Abstract:
:Advanced molecular materials that combine two or more physical properties are typically constructed by combining different molecules, each being responsible for one of the properties required. Ideally, single molecules could take care of this combined functionality, provided they are self-assembled correctly and endowed with different functional subunits whose strong electronic coupling may lead to the emergence of unprecedented and exciting properties. We present a class of disc-like semiconducting organic molecules that are functionalized with strong dipolar side groups. Supramolecular organization of these materials provides long-range polar order that supports collective ferroelectric behavior of the side groups as well as charge transport through the stacked semiconducting cores. The ferroelectric polarization in these supramolecular polymers is found to couple to the charge transport and leads to a bulk conductivity that is both switchable and rectifying. An intuitive model is developed and found to quantitatively reproduce the experimental observations. In a larger perspective, these results highlight the possibility of modulating material properties using the large electric fields associated with ferroelectric polarization.
journal_name
Sci Advjournal_title
Science advancesauthors
Gorbunov AV,Garcia Iglesias M,Guilleme J,Cornelissen TD,Roelofs WSC,Torres T,González-Rodríguez D,Meijer EW,Kemerink Mdoi
10.1126/sciadv.1701017subject
Has Abstractpub_date
2017-09-29 00:00:00pages
e1701017issue
9issn
2375-2548pii
1701017journal_volume
3pub_type
杂志文章相关文献
Science Advances文献大全abstract::The tendency to see life as zero-sum exacerbates political conflicts. Six studies (N = 3223) examine the relationship between political ideology and zero-sum thinking: the belief that one party's gains can only be obtained at the expense of another party's losses. We find that both liberals and conservatives view life...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aay3761
更新日期:2019-12-18 00:00:00
abstract::Photoresponsive liquid crystalline elastomers (LCEs) constitute ideal actuators for soft robots because their light-induced macroscopic shape changes can be harnessed to perform specific articulated motions. Conventional LCEs, however, do not typically exhibit complex modes of bending and twisting necessary to perform...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aay5349
更新日期:2020-03-27 00:00:00
abstract::Cyclosporine A (CsA) is a powerful immunosuppressant, but it is an ineffective stand-alone treatment for systemic lupus erythematosus (SLE) due to poor target tissue distribution and renal toxicity. We hypothesized that CD71 (transferrin receptor 1)-directed delivery of CsA to the lymphatic system would improve SLE ou...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.abb3900
更新日期:2020-06-12 00:00:00
abstract::The importance of comets for the origin of life on Earth has been advocated for many decades. Amino acids are key ingredients in chemistry, leading to life as we know it. Many primitive meteorites contain amino acids, and it is generally believed that these are formed by aqueous alterations. In the collector aerogel a...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.1600285
更新日期:2016-05-27 00:00:00
abstract::Lymphatic filariasis and onchocerciasis are two important neglected tropical diseases (NTDs) that cause severe disability. Control efforts are hindered by the lack of a safe macrofilaricidal drug. Targeting the Wolbachia bacterial endosymbionts in these parasites with doxycycline leads to a macrofilaricidal outcome, b...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aao1551
更新日期:2017-09-27 00:00:00
abstract::Interactions between top-down and bottom-up processes in the cerebral cortex hold the key to understanding attentional processes, predictive coding, executive control, and a gamut of other brain functions. However, the underlying circuit mechanism remains poorly understood and represents a major challenge in neuroscie...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.1601335
更新日期:2016-11-16 00:00:00
abstract::Altered cerebral glucose uptake is one of the hallmarks of Alzheimer's disease (AD). A dynamic glucose-enhanced (DGE) magnetic resonance imaging (MRI) approach was developed to simultaneously monitor d-glucose uptake and clearance in both brain parenchyma and cerebrospinal fluid (CSF). We observed substantially higher...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aba3884
更新日期:2020-05-13 00:00:00
abstract::Smart materials that are capable of memorizing a temporary shape, and morph in response to a stimulus, have the potential to revolutionize medicine and robotics. Here, we introduce an innovative method to program protein hydrogels and to induce shape changes in aqueous solutions at room temperature. We demonstrate our...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aba6112
更新日期:2020-04-29 00:00:00
abstract::Ewing sarcoma (EwS) is an aggressive tumor that affects adolescents and young adults. EwS is defined by a chromosomal translocation, EWSR1-FLI1 being the most common, that causes genome reprogramming through remodeling of enhancers. Here, we describe an unexpected function of RING1B, which is highly expressed in EwS. ...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aba3058
更新日期:2020-10-23 00:00:00
abstract::The process of sheep and goat (caprine) domestication began by 9000 to 8000 BCE in Southwest Asia. The early Neolithic site at Aşıklı Höyük in central Turkey preserves early archaeological evidence of this transformation, such as culling by age and sex and use of enclosures inside the settlement. People's strategies f...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aaw0038
更新日期:2019-04-17 00:00:00
abstract::Massive declines in population abundances of marine animals have been documented over century-long time scales. However, analogous loss of spatial extent of habitat-forming organisms is less well known because georeferenced data are rare over long time scales, particularly in subtidal, tropical marine regions. We use ...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.1603155
更新日期:2017-09-06 00:00:00
abstract::Dirac materials such as graphene and topological insulators (TIs) are known to have unique electronic and spintronic properties. We combine graphene with TIs in van der Waals heterostructures to demonstrate the emergence of a strong proximity-induced spin-orbit coupling in graphene. By performing spin transport and pr...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aat9349
更新日期:2018-09-21 00:00:00
abstract::The development of advanced chemical-to-electrical energy conversions requires fast and efficient electrocatalysis of multielectron/multiproton reactions, such as the oxygen reduction reaction (ORR). Using molecular catalysts, correlations between the reaction rate and energy efficiency have recently been identified. ...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aaz3318
更新日期:2020-03-13 00:00:00
abstract::The social bond between parents and offspring is characterized by coadaptation and balance between altruistic and selfish tendencies. However, its underlying genetic mechanism remains poorly understood. Using transcriptomic screens in the subsocial European earwig, Forficula auricularia, we found the expression of mor...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aaw0070
更新日期:2020-01-03 00:00:00
abstract::Resistances that exceed the Mott-Ioffe-Regel limit (known as bad metal behavior) and non-Fermi liquid behavior are ubiquitous features of the normal state of many strongly correlated materials. We establish the conditions that lead to bad metal and non-Fermi liquid phases in NdNiO3, which exhibits a prototype bandwidt...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.1500797
更新日期:2015-11-06 00:00:00
abstract::We present results from a study in the Democratic Republic of the Congo that uses mobile money networks to run rotating savings and credit associations (ROSCAs), peer-to-peer finance groups ubiquitous across the developing world. We find high rates of contribution and ROSCA success. The unexpected success of such e-RO...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.abc5831
更新日期:2021-01-01 00:00:00
abstract::Planarians exhibit traits of cephalization but are unique among bilaterians in that they ingest food by means of goal-directed movements of a trunk-positioned pharynx, following protrusion of the pharynx out of the body, raising the question of how planarians control such a complex set of body movements for achieving ...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aaz0882
更新日期:2020-04-08 00:00:00
abstract::Bioengineered three-dimensional (3D) matrices expand our experimental repertoire to study tumor growth and progression in a biologically relevant, yet controlled, manner. Here, we used peptide amphiphiles (PAs) to coassemble with and organize extracellular matrix (ECM) proteins producing tunable 3D models of the tumor...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.abb3298
更新日期:2020-10-02 00:00:00
abstract::Membrane proteins must balance the sequence constraints associated with folding and function against the hydrophobicity required for solvation within the bilayer. We recently found the expression and maturation of rhodopsin are limited by the hydrophobicity of its seventh transmembrane domain (TM7), which contains pol...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aay7505
更新日期:2020-03-04 00:00:00
abstract::Rising temperatures in the Arctic Ocean region are responsible for changes such as reduced ice cover, permafrost thawing, and increased river discharge, which, together, alter nutrient and carbon cycles over the vast Arctic continental shelf. We show that the concentration of radium-228, sourced to seawater through se...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aao1302
更新日期:2018-01-03 00:00:00
abstract::Mineral exploitation has spread from land to shallow coastal waters and is now planned for the offshore, deep seabed. Large seafloor areas are being approved for exploration for seafloor mineral deposits, creating an urgent need for regional environmental management plans. Networks of areas where mining and mining imp...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aar4313
更新日期:2018-07-04 00:00:00
abstract::In a recent paper, Lechner, Hauke, and Zoller (LHZ) described a means to translate a Hamiltonian of N spin-1/2 particles with "all-to-all" interactions into a larger physical lattice with only on-site energies and local parity constraints. LHZ used this mapping to propose a novel form of quantum annealing. We provide ...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.1601246
更新日期:2016-10-21 00:00:00
abstract::Organic matter burial in mangrove forests results in the removal and long-term storage of atmospheric CO2, so-called "blue carbon." However, some of this organic matter is metabolized and returned to the atmosphere as CH4. Because CH4 has a higher global warming potential than the CO2 fixed in the organic matter, it c...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aao4985
更新日期:2018-06-13 00:00:00
abstract::Wearable textile electronics are highly desirable for realizing personalized health management. However, most reported textile electronics can either periodically target a single physiological signal or miss the explicit details of the signals, leading to a partial health assessment. Furthermore, textiles with excelle...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aay2840
更新日期:2020-03-13 00:00:00
abstract::[This corrects the article DOI: 10.1126/sciadv.aar3761.]. ...
journal_title:Science advances
pub_type: 杂志文章,已发布勘误
doi:10.1126/sciadv.aau4713
更新日期:2018-07-06 00:00:00
abstract::The homotrimeric molecular chaperone Skp of Gram-negative bacteria facilitates the transport of outer membrane proteins across the periplasm. It has been unclear how its activity is modulated during its functional cycle. Here, we report an atomic-resolution characterization of the Escherichia coli Skp monomer-trimer t...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.abc5822
更新日期:2020-10-21 00:00:00
abstract::Perovskite oxides exhibit potential for use as electrocatalysts in the oxygen evolution reaction (OER). However, their low specific surface area is the main obstacle to realizing a high mass-specific activity that is required to be competitive against the state-of-the-art precious metal-based catalysts. We report the ...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.1603206
更新日期:2017-06-21 00:00:00
abstract::Metabolites of the intestinal microbiota are thought to be generated through metabolic pathways spanning multiple taxa of intestinal bacteria. We have previously shown that the level of putrescine, a polyamine found abundantly in the human intestinal lumen, is increased in the colonic lumen following administration of...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aat0062
更新日期:2018-06-27 00:00:00
abstract::Prosocial behavior is paradoxical because it often entails a cost to one's own welfare to benefit others. Theoretical models suggest that prosociality is driven by several forms of reciprocity. Although we know a great deal about how each of these forms operates in isolation, they are rarely isolated in the real world...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aba0504
更新日期:2020-06-03 00:00:00
abstract::Pathological cardiac hypertrophy eventually leads to heart failure without adequate treatment. The immunoproteasome is an inducible form of the proteasome that is intimately involved in inflammatory diseases. Here, we found that the expression and activity of immunoproteasome catalytic subunit β5i were significantly u...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aau0495
更新日期:2019-05-08 00:00:00