Magnetic nanoadsorbents with amino-functionalized polymers for magnetic separation removal of copper ion.

Abstract:

:The adsorption of copper ions on magnetic adsorbents with amino-functionalized polymers (DETA/SiO2/Fe3O4) has been investigated. In addition, the structure and characterization of magnetic nano-adsorbents were confirmed using FTIR, TGA, TEM, VSM, and BET. The results showed that DETA/SiO2/Fe3O4 exhibited a paramagnetic behaviour and could be easily recovered and quickly separated from a suspension solution. The optimum pH level for adsorption of copper ions was proposed to be in the range of pH level from 5 to 6, and the maximum adsorption capacity (qm ) and activated energy (Ea ) at 298 K was 13.459 mg g-1 and 22.421 kJ mol-1, respectively. The copper ions adsorption behaviour by DETA/SiO2/Fe3O4 was in good agreement with the Langmuir isotherm rather than Freundlich equation. A pseudo-second-order model could best describe the adsorption kinetics, and the optimal condition of copper ions desorption (99%) from DETA/SiO2/Fe3O4 was provided by 1.0 M HNO3. The novel magnetic nano-adsorbents could not only be regenerated by HNO3 solutions but also reused by the recovery of magnetic force without requiring further downstream treatment.

journal_name

Environ Technol

journal_title

Environmental technology

authors

Chen HW,Chang SH

doi

10.1080/09593330.2020.1805027

subject

Has Abstract

pub_date

2020-08-13 00:00:00

pages

1-10

eissn

0959-3330

issn

1479-487X

pub_type

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