Modeling study of polychlorinated dibenzo-p-dioxins and dibenzofurans behavior in flue gases under electron beam irradiation.

Abstract:

:The efficiency of the electron beam treatment of industrial flue gases for the removal of sulfur and nitrogen oxides was investigated as applied to polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) using methods of mathematical modeling. The proposed kinetic model of the process includes mechanism of PCDD/Fs decomposition caused by their interaction with OH radicals generated in the flue gases under the electron beam (EB) irradiation as well as PCDD/Fs formation from unburned aromatic compounds. The model allows to predict the main features of the process, which are observed in pilot plant installations, as well as to evaluate the process efficiency. The results of calculations are compared with the available experimental data.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Gerasimov G

doi

10.1016/j.chemosphere.2016.05.064

subject

Has Abstract

pub_date

2016-09-01 00:00:00

pages

100-6

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(16)30711-1

journal_volume

158

pub_type

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