Preliminary screening of polybrominated diphenyl ethers (PBDEs), hexabromocyclododecane (HBCDD) and tetrabromobisphenol A (TBBPA) flame retardants in landfill leachate.

Abstract:

:The occurrence of selected brominated flame retardants, including nine polybrominated diphenyl ether (PBDE) congeners, hexabromocyclododecane (HBCDD) and tetrabromobisphenol A (TBBPA) in leachate samples from eight landfill sites in South Africa, were investigated. In addition, the possible influences of dissolved organic carbon on their levels were also evaluated. Filtered leachate samples were subjected to solid-phase extraction to isolate the various target compounds. PBDEs with six bromine substituents and above, as well as α-HBCDD, β-HBCDD and TBBPA, were generally found below the detection limit. However, the mean value of the total lower PBDE congeners ranged between 0.04 and 0.48 μg L-1, and the concentrations of γ-HBCDD ranged from not detectable (ND) to 0.05 μg L-1. No significant correlation was observed between the target compounds and dissolved organic carbon, although weak to moderate correlations were mostly observed for the lower PBDEs.

journal_name

Environ Monit Assess

authors

Daso AP,Rohwer ER,Koot DJ,Okonkwo JO

doi

10.1007/s10661-017-6131-z

subject

Has Abstract

pub_date

2017-08-01 00:00:00

pages

418

issue

8

eissn

0167-6369

issn

1573-2959

pii

10.1007/s10661-017-6131-z

journal_volume

189

pub_type

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