Abstract：
:Fragrances such as OTNE (marketed as Iso-E-Super®) and bactericides such as triclosan (marketed as Igrasan) are present in waste water and thus finally sorbed to sewage sludge. With that sludge they can reach agricultural fields where they potentially can undergo photodegradation processes. In this study the photodegradation of OTNE and triclosan on dried loamy sand was measured under artificial sunlight conditions in laboratory experiments. These compounds were artificially added with concentrations of 1 μg g(-1) on pre-rinsed dried loamy sand. The decrease in concentration with light irradiation was measured for 32d in comparison to soil samples without light irradiation. The estimated light source intensity was 27 W m(-2). Within the experiment, the apparent half-life was 7 and 17d for OTNE and triclosan respectively. The decrease did not simply follow first-order kinetics. The apparent rate constant decreased in the latter stage of reaction, suggesting that part of the chemicals were inaccessible for degradation. Two models, i.e., a diffusion-limited model, and a light penetration-limited model, were used in comparison to the measured data to explain the observed degradation limitations in the latter stages of the experiments. Comparing the hereby obtained model parameters with estimated physico-chemical parameters for the soil and the two chemical compounds, the light penetration-limited model, in which the degradation in the soil surface layer is assumed to be limited due to the shading effect of light in the upper thin soil layer, showed to be the most realistic in describing the photodegradation.
journal_name
Chemospherejournal_title
Chemosphereauthors
Ozaki N,Bester K,Moldrup P,Henriksen K,Komatsu Tdoi
10.1016/j.chemosphere.2011.03.006subject
Has Abstractpub_date
2011-06-01 00:00:00pages
1475-9issue
11eissn
0045-6535issn
1879-1298pii
S0045-6535(11)00275-Xjournal_volume
83pub_type
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