Abstract:
:In order to improve the adsorption capacities of corncob-based biochars for heavy metal, the different pyrolysis temperature (350 °C, 450 °C and 550 °C) of corncob-based biochars were modified with the acrylonitrile, and adsorption capacities of Cadmium from solution by biochars were studied. The results showed that only at 350 °C the biochar can be successfully modified. The Cd adsorption capacity (85.65 mg/g) by the biosorbent was higher than other methods of modifying biochars previously reported. SEM-EDS and FTIR confirmed that the CN group was grafted on the biochar at low pyrolysis temperature. Batch adsorption experiment including pH-dependence, adsorption kinetics, and isotherms and XPS results showed that the removal mechanism of Cd(II) by the modified biochar was ion exchange and adsorption-complexation. This research not only obtained a novel method to modify biochar but also furthered research into the lignin of biochar composition, and provided an efficient sorbent for heavy metal.
journal_name
Bioresour Technoljournal_title
Bioresource technologyauthors
Luo M,Lin H,Li B,Dong Y,He Y,Wang Ldoi
10.1016/j.biortech.2018.03.075subject
Has Abstractpub_date
2018-07-01 00:00:00pages
312-318eissn
0960-8524issn
1873-2976pii
S0960-8524(18)30426-7journal_volume
259pub_type
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