Abstract:
:The dissipation kinetics and residual levels of florasulam and tribenuron-methyl in wheat field ecosystem were determined using a quick, easy, cheap, efficient, rugged and safe method (QuEChERS) with rapid resolution liquid chromatography tandem mass spectrometry (RRLC-MS/MS). The average recoveries of florasulam and tribenuron-methyl at three spiking levels in wheat plant, soil, wheat straw and wheat grain ranged from 72.8% to 99.2% with relative standard deviations (RSDs) were less than 10.1% and 82.5% to 103.8% with RSDs were less than 9.4%, respectively. The limits of quantification (LOQs) of florasulam and tribenuron-methyl for wheat plant, wheat straw, wheat grain and soil were 0.01, 0.01, 0.005, 0.005 mg kg(-1), respectively. The field trials results showed that the half-lives of florasulam were 2.76-10.83 d. Half-lives for tribenuron-methyl were found to be 1.27-5.37 d. The terminal residues in wheat grain were much lower than maximum residue limits (MRLs) set by China (0.01 mg kg(-1) for florasulam and 0.05 mg kg(-1) for tribenuron-methyl), which considered to be safe for human beings. These results will contribute to establishing the scientific basis of the dosage of florasulam and tribenuron-methyl for use in wheat field ecosystems.
journal_name
Chemospherejournal_title
Chemosphereauthors
Dong B,Qian W,Hu Jdoi
10.1016/j.chemosphere.2014.09.016subject
Has Abstractpub_date
2015-02-01 00:00:00pages
486-91eissn
0045-6535issn
1879-1298pii
S0045-6535(14)01082-0journal_volume
120pub_type
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