Process enhancement of supercritical methanol biodiesel production by packing beds.

Abstract:

:Continuous fixed bed reactors filled by three kinds of packing which were glass bead, glass spring and Dixon rings were investigated. The effect of temperature, pressure, the molar ratio of methanol to oil, flow rate, the size and shape of the packing were researched. The highest yield 90.84% of FAME was obtained by filling Dixon rings as packing with the condition of the temperature was 350°C, the pressure was 22MPa, the molar ratio of methanol to oil was 42:1. In addition, the reusability of Dixon rings was perfect. Numerical simulation was researched to provide theoretical basis for experimental results, besides the kinetics and thermodynamics behavior were investigated to explore the reaction mechanism.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Qiao BQ,Zhou D,Li G,Yin JZ,Xue S,Liu J

doi

10.1016/j.biortech.2016.12.085

subject

Has Abstract

pub_date

2017-03-01 00:00:00

pages

298-304

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(16)31763-1

journal_volume

228

pub_type

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