract::The aim of the study was to investigate the protective role of thiourea on the physiological, hematological, biochemical and histopathological parameters of Leuciscus cephalus exposed to sublethal concentration of Pendigan 330 EC herbicide. The animals were divided in four experimental groups (control, animals subject...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-016-1834-3

    authors: Paunescu A,Zgurschi G,Soare LC,Man GM,Brinzea G,Fierascu RC,Fierascu I,Ponepal MC

    更新日期:2016-08-01 00:00:00

  • Presence of polycyclic aromatic hydrocarbons (PAHs) in top soils from rural terrains in Mexico City.

    abstract::A soil survey was carried out to determine the levels and sources and concentrations of 16 polycyclic aromatic hydrocarbons in 2 semi-rural terrains in Mexico City (Tlahuac and Milpa Alta) during 2008-2009. PAH determination was made by Soxhlet extraction and chromatographic clean-up with final analysis by gas chromat...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-011-0434-5

    authors: Ortiz R,Vega S,Gutiérrez R,Gibson R,Schettino B,Ramirez Mde L

    更新日期:2012-03-01 00:00:00

  • Dispersion and ecological risk assessment of di (2-ethylhexyl) phthalate (DEHP) in the surface waters of Thailand.

    abstract::Previous environmental monitoring indicated that di (2-ethylhexyl) phthalate (DEHP) was released into the environment. This study collected both water and sediment samples from the source area, deltas of major rivers discharging into the Gulf of Thailand, and 2 tourist beaches from February 2007-August 2009. The analy...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-010-9980-5

    authors: Sirivithayapakorn S,Thuyviang K

    更新日期:2010-05-01 00:00:00

  • Total Suspended Solids Effects on Freshwater Lake Biota Other than Fish.

    abstract::Protective benchmarks for the effects of total suspended solids (TSS) on freshwater aquatic biota primarily focus on fish; whether these benchmarks will also protect their prey or co-existing lower trophic level aquatic biota was uncertain. We conducted an extensive literature review of TSS effects on those organisms ...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章,评审

    doi:10.1007/s00128-017-2154-y

    authors: Chapman PM,Hayward A,Faithful J

    更新日期:2017-10-01 00:00:00

  • "No-effect-level" of malathion (o,o'-dimethyl dithiophosphate of diethyl mervaptosuccinate) in Bubalus bubalis.

    abstract::An oral dose of 0.5 mg/kg/day malathion continuously administered for one year has been investigated to produce no change in biochemical (RChE, PChE, aspartate- and alanine aminotransferases, blood glucose, serum urea and plasma total proteins) or haematological (Hb, PCV, tRBC and tWBC) parameters and, therefore, cons...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/BF01683606

    authors: Gupta RC,Paul BS

    更新日期:1978-12-01 00:00:00

  • Antioxidant and antitranspirant protection of apple foliage against ozone injury.

    abstract::Visible injury to apple foliage from exposure to ozone includes brown stippling on lower leaf surfaces and a light yellow mosaic on upper surfaces. Histologically, chlorophyll is destroyed and palisade and spongy mesophyll cells collapse following disintegration of their protoplasm. Foliar spray applications of the an...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/BF01812646

    authors: Elfving DC,Gilbert MD,Edgerton LJ,Wilde MH,Lisk DJ

    更新日期:1976-03-01 00:00:00

  • Effect of Ziram, Thiram, and Dithane M-45 on bone marrow cells of mice-assessed by micronucleus test.

    abstract::Micronucleus test is an extensively used protocol to assess the mutagenicity of environmental chemicals. This was developed by Schmid and his co-workers (Matter and Schmid, 1971; Ledebur and Schmid, 1973). The micronucleus test is simple, quick and as sensitive as the chromosome aberration analysis. It is based on the...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s001289900029

    authors: Hemavathi E,Rahiman MA

    更新日期:1996-02-01 00:00:00

  • Quantitative study of Leydig cell populations in mice exposed to low doses of cadmium.

    abstract::Leydig cell morphological changes were evaluated using morphometric and stereological methods in male mice exposed to low doses of cadmium. A possible reversibility of the changes after cadmium withdrawal was also considered. Nuclear morphological parameters and stereological densities of the Leydig cell population we...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-009-9700-1

    authors: Blanco A,Moyano MR,Molina AM,Blanco C,Flores-Acuña R,García-Flores JR,Espada M,Monterde JG

    更新日期:2009-06-01 00:00:00

  • Powder characteristics and biocidal activity of the MnOx-WO₃-TiO₂ system synthesized by a sol-gel method for antifouling agents.

    abstract::The TiO₂-system powders were investigated with respect to the crystallinity and the microstructure. The biocidal activity increased from TiO₂ to binary MnOx-TiO₂ to ternary MnOx-WO₃-TiO₂ against Vibrio fischeri as a model of Gram-negative bacteria. Anatase and rutile TiO₂ were not toxic even at 200 mg/L, but anatase h...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-013-1028-1

    authors: Shin B,Kim S,Lee H,Park H

    更新日期:2013-08-01 00:00:00

  • Decreased Cell-Mediated Immune Response in Bosk's Fringe-Toed Lizards (Acanthodactylus boskianus) Inhabiting an Industrialized Area in Southern Tunisia.

    abstract::Lizards increasingly are recognized as suitable contaminant biomonitors in terrestrial ecosystems. Previously, we have shown that Bosk's fringe-toed lizards (Acanthodactylus boskianus) living close to the Gabès-Ghannouche industrial complex for fertilizer and acid production in southern Tunisia were contaminated by he...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-020-02943-5

    authors: Nasri I,Hammouda A,Belliure J,Selmi S

    更新日期:2020-09-01 00:00:00

  • A rapid and sensitive method for gas chromatographic analysis of the selective piscicide, "Squaxon".

    abstract::"Squaxon" (1,1'methylenedi- 2 napthol; bis (2 hydroxy-1- naphthyl) methane) was discovered by MacPhee and Ruelle (1968, 1969) to exhibit piscicidal properties that are highly species specific. The chemical is lethal to the Northern (Ptychocheilus oregonensis) and the Umpqua (P. umpquae) squawfish, freshwater cyprinids...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/BF01685154

    authors: Gabica J,Benson WW,Watson M

    更新日期:1976-02-01 00:00:00

  • Aquatic toxicity assessment of esters towards the Daphnia magna through PCA-ANFIS.

    abstract::The widespread production of esters combined with their ability to migrate in different compartments, makes their environmental toxicity important. In this background, the multivariate image analysis-quantitative structure-toxicity relationship (MIA-QSTR) method coupled to principal component analysis-adaptive neuro-f...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-013-1066-8

    authors: Asadollahi-Baboli M

    更新日期:2013-10-01 00:00:00

  • Contrasting sensitivities to fluoride toxicity between juveniles and adults of the aquatic snail Potamopyrgus antipodarum (Hydrobiidae, Mollusca).

    abstract::In contrast to aquatic vertebrates, there is scarce available information on the contrasting tolerance to fluoride of different life stages and/or sizes of aquatic invertebrates. The purpose of this study was to assess the likely differences in sensitivity between juveniles and adults of the aquatic snail Potamopyrgus...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-011-0241-z

    authors: Aguirre-Sierra A,Alonso A,Camargo JA

    更新日期:2011-05-01 00:00:00

  • A simple allometric diffusion-based biokinetic model to predict Cu(II) uptake across gills of freshwater clam Corbicula fluminea.

    abstract::The purpose of this study was to link Fick's type mass transfer and biokinetics together with Michaelis-Menten kinetics to arrive at a simple predictive framework for quantifying biouptake mechanisms in gills of freshwater clam Corbicula fluminea exposed to Cu(II). A diffusion-based Cu(II) influx and permeability can ...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-010-0011-3

    authors: Chen WY,Lin CM,Ju YR,Liao CM

    更新日期:2010-06-01 00:00:00

  • Studies on combined effects of organophosphates and heavy metals in birds. I. Plasma and brain cholinesterase in coturnix quail fed methyl mercury and orally dosed with parathion.

    abstract::We found that mercury potentiated the toxicity and biochemical effects of parathion. Male Coturnix quail (Coturnix coturnix japonica) were fed a sublethal concentration of morsodren (4 ppm as methyl mercury) for 18 weeks. This resulted in an accumulation of 21.0 ppm of mercury in the liver and 8.4 ppm in the carcass. ...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/BF01685332

    authors: Dieter MP,Ludke JL

    更新日期:1975-03-01 00:00:00

  • Occurrence of glyphosate in surface waters of Southern Ontario.

    abstract::Glyphosate in surface waters of southern Ontario (Canada) was studied over a 2-year period. A small percentage of samples exhibited glyphosate concentrations greater than the analytical limit of quantitation (17 microg a.e./L), and the maximum concentration of glyphosate measured was 40.8 microg/L. No samples of rough...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-008-9373-1

    authors: Struger J,Thompson D,Staznik B,Martin P,McDaniel T,Marvin C

    更新日期:2008-04-01 00:00:00

  • Effects of fertilizer-urea on growth, photosynthetic activity and microcystins production of Microcystis aeruginosa isolated from Dianchi Lake.

    abstract::Urea is the most frequently applied nitrogen (N) fertilizer in agriculture, while its loss is assumed triggering algal blooms in adjacent water bodies. In this context the present study assessed the growth, photosynthetic activity as well as toxin production of Microcystis aeruginosa at different urea concentrations (...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-014-1217-6

    authors: Huang W,Bi Y,Hu Z

    更新日期:2014-05-01 00:00:00

  • Joint Toxicity of Lead, Chromium, Cobalt and Nickel to Photobacterium phosphoreum at No Observed Effect Concentration.

    abstract::Joint toxicity of Pb2+, Cr3+, Co2+ and Ni2+ toward Photobacterium phosphoreum (Ph. phosphoreum) at the no observed effect concentration (NOEC) was determined through a factorial experiment. A neural network model was designed according to experimental results and employed for toxicity prediction of unary, binary, tern...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-015-1568-7

    authors: Zeng Y,Wang L,Jiang L,Cai X,Li Y

    更新日期:2015-08-01 00:00:00

  • Accumulation of Heavy Metals in Some Organs in Barbel and Chub from Crn Drim River in the Republic of Macedonia.

    abstract::Heavy metal pollution of aquatic ecosystems is worldwide problem with consequences on the aquatic organisms. The concentrations of selected heavy metals (Fe, Mn, Zn, Cu, Cd and Pb) were determined in liver, kidney, gills, muscle and bone of barbel (Barbus rebeli) and chub (Squalius squalius) from the river Crn Drim in...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-018-2409-2

    authors: Jordanova M,Hristovski S,Musai M,Boškovska V,Rebok K,Dinevska-Ќovkarovska S,Melovski L

    更新日期:2018-09-01 00:00:00

  • Simulated rainfall removal of tricyclazole sprayed on rice foliage.

    abstract::Two rainfall simulations of 30 mm h(-1), with 48-h interval between two simulations, were performed on rice lysimeters at 24, 48, and 72 h after being sprayed with tricyclazole. In the first simulated rainfall, wash-off concentration of tricyclazole was significant irrespective of the interval between the spray time a...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-008-9431-8

    authors: Phong TK,Nhung DT,Yamazaki K,Takagi K,Watanabe H

    更新日期:2008-05-01 00:00:00

  • Movement of mirex from sediment and uptake by the hogchoker, Trinectes maculatus.

    abstract::Mirex contaminated sediments of the static test retained virtually all of the insecticide over a 4 week period. About 40% of the initial concentration was lost from the sediment under constant flow conditions. Mirex in water was directly related to levels of mirex in sediment. Mirex in water reached an equilibrium dur...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/BF01685244

    authors: Kobylinski GJ,Livingston RJ

    更新日期:1975-12-01 00:00:00

  • Effects of Urban-rural Atmospheric Environment on Heavy Metal Accumulation and Resistance Characteristics of Pinus tabulaeformis in Northern China.

    abstract::The washed and unwashed current (C) and previous year (C + 1) needles, branches and top soils of Pinus tabulaeformis trees were sampled at five sites Haitai industrial district (HT), Puji River (PJ), Fukang road (FK), Residential area (RA) and Baxian Mountain (BX) in Tianjin along an urban-rural gradient and analyzed ...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-019-02548-7

    authors: Zhao R,Yang T,Shi C,Zhou M,Chen G,Shi F

    更新日期:2019-03-01 00:00:00

  • Decadal Changes in Trace Metal Concentrations in Upland Headwater Lakes.

    abstract::The objective of this study was to assess the current chemistry of trace elements in upland headwater lakes in Ireland and determine their trends during the last decade in response to decreasing emissions. Twenty-nine upland lakes were sampled in 2017-2018; 19 were previously sampled in 2007-2008. The 2017-2018 sample...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-020-02984-w

    authors: Nelson SAM,Aherne J

    更新日期:2020-11-01 00:00:00

  • Total mercury content in cultured oysters from NW Mexico: health risk assessment.

    abstract::The total mercury (Hg) content of the soft tissues of cultured oysters of the genus Crassostrea obtained during the dry and rainy seasons at sampling sites of NW Mexico with different degrees of urbanization, was determined by cold vapor atomic absorption spectrophotometry. Hg levels ranged from 0.05 to 0.37 µg/g (dry...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-014-1430-3

    authors: Delgado-Álvarez CG,Ruelas-Inzunza J,Osuna-López JI,Voltolina D,Frías-Espericueta MG

    更新日期:2015-02-01 00:00:00

  • Multiresidue analysis of organochlorine pesticides in milk, egg and meat by GC-ECD and confirmation by GC-MS.

    abstract::A multiresidue method was developed and optimized for the quantification of organochlorine pesticides (OCPs) in milk, egg and meat samples. Sample extraction was performed by adopting QuEChERS principle and the extracts were cleaned-up dispersive solid-phase extraction with primary secondary amine after salting out wi...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-012-0789-2

    authors: Selvi C,Paramasivam M,Rajathi DS,Chandrasekaran S

    更新日期:2012-11-01 00:00:00

  • Bioaccumulation and distribution of metals in sediments and Avicenna marina tissues in the Hara Biosphere Reserve, Iran.

    abstract::The metal pollution in Sediments and Avicenna marina tissues in the Hara Biosphere Reserve was monitored for Lead (Pb), Cadmium (Cd), and Nickel (Ni) with atomic absorption spectrometer. The results showed that the mean concentration of Pb, Cd, and Ni in the water and sediments were much higher than the recommended th...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-012-0751-3

    authors: Nowrouzi M,Pourkhabbaz A,Rezaei M

    更新日期:2012-10-01 00:00:00

  • Geo-Accumulation Indices of Heavy Metals in Soil and Groundwater of Kanpur, India Under Long Term Irrigation of Tannery Effluent.

    abstract::Soil and groundwater from long-term (>50 years) tannery effluent irrigated areas of Kanpur were analyzed and significant buildup of heavy metals such as Cr, Ni, Cd, Pb, Zn, and As in the range of 252-972, 23-30, 2.3-14.1, 23.7-58.8, 138-338 and 6.8-11 mg kg-1, respectively in soil was found. Few groundwater samples in...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-016-1983-4

    authors: Dotaniya ML,Meena VD,Rajendiran S,Coumar MV,Saha JK,Kundu S,Patra AK

    更新日期:2017-05-01 00:00:00

  • Fluxes and influencing factors of ammonia emission from monosodium glutamate production in Shenyang, China.

    abstract::In order to solve environmental problems resulting from ammonia released into the atmosphere, the emission of ammonia contamination from monosodium glutamate (MSG) production was quantitatively observed, and the relationships with relevant influencing factors (ammonium-N, nitrate/nitrite-N and pH) were statistically a...

    journal_title:Bulletin of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00128-010-0085-y

    authors: Liu R,Zhou Q

    更新日期:2010-09-01 00:00:00