Abstract：
:We developed a novel polymer type sulfoxide-modified solid phase enabling to achieve selective separation of polychlorinated biphenyls (PCBs) from insulation oil. In this study, firstly we prepared base-polymer based on the concept of the molecular imprinting to capture PCBs in selectively, then, the sulfoxide groups were modified on the pore surface of base-polymers by changing preparation methods. As results of liquid chromatographic analyses for the polymers as columns, the base-polymer prepared by xylene as a porogenic solvent showed selective retention ability for chlorinated aromatic compounds by the porogen imprinting effect. Additionally, the polymer-type sulfoxide solid phases showed highly retention ability for PCBs by increasing amount of introduced sulfoxide groups. Consequently, the results of separation of PCBs comparing to insulation oil suggested that the prepared solid phase can be used for the selective separation of PCBs at the same level as a commercially available media utilized for the regulated method.
journal_name
Chemospherejournal_title
Chemosphereauthors
Tominaga Y,Kubo T,Kobayashi A,Yasuda K,Kato K,Hosoya Kdoi
10.1016/j.chemosphere.2012.05.037subject
Has Abstractpub_date
2012-10-01 00:00:00pages
378-82issue
4eissn
0045-6535issn
1879-1298pii
S0045-6535(12)00658-3journal_volume
89pub_type
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