Isolation of lignin by organosolv process from different varieties of rice husk: Understanding their physical and chemical properties.

Abstract:

:The aim of this work was to study the difference in properties of lignins, those (organosolv lignins (ORGLs, 12±3% yield and 93±5% mass balance) were isolated from diverse rice husk (RH) substrates using organosolv procedure (water:ethanol, H2SO4) carried out at 180°C for 1h. To identify the possible alterations in lignin structures several bulk and molecular level advanced characterization tools were employed. Even though lignins were extracted using common isolation procedure from three varieties of similar species of RH; from XRD, GPC, and elemental analysis it was found that those have comparable properties on bulk level. But molecular level analysis conducted using UV-vis, ATR, 1D/2D HSQC NMR techniques could help disclose that isolated lignins have varying concentrations of G, H, S and T substructures. Additionally, the double bond equivalence of 4.4-4.7 reveals that few of the aromatic rings are devoid of substituent.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Singh SK,Dhepe PL

doi

10.1016/j.biortech.2016.09.042

subject

Has Abstract

pub_date

2016-12-01 00:00:00

pages

310-317

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(16)31299-8

journal_volume

221

pub_type

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