Novel Collimated Beam Setup to Study the Kinetics of VUV-Induced Reactions.

Abstract:

:Vacuum UV (VUV) process is an incipient advanced oxidation process, which can be used for water treatment. This process relies on the formation of hydroxyl radicals through the VUV-induced photolysis of water. In particular, the use of ozone-generating mercury vapor lamps, which emit 10% of the radiation at 185 nm and 90% at 254 nm, is showing very promising results for the degradation of micropollutants. The kinetics of VUV process has been studied in batch- and flow-through reactors, but the effect of 254 and 185 nm photons cannot be isolated, mass transfer resistances can take place and the interpretation of the results is complex. In this technical note, a new VUV collimated beam to conduct kinetic tests is presented, which offers several advantages: (1) it allows the irradiation of samples with 185, 254 nm photons, or both, (2) the concentration of reagents is uniform in the reaction volume and (3) it allows to change the fluence rate by changing the distance between the lamp and the photoreactor. Details of the geometry are presented, as well as an analysis of the collimation and uniformity of the radiation of the new VUV-collimated beam setup.

journal_name

Photochem Photobiol

authors

Duca C,Imoberdorf G,Mohseni M

doi

10.1111/php.12157

subject

Has Abstract

pub_date

2014-01-01 00:00:00

pages

238-40

issue

1

eissn

0031-8655

issn

1751-1097

journal_volume

90

pub_type

杂志文章
  • Multidimensional reaction coordinate for the excited-state H-atom transfer in perylene quinones: importance of the 7-membered ring in hypocrellins A and B.

    abstract::The excited-state intramolecular H-atom transfer reactions of hypocrellins B and A are compared by using time-resolved absorption and fluorescence upconversion techniques. The hypocrellin B photophysics are well described by a simple model involving one ground-state species and excited-state forward and reverse H-atom...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:

    authors: Datta A,Smirnov AV,Wen J,Chumanov G,Petrich JW

    更新日期:2000-02-01 00:00:00

  • Cyclobutane dimers and (6-4) photoproducts in human cells are mended with the same patch sizes.

    abstract::The size of excision repair patches corresponding to excision of (6-4) pyrimidine-pyrimidone photoproducts and (5-5, 6-6) cyclobutane dimers have been independently determined by using bromodeoxyuridine substitution and density increases in isopycnic gradients of small DNA fragments. The two classes of photoproducts w...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.1991.tb02033.x

    authors: Cleaver JE,Jen J,Charles WC,Mitchell DL

    更新日期:1991-09-01 00:00:00

  • Immobilized organic photosensitizers with versatile reactivity for various visible-light applications.

    abstract::Various photosensitizers were grafted by conventional peptide coupling methods to functionalized silica with several macroscopic shapes (powders, films) or embedded in highly transparent and microporous silica xerogel monoliths. Owing to the transparency and free-standing shape of the monoliths, the transient species ...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/php.12166

    authors: Ronzani F,Saint-Cricq P,Arzoumanian E,Pigot T,Blanc S,Oelgemöller M,Oliveros E,Richard C,Lacombe S

    更新日期:2014-03-01 00:00:00

  • Reactions of excited states of phenoxazin-3-one dyes with amino acids.

    abstract::The interaction with amino acids of the excited states of the N-oxide resazurin and its deoxygenation product resorufin, has been studied in aqueous solution at pH 7.5. Steady-state and time-resolved studies show that the fluorescence is quenched by amino acids. Complexation of the dyes in the ground state with aromat...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1562/2004-10-12-RA-342

    authors: Villegas ML,Bertolotti SG,Previtali CM,Encinas MV

    更新日期:2005-07-01 00:00:00

  • 8-methoxypsoralen plus UVA induces the 72 kDa heat shock protein in organ-cultured normal human skin.

    abstract::The proteins induced by heat and other stressors, called heat shock proteins (HSP) or stress proteins, are considered to play a general role in protection from cellular injury. Exposure to UVA (320-400 nm) following application of 8-methoxypsoralen (8-MOP), termed PUVA is commonly used in the field of dermatology. In ...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.1993.tb04974.x

    authors: Muramatsu T,Yamashina Y,Tada H,Kobayashi N,Yamaji M,Ohno H,Shirai T,Takahashi A,Ohnishi T

    更新日期:1993-12-01 00:00:00

  • Protonation-state-Coupled Conformational Dynamics in Reaction Mechanisms of Channel and Pump Rhodopsins.

    abstract::Channel and pump rhodopsins use energy from light absorbed by a covalently bound retinal chromophore to transport ions across membranes of microbial cells. Ion transfer steps, including proton transfer, can couple to changes in protein conformational dynamics and water positions. Although general principles of how mic...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章,评审

    doi:10.1111/php.12790

    authors: Bondar AN,Smith JC

    更新日期:2017-11-01 00:00:00

  • Effects of ursodeoxycholic acid on photodynamic therapy in a murine tumor model.

    abstract::We previously reported that the efficacy of photodynamic therapy (PDT) in cell culture was enhanced by ursodeoxycholic acid (UDCA), a nontoxic bile acid. In this study, we examined the ability of UDCA to promote tumor control by PDT in the mouse, using the radiation-induced fibrosarcoma tumor and the photosensitizing ...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1562/0031-8655(2003)078<0407:eouaop>2.0.co;2

    authors: Garbo GM,Vicente MG,Fingar V,Kessel D

    更新日期:2003-10-01 00:00:00

  • Effects of Combined Lysosomal and Mitochondrial Photodamage in a Non-small-Cell Lung Cancer Cell Line: The Role of Paraptosis.

    abstract::We previously reported that a low level of lysosomal photodamage potentiated the phototoxic effect of subsequent mitochondrial photodamage mediated by the benzoporphyrin derivative (BPD) in murine hepatoma 1c1c7 cells. This was attributed to release of Ca2+ from damaged lysosomes and a calpain-mediated conversion of t...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/php.12805

    authors: Kessel D,Reiners JJ Jr

    更新日期:2017-11-01 00:00:00

  • Increasing Temperature Counteracts the Negative Effect of UV Radiation on Growth and Photosynthetic Efficiency of Microcystis aeruginosa and Raphidiopsis raciborskii.

    abstract::High temperature can promote cyanobacterial blooms, whereas ultraviolet radiation (UVR) can potentially depress cyanobacterial growth by damaging their photosynthetic apparatus. Although the damaging effect of UVR has been well documented, reports on the interactive effects of UV radiation exposure and warming on cyan...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/php.13377

    authors: Noyma NP,Mesquita MCB,Roland F,Marinho MM,Huszar VLM,Lürling M

    更新日期:2021-01-04 00:00:00

  • Effects of low-power laser irradiation on cell locomotion in protozoa.

    abstract::Low-power lasers are commonly used in human medicine for treatment of various pathological conditions, but mechanisms of their healing effects are still poorly understood. The results of this study provide information related to these effects at the cellular level. Two different protozoan species, Euglena gracilis and...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1562/0031-8655(2004)080<0531:EOLLIO>2.0.CO;2

    authors: Koutna M,Janisch R,Unucka M,Svobodnik A,Mornstein V

    更新日期:2004-11-01 00:00:00

  • Phototaxis of Haloarcula marismortui revealed through a novel microbial motion analysis algorithm.

    abstract::Haloarcula marismortui has been described to be nonmotile prior to the recent identification of flagellar filaments, suggesting the motile nature of H. marismortui. Here we observed the locomotion of freshly cultured H. marismortui cells and tracked the swimming trajectories via ImageJ. Trajectories of H. marismortui ...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.2010.00768.x

    authors: Lin YC,Fu HY,Yang CS

    更新日期:2010-09-01 00:00:00

  • Effect of vitamin E on cytotoxicity, DNA single strand breaks, chromosomal aberrations, and mutation in Chinese hamster V-79 cells exposed to ultraviolet-B light.

    abstract::The effect of pretreatment with vitamin E on cytotoxicity, DNA single strand breaks, and chromosomal aberrations as well as on mutation induced by ultraviolet-B light (UV-B) was investigated in Chinese hamster V-79 cells. Cellular pretreatment with non-toxic levels of 25 microM alpha-tocopherol succinate (vitamin E) f...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.1992.tb09598.x

    authors: Sugiyama M,Tsuzuki K,Matsumoto K,Ogura R

    更新日期:1992-07-01 00:00:00

  • Photochemistry of DNA using 193 nm excimer laser radiation.

    abstract::Photoproducts in double-stranded DNA induced by 193 nm radiation have been investigated. Double-stranded, supercoiled pBR322 DNA in buffered aqueous solution was exposed to varying fluences of 193 nm radiation from an ArF excimer laser. The quantum yields for formation of cyclobutylpyrimidine dimers, frank strand brea...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.1990.tb01961.x

    authors: Kochevar IE,Buckley LA

    更新日期:1990-05-01 00:00:00

  • NLOphoric Triphenylamine Derived Donor-π-Acceptor-π-Donor Based Colorants: Synthesis, Spectroscopic, Density Functional Theory and Z-scan Studies.

    abstract::Three Donor-π-Acceptor-π-Donor type styryl dyes (5a-c) with different secondary donors are synthesized and characterized to study their nonlinear and linear optical properties. The structure-property relationships of the dyes are described in the light of systematic photophysical and theoretical investigations. The ph...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/php.13089

    authors: Raikwar MM,Mathew E,Varghese M,Joe IH,Nethi SN

    更新日期:2019-07-01 00:00:00

  • Roles of porphyrin and iron metabolisms in the δ-aminolevulinic acid (ALA)-induced accumulation of protoporphyrin and photodamage of tumor cells.

    abstract::δ-Aminolevulinic acid (ALA)-induced porphyrin accumulation is widely used in the treatment of cancer, as photodynamic therapy. To clarify the mechanisms of the tumor-preferential accumulation of protoporphyrin, we examined the effect of the expression of heme-biosynthetic and -degradative enzymes on the ALA-induced ac...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.2011.00950.x

    authors: Ohgari Y,Miyata Y,Miyagi T,Gotoh S,Ohta T,Kataoka T,Furuyama K,Taketani S

    更新日期:2011-09-01 00:00:00

  • Ex vivo fluorescence imaging of normal and malignant urothelial cells to enhance early diagnosis.

    abstract::Urinary cytology is a noninvasive and unconstraining technique for urothelial cancer diagnosis but lacks sensitivity for detecting low-grade lesions. In this study, the fluorescence properties of classical Papanicolaou-stained urothelial cytological slides from patients or from cell lines were monitored to investigate...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.2007.00079.x

    authors: Steenkeste K,Lécart S,Deniset A,Pernot P,Eschwège P,Ferlicot S,Lévêque-Fort S,Briandet R,Fontaine-Aupart MP

    更新日期:2007-09-01 00:00:00

  • Synchronous fluorescence spectroscopy for the detection and characterization of cervical cancers in vitro.

    abstract::The objective of this study was to assess the diagnostic potential of synchronous fluorescence (SF) spectroscopy (SFS) technique for the detection and characterization of normal and different malignancy stages of moderately differentiated squamous cell carcinoma (MDSCC), poorly differentiated squamous cell carcinoma (...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.2009.00628.x

    authors: Ebenezar J,Aruna P,Ganesan S

    更新日期:2010-01-01 00:00:00

  • The effect of charge on cellular uptake and phototoxicity of polylysine chlorin(e6) conjugates.

    abstract::The effect of charge on the cellular uptake, localization and phototoxicity of conjugates between chlorin(e6) (ce6) and poly-L-lysine was studied in vitro. These conjugates (average MW 35-55 kDa) were synthesized to have polycationic, polyanionic or neutral charges. Two human cell lines (A431 epidermoid carcinoma cell...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.1997.tb01916.x

    authors: Soukos NS,Hamblin MR,Hasan T

    更新日期:1997-04-01 00:00:00

  • Comparison of UV-absorbing nets in pepper crops: spectral properties, effects on plants and pest control.

    abstract::In horticultural crops, the use of screens to protect plants is the usual strategy in the Mediterranean area. Screen manufacturers offer a range of netting that vary in their UV-absorbing properties. We compared the photoeffects of seven different screens. Sweet pepper trials were conducted at the Gilat Research Cente...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.2009.00657.x

    authors: Legarrea S,Karnieli A,Fereres A,Weintraub PG

    更新日期:2010-03-01 00:00:00

  • Biological weighting function for the mortality of Boeckella gracilipes (Copepoda, Crustacea) derived from experiments with natural solar radiation.

    abstract::We performed in situ experiments during the austral summer of 1998 to quantify the mortality of the fresh-water copepod Boeckella gracilipes as a function of the UV dose. The copepods were exposed to solar radiation at the water-surface for approximately 24-34 h. Long-pass cut-off filters (Schott) were used in the exp...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1562/0031-8655(2000)072<0314:bwfftm>2.0.co;2

    authors: Tartarotti B,Cravero W,Zagarese HE

    更新日期:2000-09-01 00:00:00

  • A Sharp Jump in Photocatalytic Activity of Elemental Sulfur for Dye Degradation in Alkaline Solution.

    abstract::Elemental sulfur is a low-cost and abundant substance as one of the largest by-products of the oil industry which was widely used in many industrial activities. Cyclo-octasulfur (S8 ) is one of the sulfur allotropes that is a very stable substance in standard conditions. In this study, we report a low-cost and fast me...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/php.13301

    authors: Peyman VA,Azizian S

    更新日期:2020-11-01 00:00:00

  • Alkali-labile photolesions mapping to purine sites in ultraviolet-irradiated DNA.

    abstract::Gel sequencing experiments with the 5'- and 3'-end-labeled oligonucleotides d(A3GA4GA5GA6GA3G) and d(AT)10 have demonstrated that dimeric adenine photoproducts and thymine-adenine photoadducts constitute alkali-labile lesions in UV-irradiated DNA. On treatment with hot piperidine, DNA strand breakage occurs predominan...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.1994.tb05022.x

    authors: Hejmadi V,Stevenson C,Kumar S,Davies RJ

    更新日期:1994-02-01 00:00:00

  • The Different Resistance of Two Astragalus Plants to UV-B Stress is Tightly Associated with the Organ-specific Isoflavone Metabolism.

    abstract::In this work, the changes in isoflavone levels and the expression of genes involved in their biosynthesis were studied in two Astragalus by UPLC-MS and real-time PCR after 10 days of UV-B treatment (λmax  = 313 nm, 804 J m-2 ). Isoflavones were significantly induced by UV-B irradiation. The influence might be activate...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/php.12841

    authors: Liu Y,Liu J,Wang Y,Abozeid A,Tian DM,Zhang XN,Tang ZH

    更新日期:2018-01-01 00:00:00

  • Suberythemal Sun Exposures at Swedish Schools Depend on Sky Views of the Outdoor Environments - Possible Implications for Pupils' Health.

    abstract::More scheduled outdoor stay is increasingly advocated for school children. This study measured 2(nd) , 5(th) and 8(th) graders' erythemal UV-exposure in September, March and May at four Swedish schools. We related those exposures, as fractions of total available ambient radiation, to the schools outdoor environments d...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/php.12540

    authors: Pagels P,Wester U,Söderström M,Lindelöf B,Boldemann C

    更新日期:2016-01-01 00:00:00

  • Protective Effect of BLED-exposed Conditioned Media on Cell Injury.

    abstract::Previous studies have reported that 450 nm blue light emitting diode (BLED) induces apoptosis through a mitochondria-mediated pathway in cancer cells and reduces the early stage tumor growth. This study was performed to determine the effects of BLED-irradiated cell metabolites on cell injury. Our results showed that c...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/php.12887

    authors: Oh PS,Kim EM,Kim M,Kim IS,Han YH,Lim S,Sohn MH,Ko MH,Jeong HJ

    更新日期:2018-05-01 00:00:00

  • Solar UV exposure of seafarers along subtropical and tropical shipping routes.

    abstract::Seafarers working on decks of vessels at low latitudes are exposed to extremely high solar UV radiation. Their risk of developing skin cancer may be enhanced. Solar erythemal UV irradiance and exposure were measured for the first time on merchant vessels going along typical international routes at low latitudes. The m...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/php.12144

    authors: Feister U,Meyer G,Kirst U

    更新日期:2013-11-01 00:00:00

  • Calculation of singlet oxygen dose using explicit and implicit dose metrics during benzoporphyrin derivative monoacid ring A (BPD-MA)-PDT in vitro and correlation with MLL cell survival.

    abstract::Photodynamic therapy (PDT) oxygen consumption, clonogenic cell survival, fluorescence photobleaching and photoproduct formation were investigated during benzoporphyrin derivative monoacid (BPD-MA)-PDT of MAT-LyLu cells in vitro. Cells were incubated with BPD-MA concentrations of 0.1, 0.5 or 2.5 μg mL(-1) for 2 h and t...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.2011.00942.x

    authors: Weston MA,Patterson MS

    更新日期:2011-09-01 00:00:00

  • Formation of aggregates of tryptic fragments derived from the carboxyl-terminal half of pea phytochrome and localization of the site of contact between the fragments by amino-terminal amino acid sequence analysis.

    abstract::Limited trypsinization of large pea (Pisum sativum cv. Alaska) phytochrome and subsequent size-exclusion chromatography (SEC) in 0.1 M Na phosphate, pH 7.8, yielded a high-molecular-mass aggregate of tryptic fragments of phytochrome. Further SEC in 0.1 M Tris-HCl, pH 7.5, plus various concentrations of NaSCN, indicate...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.1989.tb04136.x

    authors: Yamamoto KT,Tokutomi S

    更新日期:1989-07-01 00:00:00

  • Distance-dependent fluorescence quenching of tryptophan by acrylamide.

    abstract::We used GHz frequency-domain fluorometry to investigate the time-dependent intensity decays of N-acetyl-L-trytophanamide (NATA) when collisionally quenched by acrylamide in propylene glycol at 20 degrees C. The intensity decays of NATA became increasingly heterogeneous in the presence of acrylamide. The NATA intensity...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.1994.tb05092.x

    authors: Lakowicz JR,Zelent B,Gryczynski I,Kuśba J,Johnson ML

    更新日期:1994-09-01 00:00:00

  • Scrambled self-assembly of bacteriochlorophylls c and e in aqueous Triton X-100 micelles.

    abstract::Bacteriochlorophyll (BChl) e was coassembled with BChl c in Triton X-100 micelles in aqueous solutions. The Qy absorption bands of the coaggregates were positioned between those of aggregates consisting solely of BChl c or e. The electronic absorption spectra of the coaggregates could not be reproduced by linear combi...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/php.12219

    authors: Saga Y,Saiki T,Takahashi N,Shibata Y,Tamiaki H

    更新日期:2014-05-01 00:00:00