Abstract:
:The citric acid functionalized magnetic graphene oxide coated corn straw (CA-mGOCS) as a new adsorbent was synthesized in this work for the elimination of methylene blue (MB) from waste water. The as-prepared CA-mGOCS was tested by SEM, FTIR, XRD, Roman spectrum, TGA, particle size analyzer, BET and magnetic properties analyzer. Some factors affecting adsorption removal efficiency were explored. As a result, the addition of 5g CS (CA-mGO5CS) had the better adsorption performance than other adsorbents. The pseudo-second-order model and the Freundlich described the adsorption behavior well. The equilibrium adsorption capacity was 315.5mgg-1 for MB at pH=12 and 298k. The electrostatic incorporation as well as hydrophobic interactions between CA-mGO5CS and MB determined the favourable adsorption property. Besides, the thermodynamic studies results ΔG<0, ΔH<0, ΔS<0 suggested that the adsorption was a spontaneous, exothermic and randomness decrease process. Finally, reusability studies imply that CA-mGO5CS has an excellent reproducibility.
journal_name
Bioresour Technoljournal_title
Bioresource technologyauthors
Ge H,Wang C,Liu S,Huang Zdoi
10.1016/j.biortech.2016.09.060subject
Has Abstractpub_date
2016-12-01 00:00:00pages
419-429eissn
0960-8524issn
1873-2976pii
S0960-8524(16)31317-7journal_volume
221pub_type
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