Phosphorus in recycling fertilizers - analytical challenges.

Abstract:

:The importance of secondary raw materials for phosphorus (P) fertilizer production is expected to increase in the future due to resource depletion, supply risks, and heavy metal contamination of fossil phosphate resources. Municipal wastewater is a promising source for P recovery. In Germany for instance, it contains almost 50% of the total amount of P that is currently applied as mineral fertilizer. Several procedures have been developed to recover and re-use P resulting in a growing number of recycling fertilizers that are currently not regulated in terms of fertilizer efficiency. We tested various materials and matrices for their total P content, solubility of P in neutral ammonium citrate (Pnac) and water, and performed robustness tests to check if existing analytical methods are suitable for those new materials. Digestion with inverse aqua regia was best suited to determine the total P content. Pnac sample preparation and analyses were feasible for all matrices. However, we found significant time and temperature dependencies, especially for materials containing organic matter. Furthermore, several materials didn't reach equilibrium during the extractions. Thus, strict compliance of the test conditions is strongly recommended to achieve comparable results.

journal_name

Environ Res

journal_title

Environmental research

authors

Krüger O,Adam C

doi

10.1016/j.envres.2017.02.034

subject

Has Abstract

pub_date

2017-05-01 00:00:00

pages

353-358

eissn

0013-9351

issn

1096-0953

pii

S0013-9351(17)30386-9

journal_volume

155

pub_type

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